<p>The asymptotic shape of the marginal frequency distribution of geochemical variables has been proposed as indicator of multi-fractality. Transition into a certain statistical regime as inferred from the distribution function may be considered as criterion to delineate geochemical anomalies, including mineral resources or pollutants such as radioactive fallout or geogenic radon.</p><p>The argument is that asymptotic linearity in log-log scale, log(F(z)) = a - b log(z) as z&#8594;&#8734;, b>0 a constant, indicates multi-fractality.</p><p>We discuss this with respect to two issues:</p><p>(1) What are the consequences of estimating the slope b for non-ergodic, in particular non-representative and preferential sampling schemes, as often the case in geochemical or pollution surveys?</p><p>(2) Frequently in geochemistry, multiplicative cascades are considered valid generators of multifractal fields, corroborated by observed f(&#945;) functions and variograms (Mat&#232;rn or power, for low lags). This generator leads to marginally asymptotically (high cascade orders) log-normal distributions, which in log-log scale are asymptotically (high z) parabolic, not linear.</p><p>Theoretical aspects are addressed as well as examples given.</p>