Hyperbolic metamaterials: fusing artificial structures to natural 2D materials

Optical metamaterials have presented an innovative method of manipulating light. Hyperbolic metamaterials have an extremely high anisotropy with a hyperbolic dispersion relation. They are able to support high-k modes and exhibit a high density of states which produce distinctive properties that have been exploited in various applications, such as super-resolution imaging, negative refraction, and enhanced emission control. Here, state-of-the-art hyperbolic metamaterials are reviewed, starting from the fundamental principles to applications of artificially structured hyperbolic media to suggest ways to fuse natural two-dimensional hyperbolic materials. The review concludes by indicating the current challenges and our vision for future applications of hyperbolic metamaterials.

Self-assembly of photonic crystals by controlling the nucleation and growth of DNA-coated colloids

DNA-coated colloids can self-assemble into an incredible diversity of crystal structures, but their applications have been limited by poor understanding and control over the crystallization dynamics. To address this challenge, we use microfluidics to quantify the kinetics of DNA-programmed self-assembly along the entire crystallization pathway, from thermally activated nucleation through reaction-limited and diffusion-limited phases of crystal growth. Our detailed measurements of the temperature and concentration dependence of the kinetics at all stages of crystallization provide a stringent test of classical theories of nucleation and growth. After accounting for the finite rolling and sliding rates of micrometer-sized DNA-coated colloids, we show that modified versions of these classical theories predict the absolute nucleation and growth rates with quantitative accuracy. We conclude by applying our model to design and demonstrate protocols for assembling large single crystals with pronounced structural coloration, an essential step in creating next-generation optical metamaterials from colloids.

The chiral coating on an achiral nanostructure by the secondary effect in focused ion beam induced deposition

Optical metamaterials are widely used in electromagnetic wave modulation due to their sub-wavelength feature sizes. In this paper, a method to plate an achiral nanopillar array with chiral coating by the secondary effect in focused ion beam induced deposition is proposed. Guided by the pattern defined in a bitmap with variable residence time, the beam scan strategy suppresses the interaction between adjacent nanostructures. A uniform chiral coating is formed on the target nanostructure without affecting the adjacent nanostructure, under carefully selected beam parameters and the rotation angle of the sample stage. Energy Dispersive X-Ray Spectroscopy results show that the chiral film has high purity metal, which enables the generation of localized surface plasmon resonances and causes the circular dichroism under circularly polarized light illumination. Finally, the tailorable circular dichroism spectrum of the coated array is verified by the Finite Difference Time Domain method.

Reconfigurable terahertz metasurfaces coherently controlled by wavelength-scale-structured light

Structuring light–matter interaction at a deeply subwavelength scale is fundamental to optical metamaterials and metasurfaces. Conventionally, the operation of a metasurface is determined by the collective electric polarization response of its lithographically defined structures. The inseparability of electric polarization and current density provides the opportunity to construct metasurfaces from current elements instead of nanostructures. Here, we realize metasurfaces using structured light rather than structured materials. Using coherent control, we transfer structure from light to transient currents in a semiconductor, which act as a source for terahertz radiation. A spatial light modulator is used to control the spatial structure of the currents and the resulting terahertz radiation with a resolution of 5.6 ± 0.8 μm $5.6\pm 0.8\mathrm{\,\mu m}$ , or approximately λ / 54 $\lambda /54$ at a frequency of 1 THz. The independence of the currents from any predefined structures and the maturity of spatial light modulator technology enable this metasurface to be reconfigured with unprecedented flexibility.