Injection Molding of Coir Coconut Fiber Reinforced Polyolefin Blends: Mechanical, Viscoelastic, Thermal Behavior and Three-Dimensional Microscopy Study

In this study, the properties of a polyolefin blend matrix (PP-HDPE) were evaluated and modified through the addition of raw coir coconut fibers-(CCF). PP-HDPE-CCF biocomposites were prepared using melt blending processes with CCF loadings up to 30% (w/w). CCF addition generates an increase of the tensile and flexural modulus up to 78% and 99% compared to PP-HDPE blend. This stiffening effect is caused by a decrease in the polymeric chain mobility due to CCF, the higher mechanical properties of the CCF compared to the polymeric matrix and could be an advantage for some biocomposites applications. Thermal characterizations show that CCF incorporation increases the PP-HDPE thermal stability up to 63 °C, slightly affecting the melting behavior of the PP and HDPE matrix. DMA analysis shows that CCF improves the PP-HDPE blend capacity to absorb higher external loads while exhibiting elastic behavior maintaining its characteristics at higher temperatures. Also, the three-dimensional microscopy study showed that CCF particles enhance the dimensional stability of the PP-HDPE matrix and decrease manufacturing defects as shrinkage in injected specimens. This research opens a feasible opportunity for considering PP-HDPE-CCF biocomposites as alternative materials for the design and manufacturing of sustainable products by injection molding.

Microstructure of Filled Biocomposites Based on Polyolefin Blends

Binary and ternary composites based on low-density polyethylene and a copolymer of ethylene and vinyl acetate with / without the addition of microcrystalline cellulose have been investigated. The analysis of microstructure of the filled composites has shown more uniform distribution of particles at the mechanochemical treatment of the composite melt. Based on DSC study results, polymers amorphisation in the composites occurred under ultrasonic action. The stress-related characteristics of the materials increased that is explained by improved compatibility and partial copolymerization of the blended polymers.