Facile Fabric Detoxification Treatment Method Using Microwave and Polyethyleneimine Against Nerve Gas Agents

Generally, detoxification fabrics are defined as fabrics that remove or inhibit the production of toxic compounds, especially chemical warfare agents such as nerve gas agents. They are usually prepared using a complicated and time-consuming method. This study suggests a facile treatment method for preparing detoxification fabrics against nerve gas agents using polyethyleneimine and microwave curing. The detoxification properties of polyethyleneimine and microwave-treated polypropylene nonwoven fabric were evaluated using diisopropylfluoro-phosphate, which is a nerve agent simulant. The treated polypropylene fabric decontaminated 53.6% of diisopropylfluorophosphate (DFP) in 2 h at 32 °C, and the half-life of DFP on the surface of the treated fabric was 122 min. The result indicates that the treated fabric can act as a basic organocatalyst for the DFP hydrolysis and has a shorter half-life owing to the large number of amine groups. Therefore, the facile treatment method has the potential for use in the preparation of detoxification fabrics.

Nanostructured Molecularly Imprinted Photonic Polymers for Sensing Applications

This review article focused on fabrication of sensors by using a combination of highly ordered photonic crystals and molecular imprinted polymers as artificial recognition materials. In this article, we have discussed fundamental principle of photonic crystals, various synthetic approaches and their use in sensing applications. Moreover, nanostructuring of recognition materials, by using photonic crystals, for sensor fabrication and sensing mechanism has also been discussed. Molecular imprinted photonic polymer layers have been applied for developing sensor devices for diverse analytes such as environmental toxins, nerve gas agents, explosives, drug molecules and others. A comprehensive comparison of molecular imprinted photonic polymers based sensor systems has also been summarized in the table which contains all the related information about colloidal structure, polymer system including monomer, cross-linker and initiator as well as target analytes. Finally, emerging strategies and current challenges involved in the design of more efficient molecular imprinted photonic sensors and their possible solutions are also briefly discussed.

Towards Protecting Critical National Assets and Preparedness for Response to Hazardous Chemical, Biological and Radiological Attacks

Hazardous chemical, biological and radiological (CBR) materials are catching attention of unscrupulous actors for creating terror and havoc. Threat perception for use of such materials by terrorists and non-state actors for malicious purposes, is not imaginative but real and imminent in today’s context. World has witnessed a number of such incidences in the recent years, e.g., Mustard gas attack against Kurdish forces in Iraq; ricin laced letters sent to US President and others senators; use of Nerve gas agents in Syria; capturing of Uranium from University of al- Mousal, Iraq by IS, etc. National assets like critical buildings where main legislative, historical building, Hospitals are some of the likely targets for CBR attacks attract quick coverage by media. Authorities related with managing and safeguarding mechanisms of the facilities to prevent such events happening also to enhance their capabilities as well as effective response. Essential CBR security should include measures to rapidly detect and effectively deter the CBR incidences their deleterious consequences. In this review, protection of the critical facilities from CBR attacks and capacity in terms of infrastructure, specialised training and mutual aid have been discussed.

Toward a detoxification fabric against nerve gas agents: guanidine-functionalized poly[2-(3-butenyl)-2-oxazoline]/Nylon-6,6 nanofibers

A novel guanidine-functionalized polymer, poly[2-(3-butenyl)-2-oxazoline] (PBuOxz), has been co-electrospun with Nylon-6,6 to form fibers that could be used for the decontamination of chemical warfare agents (CWAs).