Unusual metasomatites (phyolithites) in the Kolvitskiy gabbro-anorthosite rock mass: composition and structural position

Complex mineralogical, geochemical, and geological-structural characteristics of a rare collection stone of violet color, phyolithite, in the southwestern part of the Kola Peninsula. This is a metasomatic rock formed under the conditions of brittle deformations on gabbro-anorthosites of the Paleoproterozoic Kolvitskiy rock mass. As a result of potassium metasomatosis, the plagioclase of the initial rocks was replaced by a fine-grained mica aggregate of muscovite-phengite composition with inclusions of Va-aluminoseladonite (up to 20-30 microns). Ba-aluminoseladonite contains 6.6-10.5 % by weight of BaO. Manganese is the only chromophore that accumulates in the rock during metasomatosis. It is manganese that provides the purple-violet color of pseudomorphs of mica according to anorthite. The phyolithites is depleted by REE and has a positive Eu-anomaly. The phyolithites are confined to the areas of fracturing of the north-eastern strike, located in the zone of dynamic influence of the north-western closure of the Onega-Kandalaksha rift of the Riphean age. Other formations (injection conglomerates and lamproites) are also associated with the formation of this structure, which owe their origin to an intense fluid flow.

Magmatic and metasomatic processes during formation of the Nb-Zr-REE deposits Khaldzan Buregte and Tsakhir (Mongolian Altai): Indications from a combined CL-SEM Study

Cathodoluminescence (CL) imaging and spectroscopy, as well as backscattered electron imaging, were used to assign the occurrence of several mineral phases and rock structures in altered nordmarkites and calcite-bearing granites from the Nb-Zr-REE deposits from Khaldzan Buregte and Tsakhir (Mongolian Altai) to three events: (1) intrusion of barren nordmarkites; (2) intrusion of small bodies of calcite-bearing granites with metasomatic alteration of the wall-rocks; and (3) alteration by F-rich fluids.Unusual red and yellow CL caused by Fe3+ and Mn2+ emission centres were detected in microcline and albite. Fe3+ centres were also established (along with others) in quartz, zircon, and possibly in fluorite.Magmatic and metasomatic rock structures and internal structures of the minerals coexist in the samples. The primary magmatic features were in part preserved during alteration. In contrast, the internal and the centre structures may be changed during alteration even in non-replaced mineral phases. Euhedral minerals may be formed by secondary processes as shown for lath-shaped albite. The occurrence of pseudomorphs, the inheritance of elements during replacement, and the mechanical effects of secondary minerals on earlier mineral phases during metasomatic growth are proposed as criteria for the reconstruction of the mineral succession in altered rocks. Snowball structures may be formed as a result of metasomatic alteration rather than as a magmatic intergrowth.

The Ilímaussaq batholith. A review and discussion

The Ilímaussaq batholith was examined and described in a masterly way by N.V. Ussing in the first years of this century. During the last few years, the region has been re-examined and this work is still being carried out. It is based on maps far superior to those used by Ussing. This paper is a summary of the present knowledge of the geology of the batholith. Ilímaussaq is one of many plutonic bodies in the alkaline province of South Greenland. Its formation was preceded by the accumulation of sandstone, extrusion of lavas, and block movements. The country rock consists of granite. Ussing divided the plutonic rocks of Ilímaussaq into two groups: 1) the unstratified complex made up of fairly normal rocks as augite syenite, essexite, nordmarkite, and arfvedsonite granite ; 2) the stratified, peralkaline, agpaitic nepheline syenites: sodalite foyaite, naujaite, kakortokite, and lujavrite. These rocks are often rich in sodalite and eudialyte. The marginal borders of the batholith are transgressive. The agpaites are overlain by almost horizontal beds of porphyries. The stratified part of the complex is saucer-shaped. According to Ussing the batholith was formed in two stages; in the first stage the unstratified rocks crystallized, in the second the agpaites were intruded and partially replaced the unstratified rocks. The differentiation of the agpaites has later been discussed by Fersman and Backlund. Wegmann considered the nepheline syenites to be of metasomatic origin. The Ilímaussaq batholith is compared with other regions of alkaline rocks. On this basis and in the light of new field data the magmatic and metasomatic modes of formation of the batholith are discussed. Much more field work is, however, still necessary before more final conclusions can be reached. In addition to Ussing’s interpretation of the genesis of the batholith a somewhat different magmatic explanation is put forward. Augite syenite is considered to be the primary magma. A part of this magma was trapped under an impermeable roof and huge amounts of volatiles were accumulated in the magma during its crystallization, especially in its upper part (cf. Sather, 45). The sodalite-rich naujaite crystallized in the upper part of the magma, the banded kakortokite at a deeper level. In a later phase, subsidence of parts of the batholith occurred and at this stage the melanocratic and schistose lujavrite was formed. This rock can be compared with tinguaites and may then be considered to be magmatic, but it may also be regarded as a metasomatic rock especially formed in the most deformed parts of the complex. Wegmann’s view that essexite, nordmarkite and porphyries are metasomatically transformed into nepheline syenites is discussed. It is supported by the finding of a pillow structure in the lujavrite. As an alternative the writer suggests that the metasomatism has acted upon an older plutonic body made up of augite syenite and foyaite, etc. In the writer's opinion the combination of magmatic and metasomatic processes is in best agreement with the field observations.