Oxyfuel Combustion of a Model MSW—An Experimental Study

The oxyfuel combustion of a model MSW (municipal solid waste) under various conditions was carried out in a lab-scale reactor. The aim was to study the behavior of MSW and identify challenges and opportunities associated with the development of this technology in the context of integration with CCS (carbon capture and storage). The experimental results show the effects of the oxidizer composition on the combustion process. Complete combustion can be attained under a variety of oxyfuel conditions, and the differences highlighted with O2/CO2 as an oxidizer compared with O2/N2 do not constitute showstoppers. MSW oxyfuel combustion hence offers a great potential for the combined (1) treatment of waste (contaminants’ destruction, volume, and weight reduction), (2) production of heat/power, and (3) CCS with negative CO2 emissions.

Power-to-Green Methanol via CO2 Hydrogenation—A Concept Study Including Oxyfuel Fluidized Bed Combustion of Biomass

A revolution of the global energy industry is without an alternative to solving the climate crisis. However, renewable energy sources typically show significant seasonal and daily fluctuations. This paper provides a system concept model of a decentralized power-to-green methanol plant consisting of a biomass heating plant with a thermal input of 20 MWth. (oxyfuel or air mode), a CO2 processing unit (DeOxo reactor or MEA absorption), an alkaline electrolyzer, a methanol synthesis unit, an air separation unit and a wind park. Applying oxyfuel combustion has the potential to directly utilize O2 generated by the electrolyzer, which was analyzed by varying critical model parameters. A major objective was to determine whether applying oxyfuel combustion has a positive impact on the plant’s power-to-liquid (PtL) efficiency rate. For cases utilizing more than 70% of CO2 generated by the combustion, the oxyfuel’s O2 demand is fully covered by the electrolyzer, making oxyfuel a viable option for large scale applications. Conventional air combustion is recommended for small wind parks and scenarios using surplus electricity. Maximum PtL efficiencies of ηPtL,Oxy = 51.91% and ηPtL,Air = 54.21% can be realized. Additionally, a case study for one year of operation has been conducted yielding an annual output of about 17,000 t/a methanol and 100 GWhth./a thermal energy for an input of 50,500 t/a woodchips and a wind park size of 36 MWp.

A theoretical analysis of the burn-out times of an isothermal particle of coal char under air-firing, gasification and oxyfuel combustion in fluidised beds

<p></p><p>The combustion of coal in air, its gasification with carbon dioxide, and oxyfuel combustion in oxygen/carbon dioxide mixtures was studied at high process temperatures in a bubbling fluidised bed reactor where burning is controlled by external mass transfer conditions. Theoretical analysis of the burn-out times of an isothermal particle of coal char in air is provided for the case where a fraction of carbon monoxide is oxidized close to the char particle. Burn-out time equations are provided for the gasification of char in carbon dioxide. Both burn-out time equations are compared to analytical equations derived for the oxy-fuel combustion of char particles in oxygen/carbon dioxide mixtures. The results are particularly relevant for retrofitting existing bubbling fluidised bed reactors for sustainable energy generation to meet global warming targets. </p><p></p>

A Simple Theoretical Analysis of the Burn-out Times of an Isothermal Particle of Coal Char Under Air-Firing, Gasification and Oxyfuel Combustion in Fluidised Beds

<p></p><p>Coal combustion in air, gasification with carbon dioxide, and oxyfuel combustion in oxygen/carbon dioxide mixtures was studied at high process temperatures in a bubbling fluidised bed reactor where burning is controlled by external mass transfer conditions. Theoretical analysis of the burn-out times of an isothermal particle of coal char in air is provided for the case where a fraction of carbon monoxide is oxidized close to the char particle. Burn-out time equations are provided for the gasification of char in carbon dioxide. Both burn-out time equations are compared to analytical equations derived for the oxy-fuel combustion of char particles in oxygen/carbon dioxide mixtures. The results are particularly relevant for retrofitting existing bubbling fluidised bed reactors for clean energy generation to meet global warming targets.</p><p></p>

A Simple Theoretical Analysis of the Burn-out Times of an Isothermal Particle of Coal Char Under Air-Firing, Gasification and Oxyfuel Combustion in Fluidised Beds

<p></p><p>Coal combustion in air, gasification with carbon dioxide, and oxyfuel combustion in oxygen/carbon dioxide mixtures was studied at high process temperatures in a bubbling fluidised bed reactor where burning is controlled by external mass transfer conditions. Theoretical analysis of the burn-out times of an isothermal particle of coal char in air is provided for the case where a fraction of carbon monoxide is oxidized close to the char particle. Burn-out time equations are provided for the gasification of char in carbon dioxide. Both burn-out time equations are compared to analytical equations derived for the oxy-fuel combustion of char particles in oxygen/carbon dioxide mixtures. The results are particularly relevant for retrofitting existing bubbling fluidised bed reactors for clean energy generation to meet global warming targets.</p><p></p>

A Simple Theoretical Analysis of the Burn-out Times of an Isothermal Particle of Coal Char Under Air-Firing, Gasification and Oxyfuel Combustion in Fluidised Beds

<p>Coal combustion in air, gasification with carbon dioxide and oxyfuel combustion in oxygen/carbon dioxide mixtures was studied at high process temperatures in a bubbling fluidised bed reactor where burning is controlled by external mass transfer conditions is considered. Theoretical analysis of the burn-out times of an isothermal particle of coal char in air is provided for the case where a fraction of carbon monoxide is oxidized close to the char particle. Burn-out time equations are provided for the gasification of char in carbon dioxide. Both burn-out time equations are compared to analytical equations derived for the oxy-fuel combustion of char particles in oxygen/carbon dioxide mixtures. </p>

A Simple Theoretical Analysis of the Burn-out Times of an Isothermal Particle of Coal Char Under Air-Firing, Gasification and Oxyfuel Combustion in Fluidised Beds

<p>Coal combustion in air, gasification with carbon dioxide and oxyfuel combustion in oxygen/carbon dioxide mixtures was studied at high process temperatures in a bubbling fluidised bed reactor where burning is controlled by external mass transfer conditions. Theoretical analysis of the burn-out times of an isothermal particle of coal char in air is provided for the case where a fraction of carbon monoxide is oxidized close to the char particle. Burn-out time equations are provided for the gasification of char in carbon dioxide. Both burn-out time equations are compared to analytical equations derived for the oxy-fuel combustion of char particles in oxygen/carbon dioxide mixtures. </p>