This paper reports the
isolation of a series of new coordination compounds formed with the terdentate
ligand 2,4,6-tri(2?-pyridyl)- 1,3,5-triazine (tpt)
and various bivalent cobalt salts. The stereochemistries of these compounds are
proposed after consideration of their elementary analyses, visible solid and
solution spectra, infrared spectra, magnetic moments, and thermogravimetric
studies. ��� The chelates obtained include octahedral bis-complexes
of the type [Co tpt2]X2 (where
X = Cl, Br, I, CNS, ClO4,
NO3, BF4, or BPh4)
and five- coordinate mono-complexes of the type CoXz tpt (where X = Cl, Br, I, or
NCS). A third dimeric form is also reported of general formula Co2X4 tpt,nH2O
(where X = Cl, n = 0 or I; X = Br, n = 0 or 2). In
this latter form the ligand appears to function as a composite of both
terpyridine and bipyridine, showing simultaneous terdentate and bidentate
behaviour, with one cobalt atom in either a five-coordinate or six- coordinate
environment, and the other metal atom involved in tetrahedral coordination. ��� In general the compounds formed are
high-spin with normal room- temperature magnetic moments. The single exception
is the red octahedral complex [Co tpt2]Cl2, 8.5H2O, which has a
room-temperature moment of only 4.0 B.M.