Zinc Recovery from Wulagen Sulfide Flotation Plant Tail by Applying Ether Amine Organic Collectors

Separating oxidized zinc minerals from flotation tailings is always a challenge. In this study, a flotation tailing from Wulagen zinc mine in China (Zn grade < 1%) was processed using froth flotation with combinations of amines (OPA 10, OPA 1214, OPA 13, DDA) and Na2S to study the effects of these amines on the zinc recovery as well as their interactions with other reagents, aiming to screen out a proper reagent scheme to improve zinc separation from extremely low-grade zinc flotation tailings. The results show that different amines led to different flotation performance, and the collectors were ranked as OPA 1214, OPA 13, OPA 10 and DDA in a decreasing order based on flotation collectivity and selectivity. An increase in the concentration of each collector increased the zinc recovery but reduced the concentrate zinc grade. Interactions were also observed between different amines and Na2S and Na2SiO3, and OPA 1214 outdid the others in saving the usage of both the Na2S and Na2SiO3. The measured adsorption of collector onto smithsonite was found to correlate well with flotation test results. It was concluded that hydrocarbon chains can be held accountable for the difference in the flotation performance with different amines. The longer the hydrocarbon chain, the stronger the hydrophobic association ability of amine, which is conducive to the selective amine adsorption onto sulfurized smithsonite particles and hence the smithsonite flotation.

Specific Ion Effects on the Behavior of Mixtures of Sodium Iso-Butyl Xanthate and Sodium Diethyl Dithiophosphate during the Flotation of a Cu-Ni-PGM Ore: Effects of CaCl2 and NaCl

Inorganic electrolytes present in the process water used during froth flotation may have both beneficial and detrimental effects. These effects are said to be ion specific, as some ions may result in enhanced froth stability, increased mineral recoveries and decreased concentrate grades, while others may bring the opposite effects. Onsite process water quality variations have intensified the need to understand the relationship between inorganic electrolytes and flotation reagents on flotation performance. The use of mixtures of thiol collectors in sulfide flotation is a common practice across the globe; however, very few investigations have considered these in process waters of varying compositions. This study considers the effect of common cations, Na+ and Ca2+, in process water on the behavior of mixtures of thiol collectors. Single-salt solutions of NaCl and CaCl2 at an ionic strength of 0.0213 mol·dm−3 were used to investigate the behavior of mixtures of two thiol collectors. These were carefully selected to understand how mixtures of thiol collectors behave in the presence of a monovalent cation versus a polyvalent cation. Bench-scale froth flotation tests were conducted using a Cu-Ni-PGM ore from the Merensky Reef. The results have shown that the divalent cation, Ca2+, resulted in higher %Cu and %Ni recoveries at all collector mixtures compared to the monovalent cation, Na+. The concentrate grades were, however, slightly compromised, as slightly more gangue reported to the concentrate in the presence of Ca2+. This behavior is attributed to the effect of polyvalent cations on bubble coalescence and froth stability.

Estimation and Improvement of Recovery of Low Grade Copper Oxide Using Sulfide Activation Flotation Method Based on GA–BPNN

Copper oxide ore is an important copper ore resource. For a certain copper oxide ore in Yunnan, China, experiments have been conducted on the grinding fineness, collector dosage, sodium sulfide dosage, inhibitor dosage, and activator dosage. The results showed that, by controlling the above conditions, better sulfide flotation indices of copper oxide ore are obtained. Additionally, ammonium bicarbonate and ethylenediamine phosphate enhanced the sulfide flotation of copper oxide ore, whereas the combined activator agent exhibited a better performance than either individual activator. In addition, to optimize all of the conditions in a more reasonable way, a combination of the 5-11-1 genetic algorithm and back propagation neural network (GA–BPNN) was used to set up a mathematical optimization model. The results of the back propagation neural network (BPNN) model showed that the R2 value was 0.998, and the results were in accordance with the requirement model. After 4169 iterations, the error in the objective function was 0.001, which met the convergence requirements for the final solution. The genetic algorithm (GA) model was used to optimize the BPNN model. After 100 generations, a copper recovery of 87.62% was achieved under the following conditions: grinding fineness of 0.074 mm, which accounted for 91.7%; collector agent dosage of 487.7 g/t; sodium sulfide dosage of 1157.2 g/t; combined activator agent dosage of 537.8 g/t; inhibitor dosage of 298.9 g/t. Using the combined amine and ammonium salt to enhance the sulfide activation efficiency, a GA–BPNN model was used to achieve the goal of global optimizations of copper oxide ore and good flotation indices were obtained.