Identifying Fe3Mn3O8 Phase as the Superior Catalyst for Low-Temperature Catalytic Oxidation of Formaldehyde in Air

This work reports the efficient binary Fe-Mn metal oxide catalysts for low-temperature formaldehyde (HCHO) oxidation in air. The highest catalytic activity was obtained at the molar ratio of Fe/Mn =...

THE ANALYSIS OF ADMISSIBLE LEVEL OF FORMALDEHYDE IN AIR

By production of glued and plate wood-base materials with use of carboamidoformaldehyde pitches (KFS) the main lack of technology of which is toxicity of these materials to the person. Toxicity is caused by allocation from these materials of gas, harmful to the person, - formaldehyde which is cancerogenic substance. Wood-shaving plates from needle (DSTP) and large-size shaving (OSB), fiber boards (DVP) including the Intermediate-density fiberboard (MDF), and also plywood of general purpose and different types of special plywood (decorative, bakelized, etc.), first of all, belong to such materials. The Russian Ministry of Health has established very strict requirements on release of formaldehyde in air both in premises, and in free air the admissible level of which makes (DU) only 0,01 mg/m3 of air when testing materials by chamber method. The plate materials released now can exceed DU of 17 times stated above. Especially it concerns DSTP. Despite attempts of institute Vniidrev through appeals to relevant authorities of the Ministry of Health to increase such admissible level in our country, generally for plate materials, were not crowned with success yet and this level in real time remains in force. It is possible to use such plates in premises only at very small saturation them room void volume (the saturation is defined as the relation of surface area of plates indoors to room void volume). So, by our researches for example it is proved that the written dvukhtumbovy table made of DSTP of class of release of formaldehyde E2 can be established in living room of 20 sq.m only one and no more. Only in this case, at small saturation room void volume plates, the release of formaldehyde in air of the room will meet requirements of domestic DU. In premises the case furniture is in reality with much bigger saturation that leads to room gas contamination formaldehyde. In too time abroad formaldehyde size DU in air much more also makes 0,124 mg/m3 of air. In this regard the purpose of our work consisted in the analysis of DU of formaldehyde in air of foreign researches.

SATURATION RESEARCH MAKSIMALNY BY WOOD-SHAVING PLATES OF PREMISES

The wood-shaving plates (DSTP) released by the domestic industry with use of carboamidoformaldehyde pitches (KFS) have very essential shortcoming connected with their toxicity because of considerable allocation from them gas, harmful to the person, - formaldehyde. In recent years formaldehyde is recognized as substance, cancerogenic for the person. It concerns different type of plates: from needle (DSTP) and large-size shaving (OSB), fiber boards (DVP), including medium-density DP-SP (or MDF). The Russian Ministry of Health has established very strict requirements on release of formaldehyde in air both in premises, and in free air the admissible level of which (DU and maximum-permissible concentration – maximum concentration limit) makes only 0,01 mg/m3 of air when testing materials by chamber method. The plate materials released now can exceed DU of 17 times stated above. Despite attempts of institute Vniidrev through appeals to relevant authorities of the Ministry of Health to increase such admissible level in our country, generally for plate materials, were not crowned with success yet and this level in real time remains in force. It is possible to use such plates in premises only at very small saturation room void volume plates (the saturation is defined as the relation of surface area of plates indoors to room void volume). In foreign practice of DU of formaldehyde in air much higher and makes 0,124 mg/m3 of air. Results of researches of the maximum saturation (the relation of surface area of plates to room volume) depending on class of emission of DSTP and DU formaldehyde at values 0,01 and 0,124 of mg/m3 of air in relation to premises are given in the real work.