This paper deals with polyisobutylene (PIB) migration through post-consumer agricultural waste multilayer films based on four linear low-density polyethylene (LLDPE) matrices. Connections between shear, elongational rheology and tack surface properties were revealed for both model and recycled blends. The effects of aging time and temperature were investigated and rationalized, depending on the short- and long-chain branching in LLDPE matrices as well their polyethylene (PE) crystallization. Linear and nonlinear viscoelastic properties were influenced by even small amounts of PIB. This migration also influenced slippage in the steady-flow regime. Transient uniaxial extensional properties were shown to be very sensitive to the presence of PIB, which seems to hold back the PE strain hardening properties. Therefore, the axial force and the surface friction coefficient were determined and discussed in correlation with bulk rheological findings. These results help unveil new insights about the physical mechanisms governing PIB migration with or without fillers inhibiting this migration in recycled films.
Rheology and tribology: investigating the migration of small molecules in recycled agricultural waste multilayer films
