Trondhjemitic and granitic melts formed by fractional crystallization of an olivine tholeiite from Reykjanes Peninsula, Iceland

A pair of samples, from host lava and an included segregation vein from the Reykjanes Peninsula, Iceland, allows the assessment of a complete fractional crystallization of an olivine tholeiite at low pressure. The final product consists of silicic glasses with bimodal composition: trondhjemitic and more rarely granitic. Compilation of data on major element compositions of Icelandic silicic rocks reveals a clear difference from those of the segregation glasses. Fractional crystallization of basalts at low pressure is therefore not the most likely mechanism for the origin of silicic magmas in Iceland. Similar conclusions have been reached in studies on O- and Th-isotope compositions. On the other hand, the trondhjemitic compositions of the glasses in the segregation vein from Reykjanes Peninsula suggest that fractional crystallization of olivine tholeiites could have played a significant role during the formation of the very early continental crust.

Mineral Chemistry of Leucitites from Visoke Volcano (Virunga Range, Rwanda): Petrogenetic Implications

The Visoke complex is one of the main Quaternary volcanic centres of the Virunga Range, located north of lake Kivu. Mineralogical (microprobe) data are given for two representative leucitite lavas; one sample contains a complex coarse-grained xenolith (phlogopite, diopside, leucite, titanomagnetite, perovskite and apatite) and megacrysts of pyroxene, phlogopite and olivine scattered in fine-grained leucite-rich host lava. Compared with the typical leucite-dominated, low-pressure phenocryst assemblage of the two samples studied, the chemical trends of ferromagnesian crystals suggest an earlier igneous event (high-pressure phenomenon) strongly related to the leucite-bearing magma suite.

Zirconium-rich Sodic Pyroxenes in Felsic Volcanics from the Warrumbungle Volcano, Central New South Wales, Australia

Soda-rich pyroxenes in felsic rocks from the Warrumbungle Volcano, central New South Wales, contain up to 14.5 wt. % ZrO2, which is more than double the previously reported maximum ZrO2 in pyroxene. Zr is believed to enter aegirine as the component Na(Fe2+,Mn,Mg)0.5Zr0.5Si2O6 via the coupled substitution: (Fe2+,Mn,Mg)VI+ZrVI = 2(Fe3+)VI. This component exceeds 50 mol. % in some analyses.Pronounced pyroxene Zr-enrichment is restricted to rocks in which sodic amphibole is the major ferromagnesian mineral, with pyroxene only a minor late-stage phase. The Zr-rich pyroxenes resulted from a combination of host lava peralkalinity, low oxygen fugacity, rapid disequilibrium crystallization and low mobility of the Zr ion. These factors collectively led to the development of interstitial Zr-enriched microdomains in the felsic hosts during their final stages of crystallization.