The Petrology, Geochemistry and Geochronology of Back-Arc Stratovolcanoes in the Southern Kermadec Arc-Havre Trough, SW Pacific

<p>The Kermadec Arc-Havre Trough (KAHT) is widely regarded as a classical example of an intra-oceanic arc-back-arc system, where subduction-driven arc magmatism is focused at the Kermadec volcanic arc-front, and magmatism within the Havre Trough back-arc system results from decompression-related melting. In detail, however, the Havre Trough has not been well-studied, and data for very few lavas have been reported. Recent mapping undertaken in the southern Havre Trough has resulted in the discovery of several prominent submarine stratovolcanoes, Gill Seamount, Rapuhia Seamount and the related Rapuhia Ridge, Yokosuka Seamount, and Giljanes Seamount, situated in the middle of deep rifts and on elevated crustal plateaux. The origin and evolution of these stratovolcanoes is unknown. The first detailed dataset of whole rock major and trace element geochemistry, mineral chemistry, and ⁴⁰Ar/³⁹Ar isotope data, for lavas erupted from these volcanoes is presented here, and used to investigate the processes that drive volcanism in the Havre Trough back-arc. ⁴⁰Ar/³⁹Ar ages obtained from back-arc stratovolcanoes range from ca. 1167 - 953 ka for Gill Seamount, and ca. 107 - 50 ka for Rapuhia Ridge. These ages overlap with known ages for arc-front lavas, indicating that both back-arc and arc-front volcanism are coeval. These ages are all significantly younger than the inferred initation of Havre Trough rifting ca. 5 - 6 Ma. Lavas analysed from Gill Seamount and Rapuhia Ridge are basaltic to basaltic-andesitic in whole rock composition and contain a phenocryst assemblage of olivine ± orthopyroxene + clinopyroxene ± plagioclase. Lavas from Rapuhia Seamount, Yokosuka Seamount and Giljanes Seamount range from andesitic to dacitic in composition, and have a phenocryst assemblage consisting primarily of plagioclase ± clinopyroxene ± amphibole ± Fe-Ti oxides ± apatite. Variations in mineral assemblages and whole rock compositions of the lavas are consistent with crystal fractionation of their respective phenocryst phases. The more evolved compositions of Rapuhia Seamount, Yokosuka Seamount and Giljanes Seamount, all sited on an elevated crustal plateau, are inferred to result from prolonged assimilation + fractional crystallisation (AFC) in the mid- to upper- crust. Mineral compositions provide additional evidence for fractional crystallisation, and most crystals are inferred to have crystallised in equilibrium with their host melt. However, compositions of some olivine phenocrysts in Gill Seamount and Rapuhia Ridge indicate multiple populations of olivine, suggesting their magmatic systems were open to contributions from secondary processes. Variations in Or content in plagioclase crystals for a given lava suite suggests the sample suites crystallised from melts with different starting K₂O compositions. Elevated ratios of Nb/Yb in the mafic Gill Seamount and Rapuhia Ridge lavas indicate the back-arc volcanoes and ridges originated from a less depleted mantle than that present underneath the Kermadec volcanic arc-front, likely a consequence of trenchward advection of mantle within a suprasubduction wedge and/or partial melting of a fusible enriched mantle component. All whole rock samples from these back-arc volcanoes have trace element characteristics that resemble those of typical volcanic arc magmas, indicating that they are variably modified by subducting plate-derived components despite their rear-arc setting. However, the extent of fluid enrichment is less than that at the Kermadec volcanic arc-front. Elevated REE patterns and (La/Sm)N ratios suggest the subduction-component modifying back-arc volcano magmas is dominated by subducting sediment. This sediment component is not consistent with aqueous fluid transfer or bulk mixing, but by the addition of a sediment-derived partial melt with residual accessory phases monazite + zircon + rutile. HFSE/REE fractionated trace element patterns overlap for unmodified basalts from Gill Seamount and Rapuhia Ridge, and Rumble V Ridge back-arc constructional volcanism to the south. This suggests that a similar mechanism triggers constructional back-arc volcanism at both locations in the southern Havre Trough, likely a consequence of thermal anomalies inferred to be present in the mantle wedge (Todd et al. (2011)).</p>

The Petrology, Geochemistry and Geochronology of Back-Arc Stratovolcanoes in the Southern Kermadec Arc-Havre Trough, SW Pacific

<p>The Kermadec Arc-Havre Trough (KAHT) is widely regarded as a classical example of an intra-oceanic arc-back-arc system, where subduction-driven arc magmatism is focused at the Kermadec volcanic arc-front, and magmatism within the Havre Trough back-arc system results from decompression-related melting. In detail, however, the Havre Trough has not been well-studied, and data for very few lavas have been reported. Recent mapping undertaken in the southern Havre Trough has resulted in the discovery of several prominent submarine stratovolcanoes, Gill Seamount, Rapuhia Seamount and the related Rapuhia Ridge, Yokosuka Seamount, and Giljanes Seamount, situated in the middle of deep rifts and on elevated crustal plateaux. The origin and evolution of these stratovolcanoes is unknown. The first detailed dataset of whole rock major and trace element geochemistry, mineral chemistry, and ⁴⁰Ar/³⁹Ar isotope data, for lavas erupted from these volcanoes is presented here, and used to investigate the processes that drive volcanism in the Havre Trough back-arc. ⁴⁰Ar/³⁹Ar ages obtained from back-arc stratovolcanoes range from ca. 1167 - 953 ka for Gill Seamount, and ca. 107 - 50 ka for Rapuhia Ridge. These ages overlap with known ages for arc-front lavas, indicating that both back-arc and arc-front volcanism are coeval. These ages are all significantly younger than the inferred initation of Havre Trough rifting ca. 5 - 6 Ma. Lavas analysed from Gill Seamount and Rapuhia Ridge are basaltic to basaltic-andesitic in whole rock composition and contain a phenocryst assemblage of olivine ± orthopyroxene + clinopyroxene ± plagioclase. Lavas from Rapuhia Seamount, Yokosuka Seamount and Giljanes Seamount range from andesitic to dacitic in composition, and have a phenocryst assemblage consisting primarily of plagioclase ± clinopyroxene ± amphibole ± Fe-Ti oxides ± apatite. Variations in mineral assemblages and whole rock compositions of the lavas are consistent with crystal fractionation of their respective phenocryst phases. The more evolved compositions of Rapuhia Seamount, Yokosuka Seamount and Giljanes Seamount, all sited on an elevated crustal plateau, are inferred to result from prolonged assimilation + fractional crystallisation (AFC) in the mid- to upper- crust. Mineral compositions provide additional evidence for fractional crystallisation, and most crystals are inferred to have crystallised in equilibrium with their host melt. However, compositions of some olivine phenocrysts in Gill Seamount and Rapuhia Ridge indicate multiple populations of olivine, suggesting their magmatic systems were open to contributions from secondary processes. Variations in Or content in plagioclase crystals for a given lava suite suggests the sample suites crystallised from melts with different starting K₂O compositions. Elevated ratios of Nb/Yb in the mafic Gill Seamount and Rapuhia Ridge lavas indicate the back-arc volcanoes and ridges originated from a less depleted mantle than that present underneath the Kermadec volcanic arc-front, likely a consequence of trenchward advection of mantle within a suprasubduction wedge and/or partial melting of a fusible enriched mantle component. All whole rock samples from these back-arc volcanoes have trace element characteristics that resemble those of typical volcanic arc magmas, indicating that they are variably modified by subducting plate-derived components despite their rear-arc setting. However, the extent of fluid enrichment is less than that at the Kermadec volcanic arc-front. Elevated REE patterns and (La/Sm)N ratios suggest the subduction-component modifying back-arc volcano magmas is dominated by subducting sediment. This sediment component is not consistent with aqueous fluid transfer or bulk mixing, but by the addition of a sediment-derived partial melt with residual accessory phases monazite + zircon + rutile. HFSE/REE fractionated trace element patterns overlap for unmodified basalts from Gill Seamount and Rapuhia Ridge, and Rumble V Ridge back-arc constructional volcanism to the south. This suggests that a similar mechanism triggers constructional back-arc volcanism at both locations in the southern Havre Trough, likely a consequence of thermal anomalies inferred to be present in the mantle wedge (Todd et al. (2011)).</p>

Lillooet Glacier basalts, southwestern British Columbia, Canada: products of Quaternary glaciovolcanism

The retreat of Lillooet Glacier (LG) has exposed a succession of pillow basalt and subordinate amounts of breccia and hyaloclastite. The lithofacies and physiographic setting suggest that the deposits have a glaciovolcanic origin and represent a partially dissected basaltic pillow-dominated tindar. Chemically, the LG volcanic rocks are basalt to basaltic andesite, and, as a group, they represent the highest-silica, Quaternary mafic products in the Garibaldi volcanic belt (GVB). Like other northern GVB (alkaline) basalts, they lack the Nb–Ta depletion signature typically associated with subduction-related products. Geochemical and petrologic analysis indicates that the LG basalts are comagmatic and that chemical variations within the suite are consistent with sorting of the observed phenocryst assemblage: olivine + plagioclase. Thermodynamic modeling establishes shallow, crustal, pre-eruptive storage conditions at <2 kbar (1 kbar = 100 MPa; or 7.5 km) and an H2O content of 0.5–1 wt.%. We estimate that the LG basalts were erupted at the peak of, or during the waning stages of, Fraser glaciation (17–13 ka). The eruption produced an englacial lake that was >150 m deep and that appears to have been sustained throughout the entire eruption (i.e., no discernible passage zone). Using hydrostatic constraints, we calculate a minimum overlying paleo-ice thickness of >645 m and a paleo-ice surface elevation of >1895 m above sea level.

Ilímaussaq ‘en miniature’: closed-system fractionation in an agpaitic dyke rock from the Gardar Province, South Greenland (contribution to the mineralogy of Ilímaussaq no. 117)

Based on petrography, mineral chemistry, and petrology, the physico-chemical evolution of an agpaitic dyke was found to be very similar to that of the neighbouring Ilímaussaq complex. Various mineral assemblages were used to reconstruct the crystallization conditions of the dyke rock for different stages during cooling. The early magmatic phenocryst assemblage is alkali feldspar + nepheline + augite + olivine + magnetite and indicates liquidus temperatures of ∼850ºC, silica activities of ∼0.5, and oxygen fugacities of FMQ –1.5 to –3. The groundmass assemblage albite + microcline + nepheline + sodalite + arfvedsonite + aegirine + aenigmatite + astrophyllite indicates lower temperatures of between 600 and 450ºC, at silica activities of 0.25, and oxygen fugacities around the FMQ buffer. Amphibole composition strongly responds to fluorite saturation and proves crystallization occurred in a system closed to oxygen. Late-stage hydrothermal conditions are indicated by the conversion of nepheline and sodalite to analcime and the growth of aegirine on arfvedsonite. These late-stage reactions are constrained to temperatures of <300°C, water activities of between 0.5 and unity, and oxygen fugacities above MH. The dyke has to be regarded as a small equivalent of the larger Ilímaussaq complex, in which identical differentiation processes proceeded at a scale very different in terms of magma volume and cooling times.

Cathodoluminescence Petrography of Middle Proterozoic extrusive carbonatite from Qasiarsuk, South Greenland

The amygdaloidal carbonatite lavas at Qasiarsuk have a primary phenocryst assemblage of calcite, fluor-apatite and magnetite set in a groundmass of calcite, apatite and iron oxides, and minor dolomite. Cathodoluminescence reveals a complex history, both for the major minerals which show zonal growth, and for important Nb and REE accessory phases which include pyrochlore and perovskite. The REE reside in fluor/hydrous-carbonates included exclusively in apatite. These REE minerals are similar to synthetic phases from hydrothermal experiments, but probably crystallised in equilibrium with a late-stage volatile-rich carbonate melt. Apart from low-temperature alteration, the rocks have been little disturbed since their extrusion during the earliest phase of development of the Gardar Alkaline Igneous Province.

Mineral Chemistry of Leucitites from Visoke Volcano (Virunga Range, Rwanda): Petrogenetic Implications

The Visoke complex is one of the main Quaternary volcanic centres of the Virunga Range, located north of lake Kivu. Mineralogical (microprobe) data are given for two representative leucitite lavas; one sample contains a complex coarse-grained xenolith (phlogopite, diopside, leucite, titanomagnetite, perovskite and apatite) and megacrysts of pyroxene, phlogopite and olivine scattered in fine-grained leucite-rich host lava. Compared with the typical leucite-dominated, low-pressure phenocryst assemblage of the two samples studied, the chemical trends of ferromagnesian crystals suggest an earlier igneous event (high-pressure phenomenon) strongly related to the leucite-bearing magma suite.

Zoning in highly alkaline magma bodies

We present chemical data on magmatically heterogeneous pyroclastic deposits of late Quaternary age erupted from zoned magma systems underlying Tenerife (Canary Islands), Sao Miguel and Faial (Azores), and Vesuvius. The most fractionated magmas present at each centre are respectively Na-rich phonolite, trachyte, and K-rich phonolite. Within any one deposit, chemical variation is either accompanied by changes in the phenocryst assemblage (petrographic zonation) or is largely manifested in trace element abundances, unaccompanied by any petrographic change (occult zonation). Zoning is analogous to that in calc-alkaline systems where the most fractionated products are high-silica rhyolites. When a range of magma types are considered, a correlation emerges between roofward depletion of trace elements (especially REE) in the zoned system and compatability of those same trace elements in the accessory phenocryst phases present. Thus, allanite- or chevkinite-bearing rhyolitic systems are light-REE depleted roofwards, the sphene-bearing Tenerife system is middle-REE depleted roofwards, the melanite-bearing Vesuvius system is heavy-REE depleted roofwards, while the Azores systems, which lack these phases, display roofward REE enrichment. Therefore, the behaviour of trace elements may in each case be explained by fractionation of observed phenocryst assemblages. The resemblance between features of zoned magma systems and published work on the dynamic consequences of cooling saturated aqueous solutions prompts us to suggest that sidewall crystallization and consequent boundary-layer uprise to form a capping layer at top of the system may be a plausible mechanism for the generation of both petrographic and occult zonation. Reverse zoning occurs among the first-erupted tephra of some deposits, demonstrating that the most highly differentiated magma available is not always the first to be tapped during an eruption from a zoned system.