Hydrogen Bonds: Raman Spectroscopic Study

The work outlines general ideas on how the frequency and the intensity of proton vibrations of X–H×××Y hydrogen bonding are formed as the bond evolves from weak to maximally strong bonding. For this purpose, the Raman spectra of different chemical compounds with moderate, strong, and extremely strong hydrogen bonds were obtained in the temperature region of 5 K–300 K. The dependence of the proton vibrational frequency is schematically presented as a function of the rigidity of O-H×××O bonding. The problems of proton dynamics on tautomeric O–H···O bonds are considered. A brief description of the N–H···O and C–H···Y hydrogen bonds is given.

Thin current sheets as key structures in space plasma

<p>Plasma structures with extremely small transverse size (named thin current sheets or TCSs) have been discovered and investigated by spacecraft observations in the Earth's magnetotail, then in other planetary magnetospheres and the solar wind. Their formation is related with complicated dynamic processes in collisionless space plasma near the magnetic reconnection regions. The proposed models describing TCSs in space plasma, based on the assumption of a quasi-adiabatic proton dynamics and magnetized electrons were successful. Various modifications of the initial equilibrium allowed describing such current sheets as the system of current sheets where the central sheet is supported by magnetized electron drifts, and the external sheets are supported by quasi-adiabatic protons and sometimes oxygen ions. Such current configurations are shown to have properties that are completely different from the well-known Harris model, particularly the multiscale structure, embedding and metastability. The structure and evolution of TCSs under the tearing mode as well as the related paradox of complete tearing mode stabilization in configurations with a nonzero normal magnetic field component is highlighted.</p><p>This work is supported by the Russian Science Foundation grant № 20-42-04418.</p>