Preliminary Study of Scandium Enrichment in Lateritic Profile from Weathered Ultramafic Rock in Lapaopao Area Kolaka Regency of Southeast Sulawesi

Scandium is one of the rare earth elements which is currently widely used for various needs such as the aerospace industry, solid oxide fuel cells, electronics industry and in metallurgical applications. Generally, Scandium appears in small amounts so its structural role in the host minerals cannot be readily identified. Some studies reported the scandium extraction from lateritic nickel deposit where may contain considerable amount of scandium in addition to nickel and cobalt. Preliminary research of scandium enrichment has been investigated from the ultramafik rock indicates that an enrichment of scandium concentration was found in the red limonite. The aim of this study was to investigate the potentially enrichment of scandium mineral from nickel laterite in Lapaopao Area. There are a total of 38 samples from 1 (one) diamond drill holes which represent the limonite, saprolite and bedrock profiles have been collected and studied to investigate the distribution pattern of Sc grades within the lateritic profile. These samples are being analized by XRF for major and minor element and ICP-OES method for rare earth element assaying. The study has confirmed that scandium is enriched in limonite layer of weathered ultramafic laterite profile. The scandium content from the ultramafic bedrock is 15 ppm and has enriched until 81 ppm of scandium in the limonite layer.

The Loma de Hierro Ni-laterite deposit (Venezuela): Mineralogical and chemical composition

Nickel laterite deposits developed on ultramafic rocks have traditionally been a significant source of Ni and Co and recently of Sc. Although the Loma de Hierro deposit (Venezuela) has been in operation for more than 50 years, it lacks detailed studies on the mineralogical and geochemical composition of the lateritic profile. In this study, we present a geochemical and mineral description of the main carrier phases of Ni and Co in a complete profile of the deposit. The selected weathering profile has been developed from a partially serpentinized harzburgitic protolith and has a well-developed saprolitic horizon covered by a thin limonitic horizon. The geochemical signature of the profile is characterized by a significant Mg and Si decrease towards the top of the saprolite, with a clearly visible Mg discontinuity. The main Ni-bearing minerals are secondary serpentine (1–4 wt.% NiO) and kerolite-pimelite-dominated garnierite mixtures with serpentine (18–22 wt.% NiO). Limonite is rich in goethite (0–1.85 wt. % NiO), gibbsite, and Mn-oxy-hydroxides. The latter have intermediate compositions between lithiophorite and asbolane (2–13 wt.% CoO). The highest Sc grades (40–68 ppm) were observed in the limonite with amounts positively correlated with Fe content. Rare earth elements are mainly concentrated in the upper part of the saprolite horizon (60–80 ppm), while they have a lower content in the limonite (7–45 ppm). In this horizon, rare earth elements are clearly associated with Fe, indicating adsorption and/or coprecipitation. This association was not observed in the saprolite, suggesting that other minerals (e.g., clay minerals) are controlling their concentration; more information is needed to identify the rare earth element-bearing minerals. The lateritic profile of Loma de Hierro can be classified as representative of hydrated Mg silicate deposits, and was formed in a context of continuous tectonic uplift and a low water table conditions favoring the development of a thick saprolitic horizon and the precipitation of kerolite-pimelite-dominated garnierites.

GEOELECTRICAL SIGNATURES AND THEIR RELATIONSHIPS WITH THE LATERITIC HORIZONS: A CASE STUDY OF THE N4EN MINE’S IRON CAVE, CARAJÁS COMPLEX, BRAZIL

ABSTRACT The Brazilian speleological heritage is protected by laws, and every region where caves are present requires scientific studies to assist in environmental licensing. In the context of mining in iron formations, the near-surface geophysical studies using electroresistivity survey were performed in the cave N4E-0022, located at the N4EN iron mine, Carajás Complex, northern Brazil. The near-surface geophysical surveys generated continuous images that enhanced the lithostructural mapping of the lateritic profile, especially in places to which access by conventional methods was difficult. The electrical resistivity profiles were acquired with the dipole-dipole arrangement in the upper portion of the cave. Three sections were performed in SW-NE direction and two in SE-NW direction, totaling 435 meters of acquisition. The geoelectrical signatures were correlated with the lithologic logs of drillholes, the geophysical well logging and with the typical lateritic profile in the cave N4E-0022 surroundings. The results showed a satisfactory interpretation for the near-surface geoelectrical profiles and evolved to a comparison with the lateritic profile (lateritic crust, transition horizon, and saprolite horizon), providing inherent resistivity signatures for each modeled material.Keywords: applied geophysics, iron cave, Carajás.RESUMO O patrimônio espeleológico brasileiro é protegido por leis, e qualquer região com a presença de cavidades precisa de estudos científicos para auxiliar o licenciamento de empreendimentos. No contexto da mineração em terrenos ferríferos, estudos geofísicos rasos utilizando eletrorresistividade foram executados na cavidade N4E-0022, localizada no extremo norte da Mina de N4EN, Complexo Carajás. A geofísica rasa gerou imagens contínuas que potencializaram o mapeamento lito-estrutural do substrato rochoso, principalmente em locais de difícil acesso aos métodos convencionais. Os perfis de eletrorresistividade foram adquiridos com arranjo dipolo-dipolo na porção superior da cavidade. de modo paralelo entre si na porção superior da cavidade. Três seções foram executadas na direção SW-NE e duas na direção SE-NW, totalizando 435 metros de aquisição. As assinaturas geoelétricas das seções foram correlacionadas com as descrições litológicas de furos de sondagem, perfilagens geofísicas de furos de sonda e o mapeamento de detalhe do perfil laterítico no entorno da cavidade N4E-0022, evidenciando um resultado satisfatório para as interpretações realizadas. Os resultados evoluíram para uma comparação com o perfil de alteração típico de rochas ferruginosas (crosta laterítica, horizonte de transição e saprolito), e forneceram assinaturas de resistividades inerentes à cada material modelado. Palavras-chave: geofísica aplicada, caverna ferrífera, Carajás.

Unique role of pore water in lateritic bauxite formation, Republic of Guinea

Results of the hydrogeochemical study of bauxite-bearing lateritic mantles of the Futa Djallon-Mandingo Province, West Africa, have allowed us to first characterize the pore water of vadose and infiltration hydrogeological zone. Abundances of major components (aluminum and iron) of the water are shown to be few orders higher than are those typical of the other waters of lateritic mantles. The pore water is proved to be a major factor of matter redistribution over any bauxite-bearing lateritic profile.

CLAY MINERALOGY OF THE SEDIMENTARY IRON-NICKEL ORE OF AGIOS IOANNIS, NE BOEOTIA: NEW DATA AND IMPLICATION FOR DIAGENETIC MODIFICATIONS Christidis G.

The clay mineralogy of the sedimentary Fe-Ni deposit of Agios Ioannis and a Ni lateritic profile from Pavlos, both in Lokris area, Greece, is investigated. The clay fraction of samples from Agios Ioannis consists mainly of Fe-rich chlorite and Fe-smectite, with minor serpentine, hematite and goethite. Locally, disordered talc (kerolite and/or pimelite), illite, R1 mixed layer illite/smectite and gibbsite are identified. The lateritic profile has different composition and contains mainly Fe-rich smectite (nontronite and/or ferruginous montmorillonite) with minor serpentine, goethite, magnetite, and talc, whereas chlorite is absent. It is suggested that in the Agios Ioannis deposit chlorite has formed from smectite via R0 mixed layer chlorite/smectite with >80% chlorite layers. The source of Al is probably the diagenetic transformation of pedogenic goethite to hematite during burial. The lack of chlorite in the lateritic profile of Pavlos is attributed to the limited presence of goethite. Smectite is believed to be a major mineralogical constituent of the Fe-Ni ores of the broader Lokris area.