Basalt derived from highly refractory mantle sources during early Izu-Bonin-Mariana arc development

The magmatic character of early subduction zone and arc development is unlike mature systems. Low-Ti-K tholeiitic basalts and boninites dominate the early Izu-Bonin-Mariana (IBM) system. Basalts recovered from the Amami Sankaku Basin (ASB), underlying and located west of the IBM’s oldest remnant arc, erupted at ~49 Ma. This was 3 million years after subduction inception (51-52 Ma) represented by forearc basalt (FAB), at the tipping point between FAB-boninite and typical arc magmatism. We show ASB basalts are low-Ti-K, aluminous spinel-bearing tholeiites, distinct compared to mid-ocean ridge (MOR), backarc basin, island arc or ocean island basalts. Their upper mantle source was hot, reduced, refractory peridotite, indicating prior melt extraction. ASB basalts transferred rapidly from pressures (~0.7-2 GPa) at the plagioclase-spinel peridotite facies boundary to the surface. Vestiges of a polybaric-polythermal mineralogy are preserved in this basalt, and were not obliterated during persistent recharge-mix-tap-fractionate regimes typical of MOR or mature arcs.

Basalt derived from highly refractory mantle sources during early Izu-Bonin-Mariana arc development

The character of magmatism associated with the early stages of subduction zone and island arc development is unlike that of mature systems, being dominated in the Izu-Bonon-Mariana (IBM) case by low-Ti-K tholeiitic basalts and boninites. Basalts recovered by coring the basement of the Amami Sankaku Basin (ASB), located west of the oldest remnant arc of the IBM system (Kyushu-Palau Ridge; KPR), were erupted at ~49 Ma, about 3 million years after subduction inception. The chain of stratovolcanoes defined by the KPR is superimposed on this basement. The basalts were sourced from upper mantle similar to that tapped following subduction inception, and represented by forearc basalt (FAB) dated at ~52-51 Ma. The mantle sources of the ASB basalt basement were more depleted by prior melt extraction than those involved in the vast majority of mid-ocean ridge (MOR) basalt generation. The ASB basalts are low-Ti-K, aluminous spinel-olivine-plagioclase-clinopyroxene-bearing tholeiites. We show this primary mineralogy is collectively distinct compared to basalts of MOR, backarc basins of the Philippine Sea Plate, forearc, or mature island arcs. In combination with bulk compositional (major and trace element abundances plus radiogenic isotope characteristics) data for the ASB basalts, we infer the upper mantle involved was hot (~1400oC), reduced, and refractory peridotite. For a few million years following subduction initiation, a broad region of mantle upwelling accompanied by partial melting prevailed. The ASB basalts were transferred rapidly from moderate pressures (1-2 GPa), preserving a mineralogy established at sub-crustal conditions, and experienced little of recharge-mix-tap-fractionate regimes typical of MOR or mature arcs.

The sapphirine-bearing rocks in contact with the Lherz peridotite body: New mineralogical data, age and interpretation

Sapphirine-bearing rocks are described in the Aulus Basin (Ariège, France) in a contact zone between the Lherz peridotitic body and Mesozoic metasediments which underwent the Pyrenean Cretaceous high-temperature, low-pressure metamorphic event (Monchoux, 1970, 1972a, 1972b). Sapphirine crystals occur in layered clastic deposits characterized by an uncommon suite of Al-Mg-rich minerals. A detailed petrographic study of sixteen samples representative of the diversity of the Lherz sapphirine-bearing rocks is presented. These rocks include breccias and microbreccias with various compositions. Some samples are composed of polymineralic clasts and isolated minerals that derive from regionally well-known protoliths such as ultramafic rocks, meta-ophites, “micaceous hornfels”, and very scarce Paleozoic basement rocks. Nevertheless, a large portion of the sapphirine-bearing clastic suite is composed of mono- and polymineralic debris that derive from unknown protolith(s). We define a "sapphirine-bearing mineral suite” (SBMS) composed of monomineralic debris including: sapphirine + enstatite + aluminous spinel + Mg-amphiboles + Ca-amphiboles + kornerupine + accessory minerals (apatite, diopside, rutile, serpentine, smectite, tourmaline, vermiculite and a white mica). We highlight the dominance of metamorphic Keuper clastic materials in the studied rocks and the presence of inclusions of anhydrite and F-, Cl-, Sr-rich apatite in minerals of the Al-Mg-rich suite. The brecciated texture and the presence of unequivocal sedimentary features suggest that the sapphirine-bearing rocks were mechanically disaggregated and then experienced winnowing in underwater conditions with poor mixing between the different sources. We measured U-Pb rutile age data in order to provide constraints on the age of (one of) the protolith(s) of those clastic deposits. The obtained age (98.6 + 1.2 Ma) is interpreted as the age of metamorphism of this protolith of the SBMS. Previous works interpreted the Lherz sapphirine-bearing rocks as crustal protoliths modified at depth along the contact with the ultramafic rocks of the Lherz body during their ascent towards shallower depths. These new data imply: (i) an Upper Triassic to Lower Jurassic origin for the main protolith of the sapphirine-bearing rocks; (ii) the metamorphism of this protolith along an active hot crust–mantle detachment during Cenomanian times with the involvement of metasomatic, brine-type fluids; and (iii) its brecciation during the exhumation of the material due to the evolution of the detachment, followed by subsequent sedimentary reworking of the metamorphic material.

The Tertiary lavas and sediments of northwest Rhum, Inner Hebrides

Several small outliers of Tertiary lavas and sediments rest with strong unconformity on a buried landscape eroded from Torridonian sediments and Tertiary granophyre. Erosion continued during the period of sediment and lava accumulation. Four formations are recognized; these are, in order of increasing age, the Orval Formation (hawaiite and basaltic hawaiite lavas), the Guirdil Formation (icelandite lavas, interbedded conglomerates), the Upper Fionchra Formation (tholeiitic basaltic andesite lavas, hyaloclastite deposits, basal conglomerate) and the Lower Fionchra Formation (alkali and transitional basalt, basaltic hawaiite and hawaiite lava flows, basal conglomerate); each is separated by an erosional interval. Clasts in the conglomerates reveal a history of erosion of a terrain exposing gneisses, Torridonian sediments, igneous rocks derived from the Rhum Tertiary Central Complex (including allivalites), and Tertiary lavas of local origin but also including, in the oldest conglomerates, tholeiitic basalts not now preserved on or near Rhum. Prior to and during lava and sediment accumulation, erosion on Rhum had cut down to a level similar to that of the present day, although not to the extent that high-grade thermally altered rocks, which are a marked feature of the Central Complex, were being eroded in any quantity. A sequence of east–west trending valleys, possibly initiated on the line of the earlier Main Ring Fault, drained the area of the Central Complex which then, as now, must have been high ground. Small lakes occasionally formed in the valleys allowing the accumulation of fine-grained sediment with plant remains, and promoting the formation of hyaloclastite deposits when buried by later flows. No source for any of the lava formations is preserved on Rhum; they are thought to have come from feeders north of Rhum, possibly near Canna, and to have ponded against the hills and valleys near and in the Central Complex.The oldest tholeiitic lavas, not now found in situ, were followed by alkali and transitional flows compositionally similar to the Skye Main Lava Series but characteristically feldsparphyric; the most mafic also contain phenocrysts of magnesian olivine (with included Cr-Al-rich spinels) and aluminous spinel. Both the early alkalic/transitional basalts and the youngest hawaiites and basaltic hawaiites equilibrated at pressures < 9 kb; the tholeiitic basaltic andesites and icelandites equilibrated at relatively shallows depths.Apart from a few N–S to NW–SE-trending basalt dykes, the lava formations represent the youngest Tertiary igneous event on Rhum.

Garnet-olivine reaction in the upper mantle: evidence from peridotite xenoliths in the Letseng-la-Terae kimberlites, Lesotho

ABSTRACTGarnet-bearing xenoliths from Letseng-la-Terae display a range of textures from coarse to granuloblastic. Equilibration temperatures and pressures of primary phases are in the ranges 950-1400°C and 27-50 kb, respectively. Deformed lherzolites equilibrated throughout this temperature range but coarse xenoliths are restricted to low temperature equilibration.All garnets display coronas developed during the reaction:In some rocks, reaction has completely eliminated garnet.In rocks where garnet is disrupted, the corona minerals are strung out in the fluidal texture indicating that reaction occurred before deformation. Rocks transitional to, and of granuloblastic texture, contain garnet and aluminous spinel; in addition ‘pools’ of minerals originating by dynamic separation of corona fragments are observed.Chemical comparison between the corona minerals and minerals in a garnet-spinel rock and two spinel granuloblastites, suggests that these spinel-bearing rocks may be derived from normal garnet peridotite by a complex sequence of reaction, followed by deformation, annealing and chemical homogenisation. The conclusion that reaction and deformation took place at high levels in the upper mantle is contrary to some earlier hypotheses of shearing within the low velocity zone in response to continental plate movement, but is consistent with mantle diapir models.

Chromite-chlorite intergrowths in peridotite at Chimwadzulu Hill, Malawi

SummaryChromiferous spinel and chlorite are associated and sometimes intergrown in serpentinized peridotites at Chimwadzulu Hill. The peridotites probably crystallized from a melt under the conditions of the spinel-lherzolite facies (O'Hara, 1967) in which the stable aluminous phase is spinel. The spinel that formed was probably a chromite with some Al2O3 and MgO. At lower temperatures aluminous spinel is unstable in the presence of olivine and orthopyroxene, chlorite being the stable aluminous mineral. It is thought that the chlorite crystallized under the conditions of medium-grade metamorphism that prevailed when the rocks were emplaced, and at the same time the spinel recrystallized, depleted in Al2O3 and MgO and correspondingly enriched in FeO, Fe2O3, and Cr2O3, giving rise to the observed chromite-chlorite association.

Spinels from the Dawros Peridotite, Connemara, Ireland

SummaryTwo different spinels, analyses of which are given, occur in the layered ultramafic rocks at Dawros. Chrome spinel occurs both as gravity-stratified cumulates and as complex orbs, while an Al-rich spinel is both in rocks of the main Dawros magmatic sequence and in an association with an aluminous bronzite, which may originate by recrystallization. It is concluded that while the chrome spinel is certainly of magmatic origin, the aluminous spinel is probably partly of magmatic and partly of recrystallization origin.