Petrology of Mafic Dykes from the Njimom Area (West-Cameroon): A Contribution to the Characterization of Late Paleozoic and Mesozoic Magmatism in the Southern Continental Part of the Cameroon Volcanic Line

In the western Cameroon, crop out several dyke swarms of Paleozoic–Mesozoic age. These dykes intrude the Precambrian basement in the southern continental part of the Cretaceous Cameroon Volcanic Line. In the Njimom area, two groups of mafic dykes that crosscut the Neoproterozoic basement rocks have been observed. A first group intrudes the mylonites whereas the second group intrudes the granites. The dykes are alkaline basalts and hawaiites. The mineralogical assemblage of both groups of dykes consists of plagioclase, clinopyroxene, altered olivine, and opaque oxides. The dykes that cross-cut the Precambrian mylonitic gneisses show moderate TiO2 (1.7–2.0 wt.%), low MgO (4.4–7.1 wt.%), and compatible trace element concentrations (e.g., Cr = 70–180 ppm; Ni = 30–110 ppm). The dykes that intrude the granites have TiO2 contents between 2.3 and 2.5 wt.% and moderate compatible trace element concentrations (e.g., Cr = 260–280 ppm; Ni = 170–230 ppm). MgO varies from 5.9 to 9.2 wt.%. All mafic dykes are enriched in light lanthanide element and show moderate Zr/Nb and high Zr/Y, Nb/Yb, and Ti/V ratios similar to those of average ocean island basalt (OIB)-type magmas. Some dykes that intrude the mylonites show evidence of contamination by continental crust. The composition of the clinopyroxenes of the dykes that intrude the mylonites clearly indicate different and unrelated parental magmas from dykes that intrude the granites. Contents and fractionation of the least and the most incompatible elements suggest low degrees of partial melting (3–5%) of heterogeneous source slightly enriched in incompatible elements in the spinel stability field. The geochemical features of Njimom dykes (in particular the dykes that intrude the granites) are similar to those of Paleozoic and Mesozoic dykes recorded in the southern continental part of the Cameroon Volcanic Line, suggesting multiple reactivations of pre-existing fractures that resulted in the fragmentation of western Gondwana and the opening of the South Atlantic Ocean.

Cretaceous Granitic Magmatism in South-Central Vietnam: Constraints from Zircon U–Pb Geochronology

South-central Vietnam abundantly presents magmatic rocks with larger volumes ofCretaceous granitic rocks. In this study, zircon U–Pb geochronology of granite samples from the Deoca,Ankroet, and Dinhquan complexes in south-central Vietnam are utilized to investigate Cretaceousgranitic magmatism. According to U–Pb analysis results, zircon ages of granitic rocks display the Deocaat ~113–92 Ma, the Ankroet at ~103–98 Ma, and the Dinhquan at ~97–113 Ma. The range of ages isnarrow from 113 to 92 Ma, with most common ages date at ~100 Ma. Published data and our resultsdisplay that Cretaceous granitic magmatism was active between ~87–118 Ma and most active at ~100Ma in south-central Vietnam. Additionally, the Deoca and Dinhquan complexes show inherited ages inTriassic followed by Proterozoic and Carboniferous to Ordovician. The obtained ages indicate that Itypegranitic rocks could be derived from melting of basement rocks. Our study suggests that I-typegranitic rocks in south-central Vietnam were significantly intruded around 100 Ma.

Fluids sources in basement-hosted unconformity-uranium ore systems: tourmaline chemistry and boron isotopes from the Patterson Lake corridor deposits, Canada

The Patterson Lake corridor is a new uranium district located on the southwestern margin of the Athabasca Basin. Known resources extend almost one kilometer below the unconformity in graphite- and sulfide-bearing shear zones within highly altered metamorphic rocks. Despite different host rocks and greater depths below the unconformity, alteration assemblages (chlorite, illite, kaolinite, tourmaline and hematite), ore grades and textures are typical of unconformity-related deposits. This alteration includes at least three generations of Mg-rich tourmaline (magnesio-foitite). The boron isotopic composition of magnesio-foitite varies with generation: the earliest generation only observed in shallow samples from the Triple R deposit (Tur 1) contain the heaviest isotopic signature (δ11B ≈ +26 to +19 ‰), whereas subsequent generations (Tur 2, Tur 3) yield lighter and more homogeneous isotopic signatures (δ11B ≈ +17.5 to +19.9 ‰). These results are consistent with precipitation from low temperature, NaCl- and CaCl2-rich brine(s) derived from an isotopically heavy boron source (e.g. evaporated seawater) that interacted with tourmaline and silicates in the basement rocks and/or fluids derived from depth (with low δ11B values). The lower δ11B values in paragenetically later magnesio-foitite reflect greater contributions of basement-derived boron over time whereas minor compositional variations reflect local metal sources (e.g. Cr, V, Ti) and evolving fluid chemistry (decreasing Na and Ca, increasing Mg) over time. The δ11B and chemical variation in magnesio-foitite over time reinforce the strong interactions with basement rocks in these systems while supporting incursion of basinal brines well below the unconformity contact.Thematic collection: This article is part of the Uranium Fluid Pathways collection available at: https://www.lyellcollection.org/cc/uranium-fluid-pathwaysSupplementary material:https://doi.org/10.6084/m9.figshare.c.5727555

Reuniting the Ötztal Nappe: the tectonic evolution of the Schneeberg Complex

The Ötztal Nappe in the Eastern Alps is a thrust sheet of Variscan metamorphic basement rocks and their Mesozoic sediment cover. It has been argued that the main part of the Ötztal Nappe and its southeastern part, the Texel Complex, belong to two different Austroalpine nappe systems and are separated by a major tectonic contact. Different locations have been proposed for this boundary. We use microprobe mapping of garnet and structural field geology to test the hypothesis of such a tectonic separation. The Pre-Mesozoic rocks in the area include several lithotectonic units: Ötztal Complex s.str., Texel Complex, Laas Complex, Schneeberg Complex, and Schneeberg Frame Zone. With the exception of the Schneeberg Complex which contains only single-phased (Eoalpine, i.e. Late Cretaceous) garnet, all these units have two-phased garnet with Variscan cores and Eoalpine rims. The Schneeberg Complex represents Paleozoic sediments with only low-grade (sub-garnet-grade) Variscan metamorphism which was thrust over the other units and their Mesozoic cover (Brenner Mesozoic) during an early stage of the Eoalpine orogeny, before the peak of Eoalpine metamorphism and garnet growth. Folding of the thrust later modified the structural setting so that the Schneeberg Thrust was locally inverted and the Schneeberg Complex came to lie under the Ötztal Complex s.str. The hypothesized Ötztal/Texel boundaries of earlier authors either cut across undisturbed lithological layering or are unsupported by any structural evidence. Our results support the existence of one coherent Ötztal Nappe, including the Texel Complex, and showing a southeastward increase of Eoalpine metamorphism which resulted from southeastward subduction.

Interaction between Microbes, Minerals, and Fluids in Deep-Sea Hydrothermal Systems

The discovery of deep-sea hydrothermal vents in the late 1970s widened the limits of life and habitability. The mixing of oxidizing seawater and reduction of hydrothermal fluids create a chemical disequilibrium that is exploited by chemosynthetic bacteria and archaea to harness energy by converting inorganic carbon into organic biomass. Due to the rich variety of chemical sources and steep physico-chemical gradients, a large array of microorganisms thrive in these extreme environments, which includes but are not restricted to chemolithoautotrophs, heterotrophs, and mixotrophs. Past research has revealed the underlying relationship of these microbial communities with the subsurface geology and hydrothermal geochemistry. Endolithic microbial communities at the ocean floor catalyze a number of redox reactions through various metabolic activities. Hydrothermal chimneys harbor Fe-reducers, sulfur-reducers, sulfide and H2-oxidizers, methanogens, and heterotrophs that continuously interact with the basaltic, carbonate, or ultramafic basement rocks for energy-yielding reactions. Here, we briefly review the global deep-sea hydrothermal systems, microbial diversity, and microbe–mineral interactions therein to obtain in-depth knowledge of the biogeochemistry in such a unique and geologically critical subseafloor environment.

Physical Property Characterization of the Waipapa Greywacke: An Important Geothermal Reservoir Basement Rock in New Zealand

Greywacke basement rocks in New Zealand host conventional geothermal reservoirs and may supply important hotter and deeper geothermal energy resources in the future. This work combines petrological analyses and physical property measurements of Waipapa greywacke, a basement unit hosting New Zealand geothermal reservoirs, in order to understand better how structurally controlled flow networks develop and channel geothermal fluids within it. Results show intact Waipapa greywacke has high tensile and triaxial compressive strengths, and low intrinsic permeability (~10-21 m2). Permeability of intact Waipapa greywacke does not increase significantly during triaxial loading to failure and is accompanied by minimal changes ultrasonic wave velocities. These data taken together suggest that microcrack development during brittle deformation is very limited. Upon failure, the permeability increases by two orders of magnitude and shows similar permeability to tests performed on synthetic, single, mode I fractures in intact Waipapa greywacke. Permeability persists in Waipapa greywacke fractures under confining pressures of at least 150 MPa. It is concluded that Waipapa greywacke rocks will not allow fluid flow through the matrix of the rock and that substantial geothermal fluid flow will only occur through macrofracture networks.

Thermo-tectonic studies of Mesozoic basement rocks, North Island, New Zealand

<p>The basement rocks of North Island, New Zealand, comprise metasedimentary terranes that were accreted onto the eastern Gondwana margin during Mesozoic subduction. Since the Oligocene, these terranes have been sitting at the leading edge of the Australian Plate, as the hanging wall of the Hikurangi subduction margin, overriding the subducting Pacific Plate. This thesis examines the thermo-tectonic histories of the basement rocks in North Island, using fission-track and (U-Th-Sm)/He thermochronology. In eastern North Island, thermochronological data from the basement rocks record the exhumation histories since the latest Jurassic, related to two subduction cycles. Zircon fission-track analysis yields detrital or slightly reset ages (264–102 Ma); apatite fission-track ages range from 122 to 7.9 Ma and (U-Th-Sm)/He from 33.3 to 6.0 Ma. In central North Island, modelled thermal histories suggest that the basement rocks were exhumed to shallow levels (<2 km) of the crust in the Early Cretaceous (~150–135 Ma). This was followed by a period of reheating until ~100 Ma, which is interpreted to be the result of burial by sedimentation above the accretionary wedge. From 100 Ma, models indicate thermo-tectonic quiescence until the Late Oligocene. During the late Cenozoic, exhumation of the basement rocks accelerated at ~27 Ma in the western margin of the axial ranges (Kaimanawa Mountains). This acceleration in exhumation rate is interpreted to reflect the initiation of the subduction of the Pacific Plate beneath central North Island. Since the Late Oligocene, basement exhumation in the axial ranges migrated towards the trough. Modelled thermal histories indicate significant eastwards reverse faulting on the margin-parallel Ngamatea Fault between ~27 and 20 Ma and on the Wellington-Mohaka Fault between ~20 and 10 Ma. In contrast to the activity in the axial ranges, in western North Island, the exhumational response of the basement rocks to the Cenozoic subduction was less significant and not revealed from the present thermochronological data. Since the Late Miocene, the exhumation rate in the axial ranges has varied significantly along-strike, lower in the centre and higher to the north and south. During the last 10 Myr, the total magnitude of exhumation has been ~4 km in the Wellington region in the south, >1 km in the Raukumara Range in the north and negligible (less than a few hundred metres) in the central axial ranges in the Hawke’s Bay region. Although the accumulation of underplated material at the basal upper plate may have contributed to the localised rock uplift and exhumation (e.g. in the Raukumara Range), margin-normal shortening of the upper plate in the forearc of the Hikurangi Margin has most likely dominated the unroofing process of the axial ranges. In northwestern North Island, the Northland Allochthon, an assemblage of Cretaceous–Oligocene sedimentary rocks, was emplaced during the Late Oligocene–earliest Miocene, onto in situ Mesozoic and early Cenozoic rocks. Detrital zircon and apatite fission-track ages reveal that the basal Northland Allochthon sequences and the underlying Miocene autochthonous sedimentary rocks were predominantly derived from the local Jurassic terrane (Waipapa Supergrop) and perhaps the Late Cretaceous volcanics. In addition, the Early Miocene autochthon contains significant sedimentary influx from the Late Oligocene volcanics related to the subduction initiation in northern New Zealand. Zircon and apatite fission-track data from the in situ Mesozoic basement were inverted using thermo-kinematic models coupled with an inversion algorithm. The results suggest that during the Late Oligocene, ~4–6 km thick nappes were emplaced onto the in situ rocks in the northernmost Northland region. Prior to basement unroofing in the Early Miocene, the nappes thinned towards the south. Following allochthon emplacement, eastern Northland was uplifted and unroofed rapidly over a period of ~1–6 Myr, leading to ~0.4–1.5 km erosion of the allochthon. Since the mid-Miocene, due to the decline in tectonic activity in this region, the Northland Allochthon and the underlying rocks have been eroded slowly. This thesis has documented variable exhumation and burial processes that occurred in the upper plates of both the Mesozoic Gondwana and late Cenozoic Hikurangi subduction margins. The results provide the foundation for future studies to investigate the kinematics and mechanism of the crustal exhumation and deformation of the North Island basement in further detail.</p>