Analysis of the Dispersion of Viscoelastic Clusters in the Industrial Rotor-Stator Equipment

Materials with complex rheology and viscoelasticity may require special equipment for processing, such as for dispergation. Rheological and mechanical data of the material can help with finding the required equipment or designing equipment. For highly viscous and complex material, a rotor-stator mixer can be a good choice for dispergation. Due to the laminar or creeping mechanism of flow inside the equipment, the dispergation mechanism is assumed to be a combination of the shear stress and slicing of the material by the rotor and stator blades. For the validation of the theory, the mechanical properties of the viscose identified in a previous work were used for comparison with the data from the CFD simulation of the rotor-stator mixer. The comparison showed that the rotor-stator device can overcome the complex shear modulus and ultimate strength of the material and homogenize the solution through a combination of the shear stress and slicing. The theory was also confirmed on the process line proposed for homogenization of the specific material. The stability of viscosity during the process of homogenization was measured and used as the main parameter for quality assessment.

Colloidal Probes of PNIPAM-Grafted SiO2 in Studying the Microrheology of Thermally Sensitive Microgel Suspensions

The complex rheology and the phase behavior of thermally sensitive poly(N-isopropylacrylamide) (PNIPAM) microgels have been investigated in both the swollen and collapsed states by using microrheology. To avoid the interactions between the tracer probes and the PNIPAM microgels, such as the adsorption or the depletion effect, the probes of silica (SiO2) particles have been grafted with PNIPAM chains (SiO2-PNIPAM) and characterized with Fourier transform infrared spectroscopy (FTIR). The successful preparation of SiO2-PNIPAM has also been proved by the investigation of the particle size and morphology with dynamic light scattering (DLS) and transmission electron microscope (TEM) below and beyond the phase transition temperature of PNIPAM. The microrheology of the PNIPAM microgel suspension has been investigated by using the prepared SiO2-PNIPAM particles as microrheological probes, and the results show that the diffusive coefficient of the probes in the swollen state is one-fifth of that in the collapsed state, and the viscosity of the PNIPAM microgel suspension in the swollen state is four times higher than that in the collapsed state, indicating SiO2-PNIPAM is a good probe in the microrheological study of PNIPAM microgel suspensions.