Nature and evolution of the northern Victoria Land lithospheric mantle (Antarctica) as revealed by ultramafic xenoliths

A review of northern Victoria Land ultramafic xenoliths, collected and studied over more than 30 years, was carried out. More than 200 samples were gathered and characterized in a coherent and comparative manner, both for mantle-derived and cumulate xenoliths. Almost 2000 analyses of major elements and more than 300 analyses of trace elements of in situ and separated olivine, pyroxenes, amphibole, spinel and glass were taken into consideration. Particular attention was devoted to mantle lithologies in order to emphasize the composition and the evolution of this portion of the subcontinental lithosphere. The three main localities in northern Victoria Land where mantle xenoliths were found (i.e. Mount Melbourne (Baker Rocks), Greene Point and Handler Ridge), over a >200 km distance, were described and compared with ultramafic xenoliths in three other localities (Harrow Peaks, Browning Pass and Mount Overlord) that are mainly cumulate in nature. Altogether, these data enabled us to reconstruct a long evolutionary history, from old depletion to most recent refertilization and metasomatic events, for this large sector of the northern Victoria Land subcontinental lithospheric mantle.

Recycled ancient ghost carbonate in the Pitcairn mantle plume

The extreme Sr, Nd, Hf, and Pb isotopic compositions found in Pitcairn Island basalts have been labeled enriched mantle 1 (EM1), characterizing them as one of the isotopic mantle end members. The EM1 origin has been vigorously debated for over 25 years, with interpretations ranging from delaminated subcontinental lithosphere, to recycled lower continental crust, to recycled oceanic crust carrying ancient pelagic sediments, all of which may potentially generate the requisite radiogenic isotopic composition. Here we find that δ26Mg ratios in Pitcairn EM1 basalts are significantly lower than in normal mantle and are the lowest values so far recorded in oceanic basalts. A global survey of Mg isotopic compositions of potentially recycled components shows that marine carbonates constitute the most common and typical reservoir invariably characterized by extremely low δ26Mg values. We therefore infer that the subnormal δ26Mg of the Pitcairn EM1 component originates from subducted marine carbonates. This, combined with previously published evidence showing exceptionally unradiogenic Pb as well as sulfur isotopes affected by mass-independent fractionation, suggests that the Pitcairn EM1 component is most likely derived from late Archean subducted carbonate-bearing sediments. However, the low Ca/Al ratios of Pitcairn lavas are inconsistent with experimental evidence showing high Ca/Al ratios in melts derived from carbonate-bearing mantle sources. We suggest that carbonate–silicate reactions in the late Archean subducted sediments exhausted the carbonates, but the isotopically light magnesium of the carbonate was incorporated in the silicates, which then entered the lower mantle and ultimately became the Pitcairn plume source.