scholarly journals Recycled ancient ghost carbonate in the Pitcairn mantle plume

2018 ◽  
Vol 115 (35) ◽  
pp. 8682-8687 ◽  
Author(s):  
Xiao-Jun Wang ◽  
Li-Hui Chen ◽  
Albrecht W. Hofmann ◽  
Takeshi Hanyu ◽  
Hiroshi Kawabata ◽  
...  
Keyword(s):  
Sulfur Isotopes ◽  
Isotopic Compositions ◽  
Enriched Mantle ◽  
Mass Independent Fractionation ◽  
Published Evidence ◽  
Mantle Sources ◽  
Marine Carbonates ◽  
Oceanic Basalts ◽  
End Members ◽  
Subcontinental Lithosphere

The extreme Sr, Nd, Hf, and Pb isotopic compositions found in Pitcairn Island basalts have been labeled enriched mantle 1 (EM1), characterizing them as one of the isotopic mantle end members. The EM1 origin has been vigorously debated for over 25 years, with interpretations ranging from delaminated subcontinental lithosphere, to recycled lower continental crust, to recycled oceanic crust carrying ancient pelagic sediments, all of which may potentially generate the requisite radiogenic isotopic composition. Here we find that δ26Mg ratios in Pitcairn EM1 basalts are significantly lower than in normal mantle and are the lowest values so far recorded in oceanic basalts. A global survey of Mg isotopic compositions of potentially recycled components shows that marine carbonates constitute the most common and typical reservoir invariably characterized by extremely low δ26Mg values. We therefore infer that the subnormal δ26Mg of the Pitcairn EM1 component originates from subducted marine carbonates. This, combined with previously published evidence showing exceptionally unradiogenic Pb as well as sulfur isotopes affected by mass-independent fractionation, suggests that the Pitcairn EM1 component is most likely derived from late Archean subducted carbonate-bearing sediments. However, the low Ca/Al ratios of Pitcairn lavas are inconsistent with experimental evidence showing high Ca/Al ratios in melts derived from carbonate-bearing mantle sources. We suggest that carbonate–silicate reactions in the late Archean subducted sediments exhausted the carbonates, but the isotopically light magnesium of the carbonate was incorporated in the silicates, which then entered the lower mantle and ultimately became the Pitcairn plume source.

scholarly journals Sulfur and lead isotopic evidence of relic Archean sediments in the Pitcairn mantle plume

2016 ◽  
Vol 113 (46) ◽  
pp. 12952-12956 ◽  
Author(s):  
Hélène Delavault ◽  
Catherine Chauvel ◽  
Emilie Thomassot ◽  
Colin W. Devey ◽  
Baptiste Dazas
Keyword(s):  
Lead Isotopes ◽  
Pb Isotope ◽  
Walvis Ridge ◽  
Enriched Mantle ◽  
Mass Independent Fractionation ◽  
Deep Earth ◽  
Source Component ◽  
Oceanic Island Basalts ◽  
Isotopic Mixing ◽  
Subcontinental Lithosphere

The isotopic diversity of oceanic island basalts (OIB) is usually attributed to the influence, in their sources, of ancient material recycled into the mantle, although the nature, age, and quantities of this material remain controversial. The unradiogenic Pb isotope signature of the enriched mantle I (EM I) source of basalts from, for example, Pitcairn or Walvis Ridge has been variously attributed to recycled pelagic sediments, lower continental crust, or recycled subcontinental lithosphere. Our study helps resolve this debate by showing that Pitcairn lavas contain sulfides whose sulfur isotopic compositions are affected by mass-independent fractionation (S-MIF down to Δ33S = −0.8), something which is thought to have occurred on Earth only before 2.45 Ga, constraining the youngest possible age of the EM I source component. With this independent age constraint and a Monte Carlo refinement modeling of lead isotopes, we place the likely Pitcairn source age at 2.5 Ga to 2.6 Ga. The Pb, Sr, Nd, and Hf isotopic mixing arrays show that the Archean EM I material was poor in trace elements, resembling Archean sediment. After subduction, this Archean sediment apparently remained stored in the deep Earth for billions of years before returning to the surface as Pitcairn´s characteristic EM I signature. The presence of negative S-MIF in the deep mantle may also help resolve the problem of an apparent deficit of negative Δ33S anomalies so far found in surface reservoirs.

scholarly journals Light Stable Isotopic Compositions of Enriched Mantle Sources: Resolving the Dehydration Paradox

2017 ◽  
Vol 18 (11) ◽  
pp. 3801-3839 ◽  
Author(s):  
J. E. Dixon ◽  
I. N. Bindeman ◽  
R. H. Kingsley ◽  
K. K. Simons ◽  
P. J. Le Roux ◽  
...  
Keyword(s):  
Isotopic Compositions ◽  
Enriched Mantle ◽  
Stable Isotopic ◽  
Mantle Sources

scholarly journals A heterogeneous subcontinental mantle under the African–Arabian Plate boundary revealed by boron and radiogenic isotopes

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Samuele Agostini ◽  
Paolo Di Giuseppe ◽  
Piero Manetti ◽  
Carlo Doglioni ◽  
Sandro Conticelli
Keyword(s):  
Plate Boundary ◽  
Radiogenic Isotopes ◽  
Arabian Plate ◽  
Boron Isotopes ◽  
Axial Zone ◽  
Enriched Mantle ◽  
Magma Supply ◽  
Mantle Sources ◽  
End Members ◽  
Oceanic Domain

AbstractThe northern and northwestern margins of the Arabian Plate are a locus of a diffuse and long-lasting (early Miocene to Pleistocene) Na-alkali basaltic volcanism, sourced in the asthenosphere mantle. The upwelling asthenosphere at the Africa–Arabia margin produces very limited magma volumes in the axial zone. Therefore, portions of hot, fertile mantle continue their eastward migration and are stored at shallower depths under the 100-km thick Arabian lithosphere, which is much thinner than the African one (≈175 km): this causes the occurrence and 20-Ma persistence of magma supply under the study area. Erupted basalts sampled a continuous variation of the mantle source, with a striking correlation among temperature, pressure and isotopic composition shifting between two end members: a 100 km-deep, more depleted source, and a 60 km-deep, more enriched one. In particular, we observed an unusual variation in boron isotopes, which in the oceanic domain does not vary between more depleted and more enriched mantle sources. This study shows that, at least in the considered region, subcontinental mantle is more heterogeneous than the suboceanic one, and able to record for very long times recycling of shallow material.

Archean granitoids: classification, petrology, geochemistry and origin

2019 ◽  
Vol 489 (1) ◽  
pp. 15-49 ◽  
Author(s):  
Jean-François Moyen
Keyword(s):  
Partial Melting ◽  
Mantle Source ◽  
Enriched Mantle ◽  
Mantle Sources ◽  
Tectonic System ◽  
End Members ◽  
Continuous Range ◽  
Metasomatized Mantle

AbstractThis paper describes the petrology, geochemistry and petrogenesis of Archean granitoids. Archean granites define a continuum of compositions between several end members: (i) magmas that originated by partial melting of a range of crustal sources, from amphibolites to metasediments (‘C-type’ granitoids); and (ii) magmas that formed by partial melting of an enriched mantle source, the most common agent of enrichment being felsic (TTG) melts. Differences in the degree of metasomatism results in different primitive liquids for these ‘M-type’ granitoids.Mixed sources, differentiation and interactions between different melts resulted in a continuous range of compositions, defined by variable proportions of each end member.During the Archean, evolved crustal sources (sediments or felsic crust) and metasomatized mantle sources become increasingly more important, mirroring the progressive maturation of crustal segments and the stabilization of the global tectonic system.

scholarly journals Geochemical Variation of Miocene Basalts within Shikoku Basin: Magma Source Compositions and Geodynamic Implications

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 25
Author(s):  
Shuang-Shuang Chen ◽  
Tong Hou ◽  
Jia-Qi Liu ◽  
Zhao-Chong Zhang
Keyword(s):  
Japan Sea ◽  
Isotopic Signature ◽  
Magma Source ◽  
Isotopic Compositions ◽  
Enriched Mantle ◽  
Shikoku Basin ◽  
Depleted Mantle ◽  
Parece Vela Basin ◽  
Back Arc ◽  
Ocean Ridge

Shikoku Basin is unique as being located within a trench-ridge-trench triple junction. Here, we report mineral compositions, major, trace-element, and Sr-Nd-Pb isotopic compositions of bulk-rocks from Sites C0012 (>18.9 Ma) and 1173 (13–15 Ma) of the Shikoku Basin. Samples from Sites C0012 and 1173 are tholeiitic in composition and display relative depletion in light rare earth elements (REEs) and enrichment in heavy REEs, generally similar to normal mid-ocean ridge basalts (N-MORB). Specifically, Site C0012 samples display more pronounced positive anomalies in Rb, Ba, K, Pb and Sr, and negative anomalies in Th, U, Nb, and Ta, as well as negative Nb relative to La and Th. Site 1173 basalts have relatively uniform Sr-Nd-Pb isotopic compositions, close to the end member of depleted mantle, while Site C0012 samples show slightly enriched Sr-Nd-Pb isotopic signature, indicating a possible involvement of enriched mantle 1 (EM1) and EM2 sources, which could be attributed to the metasomatism of the fluids released from the dehydrated subduction slab, but with the little involvement of subducted slab-derived sedimentary component. Additionally, the Shikoku Basin record the formation of the back-arc basin was a mantle conversion process from an island arc to a typical MORB. The formation of the Shikoku Basin is different from that of the adjacent Japan Sea and Parece Vela Basin, mainly in terms of the metasomatized subduction-related components, the nature of mantle source, and partial melting processes.

Le terrane de Slide Mountain (Cordillères canadiennes) : une lithosphère océanique marquée par des points chauds

2003 ◽  
Vol 40 (6) ◽  
pp. 833-852 ◽  
Author(s):  
M Tardy ◽  
H Lapierre ◽  
D Bosch ◽  
A Cadoux ◽  
A Narros ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
Oceanic Island ◽  
Light Rare Earth ◽  
Isotopic Compositions ◽  
Incompatible Elements ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
British Colombia ◽  
Ultramafic Cumulates ◽  
Back Arc

The Slide Mountain Terrane consists of Devonian to Permian siliceous and detrital sediments in which are interbedded basalts and dolerites. Locally, ultramafic cumulates intrude these sediments. The Slide Mountain Terrane is considered to represent a back-arc basin related to the Quesnellia Paleozoic arc-terrane. However, the Slide Mountain mafic volcanic rocks exposed in central British Colombia do not exhibit features of back-arc basin basalts (BABB) but those of mid-oceanic ridge (MORB) and oceanic island (OIB) basalts. The N-MORB-type volcanic rocks are characterized by light rare-earth element (LREE)-depleted patterns, La/Nb ratios ranging between 1 and 2. Moreover, their Nd and Pb isotopic compositions suggest that they derived from a depleted mantle source. The within-plate basalts differ from those of MORB affinity by LREE-enriched patterns; higher TiO2, Nb, Ta, and Th abundances; lower εNd values; and correlatively higher isotopic Pb ratios. The Nd and Pb isotopic compositions of the ultramafic cumulates are similar to those of MORB-type volcanic rocks. The correlations between εNd and incompatible elements suggest that part of the Slide Mountain volcanic rocks derive from the mixing of two mantle sources: a depleted N-MORB type and an enriched OIB type. This indicates that some volcanic rocks of the Slide Mountain basin likely developed from a ridge-centered or near-ridge hotspot. The activity of this hotspot is probably related to the worldwide important mantle plume activity that occurred at the end of Permian times, notably in Siberia.

scholarly journals Ore and Geochemical Specialization and Substance Sources of the Ural and Timan Carbonatite Complexes (Russia): Insights from Trace Element, Rb–Sr, and Sm–Nd Isotope Data

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 711
Author(s):  
Irina Nedosekova ◽  
Nikolay Vladykin ◽  
Oksana Udoratina ◽  
Boris Belyatsky
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Crustal Evolution ◽  
Trace Element Data ◽  
The Urals ◽  
Nd Isotope ◽  
Enriched Mantle ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
Geochemical Specialization

The Ilmeno–Vishnevogorsk (IVC), Buldym, and Chetlassky carbonatite complexes are localized in the folded regions of the Urals and Timan. These complexes differ in geochemical signatures and ore specialization: Nb-deposits of pyrochlore carbonatites are associated with the IVC, while Nb–REE-deposits with the Buldym complex and REE-deposits of bastnäsite carbonatites with the Chetlassky complex. A comparative study of these carbonatite complexes has been conducted in order to establish the reasons for their ore specialization and their sources. The IVC is characterized by low 87Sr/86Sri (0.70336–0.70399) and εNd (+2 to +6), suggesting a single moderately depleted mantle source for rocks and pyrochlore mineralization. The Buldym complex has a higher 87Sr/86Sri (0.70440–0.70513) with negative εNd (−0.2 to −3), which corresponds to enriched mantle source EMI-type. The REE carbonatites of the Chetlassky сomplex show low 87Sr/86Sri (0.70336–0.70369) and a high εNd (+5–+6), which is close to the DM mantle source with ~5% marine sedimentary component. Based on Sr–Nd isotope signatures, major, and trace element data, we assume that the different ore specialization of Urals and Timan carbonatites may be caused not only by crustal evolution of alkaline-carbonatite magmas, but also by the heterogeneity of their mantle sources associated with different degrees of enrichment in recycled components.

Status-quo of carbonate cadmium isotope compositions as a paleo-productivity proxy

2021 ◽  
Author(s):  
Simon V. Hohl
Keyword(s):  
Isotopic Composition ◽  
Isotope Composition ◽  
Status Quo ◽  
Ambient Seawater ◽  
Isotopic Compositions ◽  
Marine Carbonates ◽  
The Status ◽  
State Changes ◽  
Underlying Processes ◽  
Isotope Systematics

<p>Cadmium (Cd) and isotope systematics are emerging tools for studying the biogeochemical cycling of micronutrients in the oceans, and sedimentary archives, as Cd concentrations in seawater show a nutrient-like behaviour, with surface depletion and deep water enrichments. However, the underlying processes are yet to be fully understood. The Cd concentration and isotopic composition of seawater are set by the balance of Cd inputs (and their isotopic composition) and the fractionation on removal to sedimentary sinks. The most favoured explanation is the Cd utilisation by marine phototrophic biomass, causing the surface water’s dissolved Cd pool depletion creating a depth gradient of increasing Cd concentrations and lighter isotopic compositions. Under incomplete oxidative recycling, organic matter may act as an effective Cd sink and authigenic minerals may store the ambient seawater’s Cd isotope composition.</p><p>Consequently, stable Cd isotope compositions in marine carbonates show broad variations linked to paleo-productivity and redox state changes. Additional fractionation processes govern the Cd isotopic compositions of marine sediments. Besides biological utilisation, experimental Cd partitioning into authigenic calcites or sulphides under variable redox and salinity conditions has been shown.  Therefore, when applying Cd isotopes in carbonates, other geochemical proxies must be evaluated very carefully to understand the involved Cd fractionation processes. This presentation aims to present the status quo of research done on authigenic and biologic carbonates and carbonate leachates in carbonatic shales to show the strengths and pitfalls of this new emerging bio-geoscience isotope proxy and its use for paleoenvironmental reconstructions on Earth and beyond.</p><p> </p><p> </p>

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