A facile, simple, and inexpensive ionic liquid, 1-alkyl-3-methylimidazole chloride, as ligand for the iron(iii)-mediated reverse atom transfer radical polymerization of methyl methacrylate

The facile, simple, and inexpensive ILs, 1-alkyl-3-methylimidazole chloride ([Rmim][Cl]), are explored for the first time as ligands for the reverse ATRP of methacrylates.

A novel copper catalyst containing a hydroxyl functional group: a facile strategy to prepare block copolymers of vinyl monomer and ε-caprolactone via tandem reverse ATRP and ROP

A facile hydroxyl-functionalized catalyst was first accessed to prepare block copolymers of vinyl and cyclic ester monomers via tandem reverse ATRP/ROP.

Facile, simple, and inexpensive ionic liquid, 1-phenyl-3-methylimidazole diphenyl phosphate, as an efficient phosphorus-based ligand for copper-catalyzed reverse atom transfer radical polymerization of methyl methacrylate

A facile, simple, and inexpensive ionic liquid, 1-phenyl-3-methylimidazole diphenyl phosphate has been successfully used as an efficient phosphorus ligand for CuBr2-mediated reverse ATRP.

Facile iron(iii)-mediated ATRP of MMA with phosphorus-containing ligands in the absence of any additional initiators

Fe(iii)-mediated ATRP using phosphorus reagents was studied without any additional initiator and reducing agent. The polymerization was demonstrated as reverse ATRP, in which phosphorus reagents acted as both ligand and thermal radical initiator.