A worldwide meta-analysis (1977–2020) of sediment core dating using fallout radionuclides including ¹³⁷Cs and ²¹⁰Pb_xs

Dating recent sediment archives (< 150 years) constitutes a prerequisite for environmental and climatic reconstructions. Radiocaesium (137Cs) emitted during thermonuclear bomb testing (∼ 1950–1980) and nuclear accidents and the decrease in excess lead-210 (210Pbxs) with depth are often combined to establish sediment core chronology. Although these methods have been widely used during the last several decades, there is a lack of structured and comprehensive worldwide synthesis of fallout radionuclide analyses used for dating sediment cores in environmental and Earth sciences. The current literature overview was based on the compilation of 573 articles published between 1977 and 2020, reporting the collection of 1351 individual dating sediment cores (the dataset can be accessed at https://doi.org/10.1594/PANGAEA.931493; Foucher et al., 2021). This review was conducted in order to map the locations where 137Cs fallout events were detected. These included the thermonuclear bomb testing peak in 1963, the Chernobyl accident in 1986, the Fukushima accident in 2011, and 24 additional events identified at 112 sites that led to local or regional radioactive releases (e.g., Sellafield accidents, Chinese nuclear tests). When 210Pbxs records were used along with 137Cs data, detailed information on the 210Pbxs age–depth models were also synthesized. With the current growing number of studies analyzing sediment cores and the increasing interest in the deployment of sediment fingerprinting techniques including radionuclides as potential discriminant properties, this spatialized synthesis provides a unique worldwide compilation for characterizing fallout radionuclide sources and levels at the global scale. This synthesis provides in particular a reference of 137Cs peak attribution for improving the sediment core dating, and it outlines the main questions that deserve attention in future research as well as the regions where additional 137Cs fallout investigations should be conducted in priority.

A worldwide meta-analysis (1977–2020) of sediment core dating using fallout radionuclides including ¹³⁷Cs and ²¹⁰Pb_xs

Dating recent sediment archives (< 150 years) constitutes a prerequisite for environmental and climatic reconstructions. Radiocaesium (137Cs) emitted during thermonuclear bomb testing (~1950 ̶ 1980) and nuclear accidents, as well as the decrease of excess lead-210 (210Pbxs) with depth are often combined to establish sediment core chronology. Although these methods have been widely used during the last several decades, there is a lack of structured and comprehensive worldwide synthesis of fallout radionuclide analyses used for dating sediment cores in environmental and Earth sciences. The current literature overview was based on the compilation of 573 articles published between 1977 and 2020, reporting the collection of 1351 individual dating sediment cores (the dataset can be accessed at https://doi.pangaea.de/10.1594/PANGAEA.931493). This review was conducted in order to map the locations where 137Cs fallout events were detected. These included the thermonuclear bomb testing peak in 1963, the Chernobyl accident in 1986, the Fukushima accident in 2011, and 24 additional events identified in 112 sites that led to local radioactive releases (e.g. Sellafield accidents, Chinese nuclear tests). When 210Pbxs records were used along with 137Cs data, detailed information on the 210Pbxs age depth models were also synthesized. Multiple information including the core collection method, sediment properties, radionuclide analysis techniques and catchment characteristics were also compiled. With the current growing number of studies analyzing sediment cores and the increasing interest in the deployment of sediment fingerprinting techniques including radionuclides as potential discriminant properties, this spatialized synthesis provides a unique worldwide compilation for characterizing fallout radionuclide sources and levels at the global scale. This synthesis provides in particular a referential of 137Cs peak attribution for improving the sediment core dating and it outlines the main questions that deserve attention in future research as well as the regions where additional 137Cs fallout investigations should be conducted in priority.

Soil degradation due to the conversion of native grassland into cropland in the Pampa biome – (Southern Brazil) and impact on suspended sediment supply to the rivers

&lt;p&gt;The conversion of the natural grasslands of the Pampa biome (Southern Brazil) into cropland may lead to an increase in soil erosion rates and sediment delivery to the rivers. Grasslands represent a significant sink of carbon, and according to the literature, 59% of the soil organic carbon (SOC) is lost when pastures are converted into cropland. It makes soils even more vulnerable to water and land degradation. This study aims to evaluate the impact of land use change on the river sediment composition by calculating the sediment contribution of each potential sediment source using organic matter composition, ultra-violet and visible (UV-VIS) spectra derived parameters and fallout radionuclide activities, as potential tracers in a sediment fingerprinting approach. The study site (Ibirapuit&amp;#227; river basin &amp;#8211; 5,942 km&amp;#178;) is located in the Pampa biome, Southern Brazil, were sandy and shallow soils predominate, occupied mainly by native grasslands that are gradually being converted to cropfields, especially soybean. Potential sediment sources were sampled, which include croplands (n=36), native grasslands (n=31), unpaved roads (n=31) and subsurface sources (channel banks (n=18) and gullies (n=16)). Samples were taken from the soil surface layer of croplands and grasslands, as well as from the top layer of exposed sites of gullies, channel banks and unpaved roads. Samples were oven dried (50 &amp;#176;C), gently disaggregated and dry sieved to 63 mm to avoid particle size effects prior to further analysis. Suspended sediment samples were collected using time integrated samplers deployed in the bottom of the river, and during rainfall runoff events at the outlet of the catchment. Organic matter parameters (total organic carbon - TOC, total nitrogen - TN, &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C and &amp;#948;&lt;sup&gt;15&lt;/sup&gt;N) were measured using a continuous flow isotope ratio mass spectrometry (EA-IRMS). Diffuse reflectance spectra in the UV-VIS wavelengths was measured using a Cary 5000 UV-VIS-NIR spectrophotometer, and 33 parameters were derived from the spectra. Fallout radionuclide (&lt;sup&gt;137&lt;/sup&gt;Cs and &lt;sup&gt;210&lt;/sup&gt;Pb&lt;sub&gt;xs&lt;/sub&gt;) activities were measured by gamma spectrometry using low-background high-purity germanium detectors. Tracers were selected following a three step procedure, including: (i) a conservative range test, (ii) a Kruskal&amp;#8211;Wallis H-test, and (iii) a linear discriminant function analysis. The selected tracers were introduced into a mass balance mixing model to estimate the source contributions to in-stream sediment by minimizing the sum of square residuals. TOC and TN show significant differences between cropland and native grassland, while the isotopes &amp;#948;&lt;sup&gt;13&lt;/sup&gt;C and &amp;#948;&lt;sup&gt;15&lt;/sup&gt;N, presented a lower discrimination potential. TOC and UV-VIS derived parameters did not present a good discriminant potential when they were tested in isolation, although they increased the source discrimination when combined with organic matter parameters. Fallout radionuclides have a good discriminant potential between surface and subsurface sources, but also between native grasslands and croplands. Croplands are the main sediment source in the Ibirapuit&amp;#227; river catchment (36%), followed by the native grasslands (33%). However, the area occupied by croplands is approximately eight times smaller, demonstrating that erosion processes have been intensified by the conversion of native grasslands into croplands and/or croplands are better connected to the river network.&lt;/p&gt;