Laser driving technology is an important technology in high energy physics, shock wave physics and explosive initiation application. In this paper, velocities and impact stresses of four types of laser-driven flyers (Al, Al/Al2O3/Al, CuO/Al2O3/Al, (CuO/Al)/Al2O3/Al) prepared via magnetron sputtering were obtained by photonic Doppler velocimetry (PDV) and a self-made polyvinylidene fluoride (PVDF) stress sensor at ns-class pulse width.The results showed that velocities and integrity of flyers were influenced by their diameters. Compared with Al single-layer flyer, other multi-layer flyers with Al2O3 insulation layer owned lower velocity but better integrity and initiation properties.CuO/Al as the ablation layer enhanced the velocities and shock initiation properties of multi-layer flyers. Velocity of a flyer improved with the increasing laser energy while shock initiation property did not perform in the same way. These results provide some references for the design of multi-layer flyers applied to laserdriven initiation technology.