Relationship between Phase Composition and Mechanical Properties of Peat Soils Stabilized Using Oil Shale Ash and Pozzolanic Additive

Construction of road embankments in peatlands commonly involves replacement of the peat with a fill-up soil of an adequate load-bearing capacity. This usually requires a lowering of the water level, turning a peatland from a carbon sink to a source of greenhouse gases. Thus, alternatives are sought that are less costly in both economic and ecological terms. Mass-stabilization technology can provide a cheap substitute for Portland cement. Calcareous ashes (waste materials), supplemented with pozzolanic and alkali additives to facilitate and accelerate the setting and hardening processes, are attractive alternatives to soil excavation or replacement techniques. Silica fume and waterglass were used as pozzolanic agents and KOH as a soil-alkalizing agent. X-ray fluorescence (XRF), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) analyses and stress–strain tests were performed for the hardened samples. Crystallization of alkali feldspars was observed in all test samples. Comparable hardening of peat soil was achieved for both ashes. It was shown that the ashes of Estonian kukersite (oil shale) from both pulverized firing and a circulating fluidized bed incineration process (produced in energy sector as quantitatively major solid waste in Estonia) can be used as binding agents for peat stabilization, even without the addition of Portland cement. Hardened peat soil samples behaved as a ductile material, and the cellulose fibers naturally present in peat gave the peat–ash composite plasticity, acting mechanically in the same way as the steel or glass fiber in ordinary reinforced concrete. The effect of peat fiber reinforcement was higher in cases of higher load and displacement of the composite, making the material usable in ecological constructions.

Study of Thermooxidation of Oil Shale Samples and Basics of Processes for Utilization of Oil Shale Ashes

A circular economy becomes an object of actual discussions as a real alternative to the existing linear economy system. The problem is actually in Estonia also, first of all in the sector of heat and power production which based mainly on the combustion of local solid fossil fuel—Estonian oil shale (OS) resulting in the formation of ~5–6 million tons of OS ashes annually. The thermooxidative decomposition of OS samples from different deposits and estimation of the possibilities of utilization of OS ashes formed at both—pulverized firing (PF) and circulating fluidized bed combustion (CFBC) of Estonian OS were studied. The thermal analysis combined with evolved gas analysis (EGA) methods like Fourier transform infrared (FTIR) and mass-spectroscopy (MS) was exploited. It was established that the differences in the thermal behaviour of different OS samples are caused by the differences in the chemical matrix of organic matter, chemical and mineralogical composition of the inorganic part of OS, and morphology of samples. It was also found that moderate grinding of OS ashes with simultaneous moderate water treatment notably improved the SO2 binding efficiency of cyclone ash, and that the strength and leachability characteristics of granulated OS ashes strongly depend on the post-granulation treatment conditions allowing to increase the soil neutralizing ability of the granulated products. This overview was based on our investigations carried out during the last fifteen years.

New 215 MWel CFB Power Units for Estonian Oil Shale

Estonian basic power supply is over 90% covered by oil shale fired thermal power plants. Total installed thermal capacity of the boilers is 10.7 GWth and every year about 11 millions tons of oil shale is fired. Two different combustion technologies, the old pulverized oil shale firing and the new CFB technology are used at the moment. The new CFB units totaling 430 MWel delivered by Foster Wheeler Energia started operation in 2003–2004. The very first operational experience of CFB units are very promising and all basic problems of oil shale pulverized firing like high air emissions (SO2 — 820–1360 mg/MJ; NOx — 90–110 mg/MJ), fouling and corrosion of heating surfaces, low efficiency and low operational reliability seemed to be solved. Oil shale CFB firing at much lower temperatures (∼800°C) than pulverized firing (∼1400°C) results only partial decomposition of oil shale contained carbonates, meaning lower specific fuel consumption values and decreased CO2 emissions. Also fly ash composition and properties has been changed, which results in different new prospectives of ash utilization possibilities, but also some additional ash land filling problems. The paper analyses the first data of Estonian oil shale industrial CFB firing in the light of almost 40 year experience of Estonian oil shale use in power production.