Thermodynamic Properties of the First-Generation Hybrid Dendrimer with “Carbosilane Core/Phenylene Shell” Structure

The molar heat capacity of the first-generation hybrid dendrimer with a “carbosilane core/phenylene shell” structure was measured for the first time in the temperature range T = 6–600 K using a precise adiabatic vacuum calorimeter and DSC. In the above temperature interval, the glass transition of the studied compound was observed, and its thermodynamic characteristics were determined. The standard thermodynamic functions (the enthalpy, the entropy, and the Gibbs energy) of the hybrid dendrimer were calculated over the range from T = 0 to 600 K using the experimentally determined heat capacity. The standard entropy of formation of the investigated dendrimer was evaluated at T = 298.15 K. The obtained thermodynamic properties of the studied hybrid dendrimer were compared and discussed with the literature data for some of the first-generation organosilicon and pyridylphenylene dendrimers.

HADAMARD STATES, ADIABATIC VACUA AND THE CONSTRUCTION OF PHYSICAL STATES FOR SCALAR QUANTUM FIELDS ON CURVED SPACETIME

Quasifree states of a linear Klein-Gordon quantum field on globally hyperbolic spacetime manifolds are considered. After a short mathematical review techniques from the theory of pseudodifferential operators and wavefront sets on manifolds are used to develop a criterion for a state to be an Hadamard state. It is proven that ground- and KMS-states on certain static spacetimes and adiabatic vacuum states on Robertson-Walker spaces are Hadamard states. A counterexample is given which shows that the idea of instantaneous positive energy states w.r.t. a Cauchy surface does in general not yield physical states. Finally, the problem of constructing Hadamard states on arbitrary curved spacetimes is solved in principle.