Оптимизация анодной мембраны с прострельной мишенью в системе источников мягкого рентгеновского излучения для проведения процессов рентгеновской нанолитографии

In this paper, we propose a method for optimizing the design and composition of the anode membrane with a transmission-type target as part of a system of soft X-ray sources based on field-emission triodes for performing tasks in the field of X-ray nanolithography. It allows to prevent the degradation of the operating characteristics of the system when significant electrostatic deformation of the anode occurs under the influence of a control electric field in the inter-electrode space of the triodes. For this purpose, the inclusion of an additional control electrode in the system design is considered, which makes it possible to compensate for the deformation of the anode membrane to an acceptable level and thereby stabilize the operation of X-ray sources. A numerical model of the electrostatic deflection of the anode assembly in a modified design is developed, based on which the optimal composition and geometric parameters of the anode membrane with a compensating electrode are determined. In particular, the optimal distance between the anode membrane in the initial (undeformed) state and the compensating electrode was found (equal to 5 μm), at which a minimum voltage difference (about 1.15 kV) should be applied to these electrodes to prevent critical deflection of the membrane (0.72 μm with a membrane radius of 750 µm). It is also shown that, due to their extremely high hardness (>80 GPa), diamond-like films are the most promising material for the anode electrode. The results obtained can also be useful for the development of miniature X-ray generation devices for various applications.

Specific Chemical Reactivities of Spatially Separated 3-Aminophenol Conformers with Cold Ca+ Ions

Many molecules exhibit multiple rotational isomers (conformers) that interconvert thermally and are difficult to isolate. Consequently, a precise characterization of their role in chemical reactions has proven challenging. We have probed the reactivity of specific conformers by using an experimental technique based on their spatial separation in a molecular beam by electrostatic deflection. The separated conformers react with a target of Coulomb-crystallized ions in a trap. In the reaction of Ca+ with 3-aminophenol, we find a twofold larger rate constant for the cis compared with the trans conformer (differentiated by the O–H bond orientation). This result is explained by conformer-specific differences in the long-range ion-molecule interaction potentials. Our approach demonstrates the possibility of controlling reactivity through selection of conformational states.