By Reaction with Binuclear Metal Carbonyls

2007 ◽  
pp. 273-273
Author(s):  
K. M. Mackay
1980 ◽  
Vol 19 (2) ◽  
pp. 560-562 ◽  
Author(s):  
Nicholas J. Taylor ◽  
Graham N. Mott ◽  
Arthur J. Carty

2020 ◽  
Vol 44 (30) ◽  
pp. 12942-12948
Author(s):  
Zhong Zhang ◽  
Zuqing Chen ◽  
Zhipeng Yang ◽  
Jianping Wang ◽  
Liang Pu ◽  
...  

Theoretical studies indicate the complexes M(CO)n(PS) with bent 1-e/2-e donor PS groups to be unstable for giving the stable M(CO)n−1(PS) with linear 3-e donor PS groups. In addition, only Mn2(CO)8(P2S2) is energetically viable from the Mn(CO)4(PS).


Author(s):  
Ya. A. Nuriev ◽  
L. F. Rybakova ◽  
A. A. Pasynskii ◽  
G. Z. Suleimanov ◽  
S. P. Gubin ◽  
...  

1969 ◽  
Vol 22 (1) ◽  
pp. 49 ◽  
Author(s):  
RR Schrieke ◽  
BO West

Trispentafluorophenylsilane has been prepared and characterized. The silane has been used to prepare the monohalides, (C6F5)3SiX (X = Cl, Br), as well as the disiloxane, (C6F5)3Si-O-Si(C6F5)3. The silane has also been found to react with the binuclear metal carbonyls Co2(CO)8 and M2(CO)10 (M = Mn, Re) to yield the silyl-metal derivatives. We report the preparation and infrared and mass spectra of these compounds, and their reactivity towards triphenylphosphine.


2001 ◽  
Vol 73 (7) ◽  
pp. 1059-1073 ◽  
Author(s):  
Henry F. Schaefer ◽  
R. Bruce King

Modern density functional methods, which yield geometrical parameters and energies close to experimental values for known metal carbonyls such as Fe(CO)5 and Fe2(CO)9, have been extended to unsaturated binary binuclear metal carbonyls. Novel optimized structures have been discovered containing metal­metal multiple bonds, four-electron bridging carbonyl groups, and metal electronic configurations less than 18 electrons.


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