ESR study of the interaction of mononuclear and binuclear metal carbonyls with silicon hydrides and the use of these systems to generate ?-chlorine-containing radicals

1981 ◽  
Vol 30 (6) ◽  
pp. 980-984 ◽  
Author(s):  
R. G. Gasanov ◽  
R. Kh. Freidlina
Keyword(s):  
Metal Carbonyls ◽  
Silicon Hydrides ◽  
Binuclear Metal

Binuclear metal carbonyls: molecular structure of .mu.-chloro-.mu.-(diphenylphosphido)-hexacarbonyldiiron(Fe-Fe)

1980 ◽  
Vol 19 (2) ◽  
pp. 560-562 ◽  
Author(s):  
Nicholas J. Taylor ◽  
Graham N. Mott ◽  
Arthur J. Carty
Keyword(s):  
Molecular Structure ◽  
Metal Carbonyls ◽  
Binuclear Metal

P2S2-Bridged binuclear metal carbonyls from dimerization of coordinated thiophosphoryl groups: a theoretical study

2020 ◽  
Vol 44 (30) ◽  
pp. 12942-12948
Author(s):  
Zhong Zhang ◽  
Zuqing Chen ◽  
Zhipeng Yang ◽  
Jianping Wang ◽  
Liang Pu ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Theoretical Studies ◽  
Metal Carbonyls ◽  
Binuclear Metal

Theoretical studies indicate the complexes M(CO)n(PS) with bent 1-e/2-e donor PS groups to be unstable for giving the stable M(CO)n−1(PS) with linear 3-e donor PS groups. In addition, only Mn2(CO)8(P2S2) is energetically viable from the Mn(CO)4(PS).

Structure and Bonding in Binuclear Metal Carbonyls from the Analysis of Domain Averaged Fermi Holes. 2. Fe2(CO)82−and Fe2(CO)8

2008 ◽  
Vol 112 (40) ◽  
pp. 9936-9945 ◽  
Author(s):  
Robert Ponec ◽  
György Lendvay ◽  
Markku R. Sundberg
Keyword(s):  
Metal Carbonyls ◽  
Structure And Bonding ◽  
Binuclear Metal

Reaction of thulium(0) with binuclear metal carbonyls

1982 ◽  
Vol 31 (11) ◽  
pp. 2323-2323
Author(s):  
Ya. A. Nuriev ◽  
L. F. Rybakova ◽  
A. A. Pasynskii ◽  
G. Z. Suleimanov ◽  
S. P. Gubin ◽  
...  
Keyword(s):  
Metal Carbonyls ◽  
Binuclear Metal

Trispentafluorophenylsilane and trispentafluorophenylsilyl-metal derivatives. Preparation, and infrared and mass spectra

1969 ◽  
Vol 22 (1) ◽  
pp. 49 ◽  
Author(s):  
RR Schrieke ◽  
BO West
Keyword(s):  
Mass Spectra ◽  
Metal Carbonyls ◽  
Metal Derivatives ◽  
Binuclear Metal

Trispentafluorophenylsilane has been prepared and characterized. The silane has been used to prepare the monohalides, (C6F5)3SiX (X = Cl, Br), as well as the disiloxane, (C6F5)3Si-O-Si(C6F5)3. The silane has also been found to react with the binuclear metal carbonyls Co2(CO)8 and M2(CO)10 (M = Mn, Re) to yield the silyl-metal derivatives. We report the preparation and infrared and mass spectra of these compounds, and their reactivity towards triphenylphosphine.

Unsaturated binuclear homoleptic metal carbonyls M2(CO)x (M = Fe, Co, Ni; x = 5, 6, 7, 8). Are multiple bonds between transition metals possible for these molecules?

2001 ◽  
Vol 73 (7) ◽  
pp. 1059-1073 ◽  
Author(s):  
Henry F. Schaefer ◽  
R. Bruce King
Keyword(s):  
Density Functional ◽  
Geometrical Parameters ◽  
Carbonyl Groups ◽  
Metal Carbonyls ◽  
Multiple Bonds ◽  
Density Functional Methods ◽  
Functional Methods ◽  
Electronic Configurations ◽  
Binuclear Metal ◽  
Experimental Values

Modern density functional methods, which yield geometrical parameters and energies close to experimental values for known metal carbonyls such as Fe(CO)5 and Fe2(CO)9, have been extended to unsaturated binary binuclear metal carbonyls. Novel optimized structures have been discovered containing metal­metal multiple bonds, four-electron bridging carbonyl groups, and metal electronic configurations less than 18 electrons.

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