Crystal Engineering of Coordination Polymers

2009 ◽  
pp. 451-511 ◽  
Author(s):  
Marius Andruh ◽  
Catalina Ruiz-Pérez
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering

Gold−Gold Interactions as Crystal Engineering Design Elements in Heterobimetallic Coordination Polymers

2001 ◽  
Vol 40 (23) ◽  
pp. 6026-6034 ◽  
Author(s):  
Daniel B. Leznoff ◽  
Bao-Yu Xue ◽  
Raymond J. Batchelor ◽  
Frederick W. B. Einstein ◽  
Brian O. Patrick
Keyword(s):  
Engineering Design ◽  
Coordination Polymers ◽  
Crystal Engineering ◽  
Design Elements

A threefold interpenetrated two-dimensional zinc(II) supramolecular architecture based on 3-nitrobenzoic acid and 4,4′-bipyridine

2016 ◽  
Vol 72 (2) ◽  
pp. 128-132 ◽  
Author(s):  
Long Tang ◽  
Ji-Jiang Wang ◽  
Feng Fu ◽  
Sheng-Wen Wang ◽  
Qi-Rui Liu
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering ◽  
Critical Factor ◽  
Building Blocks ◽  
Zigzag Chain ◽  
Great Success ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Hydrothermal Conditions ◽  
Nitrobenzoic Acid

With regard to crystal engineering, building block or modular assembly methodologies have shown great success in the design and construction of metal–organic coordination polymers. The critical factor for the construction of coordination polymers is the rational choice of the organic building blocks and the metal centre. The reaction of Zn(OAc)2·2H2O (OAc is acetate) with 3-nitrobenzoic acid (HNBA) and 4,4′-bipyridine (4,4′-bipy) under hydrothermal conditions produced a two-dimensional zinc(II) supramolecular architecture,catena-poly[[bis(3-nitrobenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′], [Zn(C7H4NO4)2(C10H8N2)]nor [Zn(NBA)2(4,4′-bipy)]n, which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction analysis. The ZnIIions are connected by the 4,4′-bipy ligands to form a one-dimensional zigzag chain and the chains are decorated with anionic NBA ligands which interact further through aromatic π–π stacking interactions, expanding the structure into a threefold interpenetrated two-dimensional supramolecular architecture. The solid-state fluorescence analysis indicates a slight blue shift compared with pure 4,4′-bipyridine and HNBA.

ChemInform Abstract: Square Grid and Pillared Square Grid Coordination Polymers - Fertile Ground for Crystal Engineering of Structure and Function

ChemInform ◽  
2013 ◽  
Vol 45 (2) ◽  
pp. no-no
Author(s):  
Stephen D. Burd ◽  
Patrick S. Nugent ◽  
Mona H. Mohamed ◽  
Sameh K. Elsaidi ◽  
Michael J. Zaworotko
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering ◽  
Structure And Function ◽  
Square Grid ◽  
Fertile Ground ◽  
And Function

scholarly journals Crystal engineering of coordination-polymer-based iodine adsorbents using a π-electron-rich polycarboxylate aryl ether ligand

CrystEngComm ◽  
2020 ◽  
Vol 22 (40) ◽  
pp. 6612-6619
Author(s):  
Junling Chen ◽  
Bo Li ◽  
Zhenzhen Shi ◽  
Cheng He ◽  
Chunying Duan ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Crystal Engineering ◽  
Adsorption Process ◽  
Halogen Bonding ◽  
Aryl Ether ◽  
Interaction Sites ◽  
Charge Transfer Interaction ◽  
Iodine Adsorption

This work revealed that the synergy of microporous channels and convergent arrangements of halogen bonding and charge-transfer interaction sites within coordination polymers facilitated the iodine adsorption process.

Crystal Engineering and Magnetostructural Properties of Newly Designed Azide/Acetate-Bridged Mn12 Coordination Polymers

2019 ◽  
Vol 19 (4) ◽  
pp. 2366-2379 ◽  
Author(s):  
Mo Ashafaq ◽  
Mohd Khalid ◽  
Mukul Raizada ◽  
Anzar Ali ◽  
Mohd Faizan ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering

Crystal engineering of coordination polymers containing flexible bis-pyridyl-bis-amide ligands

CrystEngComm ◽  
2015 ◽  
Vol 17 (25) ◽  
pp. 4611-4626 ◽  
Author(s):  
Kedar Bahadur Thapa ◽  
Jhy-Der Chen
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering ◽  
Amide Ligands

Eindimensionale Kupfer(II)-Koordinationspolymere: Kristall-Engineering durch variable Verknüpfungsmuster [1] / One Dimensional Copper(II) Coordination Polymers: Crystal Engineering through Variable Types of Linkage [1]

1997 ◽  
Vol 52 (1) ◽  
pp. 125-134 ◽  
Author(s):  
Rolf W. Saalfrank ◽  
Roland Harbig ◽  
Oliver Struck ◽  
Frank Hampel ◽  
Eva Maria Peters ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Crystal Engineering ◽  
Coordination Compounds ◽  
Acetate Solution ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
1D Coordination Polymer

Reaction of a methanolic copper(II) acetate solution with tetrazolyl enol derivatives 2a or 2b leads to the formation of the corresponding lD-coordination polymer 1∞[CuL2] 3a and pseudo 1D-coordination polymer [CuL2]2 3b, respectively. On the contrary, reaction of 2c with methanolic copper(II) acetate solution yields OH-bridged 1D-coordination polymer 1∞[CuL2(MeOH)2 3c. Single-crystal X-ray diffraction of the supramolecular species 3 established unequivocally the structures of the stairlike coordination compounds. Reaction of a methanolic copper(II) acetate solution with amidotetrazole derivative 6 leads to the formation of the lD-coordination polymer 1∞ [CuL2] 7. The structure of 7 has been established by X-ray structure analysis

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