Lightweight and Highly Heat‐Resistant Microcellular Polyetherimide/Barium Titanate/Carbon Nanotube Nanocomposites with High Dielectric Permittivity and Low Dielectric Loss

Author(s):  
Xiaolian Xiang ◽  
Zhonglei Ma ◽  
Jiayao Jing ◽  
Borui Guo ◽  
Menghui Zhang ◽  
...  
2020 ◽  
Vol 4 (3) ◽  
pp. 137
Author(s):  
Gayaneh Petrossian ◽  
Nahal Aliheidari ◽  
Amir Ameli

Ternary composites of flexible thermoplastic polyurethane (TPU), lead zirconate titanate (PZT), and multiwalled carbon nanotubes (MWCNTs) with very high dielectric permittivity (εr) and low dielectric loss (tan δ) are reported. To assess the evolution of dielectric properties with the interactions between conductive and dielectric fillers, composites were designed with a range of content for PZT (0–30 vol%) and MWCNT (0–1 vol%). The microstructure was composed of PZT-rich and segregated MWCNT-rich regions, which could effectively prevent the formation of macroscopic MWCNT conductive networks and thus reduce the high ohmic loss. Therefore, εr increased by a maximum of tenfold, reaching up to 166 by the addition of up to 1 vol% MWCNT to TPU/PZT. More importantly, tan δ remained relatively unchanged at 0.06–0.08, a similar range to that of pure TPU. εr/tan δ ratio reached 2870 at TPU/30 vol% PZT/0.5 vol% MWCNT, exceeding most of the reported values. This work demonstrates the potential of three-phase polymer/conductive filler/dielectric filler composites for efficient charge storage applications.


2019 ◽  
Vol 7 (1) ◽  
pp. 133-140 ◽  
Author(s):  
Biao Zhao ◽  
Mahdi Hamidinejad ◽  
Chongxiang Zhao ◽  
Ruosong Li ◽  
Sai Wang ◽  
...  

A microcellular structure can effectively tune the dielectric properties of PVDF/carbon composite foams.


2013 ◽  
Vol 03 (02) ◽  
pp. 1350010 ◽  
Author(s):  
Fei Wen ◽  
Zhuo Xu ◽  
Weimin Xia ◽  
Xiaoyong Wei ◽  
Zhicheng Zhang

In this work, nanocomposites (poly(vinylidenefluoride–trifluoroethylene–chlorotrifluoroethylene)/Graphene nanosheets) (P(VDF–TrFE–CTFE)/GNS) were fabricated via solution cast process. GNS were covalently functionalized with KH550 to improve their interfacial interactions with the terpolymer matrix P(VDF–TrFE–CTFE). Compared to neat terpolymer, significantly improved dielectric permittivity and low loss were observed for the composites. For instance, at 1 kHz the P(VDF–TrFE–CTFE)/GNS composites with 4% GNS possessed a dielectric permittivity of 144, over 14 times larger than that of neat terpolymer, while the loss was only 0.56. These findings represent an effective route to design potential dielectric polymer films for high-charge storage capacitors.


RSC Advances ◽  
2016 ◽  
Vol 6 (24) ◽  
pp. 20074-20080 ◽  
Author(s):  
Jinglei Li ◽  
Zhuo Xu ◽  
Fei Li ◽  
Xuhui Zhu ◽  
Shujun Zhang

SiO2–Ti0.98In0.01Nb0.01O2 (SiO2–TINO) composite ceramics were synthesized by solid-state sintering methods, where the lower dielectric loss and enhanced breakdown electric field were achieved.


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