Modulating Charge Separation Efficiency of Water Oxidation Photoanodes with Polyelectrolyte‐Assembled Interfacial Dipole Layers

2019 ◽  
Vol 30 (10) ◽  
pp. 1908492 ◽  
Author(s):  
Sanghyun Bae ◽  
Dongseok Kim ◽  
Hyunwoo Kim ◽  
Minsu Gu ◽  
Jungki Ryu ◽  
...  
2018 ◽  
Vol 6 (24) ◽  
pp. 11377-11389 ◽  
Author(s):  
S. Sultana ◽  
S. Mansingh ◽  
K. M. Parida

Self regenerating oxygen vacancy rich CeO2NS–FeOOH/Fe2O3 hybrids are optimized and show superior charge separation efficiency both in visible and UV-visible light.


2019 ◽  
Vol 7 (28) ◽  
pp. 16992-16998 ◽  
Author(s):  
André Esteves Nogueira ◽  
Mario Rodrigo Santos Soares ◽  
João Batista Souza Junior ◽  
Carlos Alberto Ospina Ramirez ◽  
Flavio Leandro Souza ◽  
...  

A colloidal deposition process combined with the thermal spreading ability of Sb over hematite surface is used to obtain a mesoporous photoanode for water oxidation.


2018 ◽  
Vol 6 (21) ◽  
pp. 9839-9845 ◽  
Author(s):  
Sha-Sha Yi ◽  
Jun-Min Yan ◽  
Qing Jiang

The carbon quantum dot (CQD) sensitized integrated Ti:Fe2O3@g-C3N4 core–shell nanoarrays demonstrate superior PEC water oxidation performance which can be ascribed to efficient charge separation efficiency derived from the well-confined heterojunction structure together with the high catalytic activity of the CQDs for H2O2 decomposition.


2016 ◽  
Vol 52 (58) ◽  
pp. 9013-9015 ◽  
Author(s):  
Zhibin Luo ◽  
Chengcheng Li ◽  
Dong Zhang ◽  
Tuo Wang ◽  
Jinlong Gong

A highly-oriented Fe2O3/ZnFe2O4 heterojunction photoanode with well-defined morphology is featured for improving charge separation efficiency.


2018 ◽  
Vol 6 (46) ◽  
pp. 23478-23485 ◽  
Author(s):  
Feng Li ◽  
Jing Li ◽  
Lili Gao ◽  
Yiping Hu ◽  
Xuefeng Long ◽  
...  

In this study, we constructed an efficient hole migration pathway by integrating ultrathin amorphous NiOOH onto the Fe2O3 coating on F doped α-Fe2O3 nanorods. The resulting photoanode presents higher charge separation efficiency than most reported hematite-based photoanode.


Author(s):  
Yating Wang ◽  
Chaosheng Peng ◽  
Tao Jiang ◽  
Jing Zhang ◽  
Zheng Jiang ◽  
...  

To improve solar light harvesting and charge separation efficiency, we develop a facile strategy for synthesizing defect-engineered three-dimensionally ordered macroporous (3DOM) WO3 photonic crystals via colloidal crystal template method and...


Nanophotonics ◽  
2020 ◽  
Vol 9 (7) ◽  
pp. 2077-2088 ◽  
Author(s):  
Daixun Jiang ◽  
Xun Sun ◽  
Xilu Wu ◽  
Shuai Zhang ◽  
Xiaofei Qu ◽  
...  

AbstractThe strategy to improve the photocatalytic removal efficiencies towards organic pollutants is still a challenge for the novel Sillen–Aurivillius perovskite type Bi4NbO8Cl. Herein, we report carbon-supported TiO2/Bi4NbO8Cl (C-TiO2/Bi4NbO8Cl) heterostructures with enhanced charge separation efficiency, which were fabricated via molten-salt flux process. The carbon-supported TiO2 particles were derived from MXene Ti3C2 precursors, and attached on plate-like Bi4NbO8Cl, acting as electron-traps to achieve supressed recombination of photo-induced charges. The improved charge separation confers C-TiO2/Bi4NbO8Cl heterostructures superior photocatalytic performance with 53% higher than pristine Bi4NbO8Cl, towards rhodamine B removal with the help of photo-induced holes. Moreover, the C-TiO2/Bi4NbO8Cl heterostructures can be expanded to deal with other water contaminants, such as methyl orange, ciprofloxacin and 2,4-dichlorophenol with 44, 25 and 13% promotion, respectively, and thus the study offers a series of efficient photocatalysts for water purification.


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