High-Surface-Area Mesoporous Germanium from Oxidative Polymerization of the Deltahedral [Ge9]4– Cluster: Electronic Structure Modulation with Donor and Acceptor Molecules

2008 ◽  
Vol 20 (3) ◽  
pp. 546-550 ◽  
Author(s):  
G. S. Armatas ◽  
M. G. Kanatzidis
Keyword(s):  
Electronic Structure ◽  
Surface Area ◽  
Oxidative Polymerization ◽  
High Surface ◽  
High Surface Area ◽  
Donor And Acceptor ◽  
Structure Modulation ◽  
Acceptor Molecules

Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization

2018 ◽  
Vol 6 (44) ◽  
pp. 21901-21905 ◽  
Author(s):  
S. Grätz ◽  
M. Oltermann ◽  
E. Troschke ◽  
S. Paasch ◽  
S. Krause ◽  
...  
Keyword(s):  
Surface Area ◽  
Ball Mill ◽  
Oxidative Polymerization ◽  
High Surface ◽  
High Surface Area ◽  
Solvent Free ◽  
Porous Polymer ◽  
Polymerization Reaction ◽  
Free Environment ◽  
Solvent Free Synthesis

An oxidative polymerization reaction was brought into the solvent-free environment of a ball mill, yielding a porous polymer with a defined structure and high surface area.

scholarly journals Electronic structure of Lewis acid sites on high surface area aluminium fluorides: a combined XPS and ab initio investigation

2009 ◽  
Vol 11 (27) ◽  
pp. 5664 ◽  
Author(s):  
Anna Makarowicz ◽  
Christine L. Bailey ◽  
Norbert Weiher ◽  
Erhard Kemnitz ◽  
Sven L. M. Schroeder ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Ab Initio ◽  
Surface Area ◽  
Lewis Acid ◽  
High Surface ◽  
High Surface Area ◽  
Acid Sites ◽  
Lewis Acid Sites

Tenacious Mass Transfer Limitations Drive Catalytic Selectivity during Electrochemical Carbon Dioxide Reduction

2019 ◽  
Author(s):  
Kailun Yang ◽  
Recep Kas ◽  
Wilson A. Smith
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst Layer ◽  
Active Surface ◽  
Active Surface Area ◽  
High Concentration ◽  
Copper Electrodes ◽  
Surface Enhanced ◽  
Local Current

<p>This study evaluated the performance of the commonly used strong buffer electrolytes, i.e. phosphate buffers, during CO<sub>2</sub> electroreduction in neutral pH conditions by using in-situ surface enhanced infrared absorption spectroscopy (SEIRAS). Unfortunately, the buffers break down a lot faster than anticipated which has serious implications on many studies in the literature such as selectivity and kinetic analysis of the electrocatalysts. Increasing electrolyte concentration, surprisingly, did not extend the potential window of the phosphate buffers due to dramatic increase in hydrogen evolution reaction. Even high concentration phosphate buffers (1 M) break down within the potentials (-1 V vs RHE) where hydrocarbons are formed on copper electrodes. We have extended the discussion to high surface area electrodes by evaluating electrodes composed of copper nanowires. We would like highlight that it is not possible to cope with high local current densities on these high surface area electrodes by using high buffer capacity solutions and the CO<sub>2</sub> electrocatalysts are needed to be evaluated by casting thin nanoparticle films onto inert substrates as commonly employed in fuel cell reactions and up to now scarcely employed in CO<sub>2</sub> electroreduction. In addition, we underscore that normalization of the electrocatalytic activity to the electrochemical active surface area is not the ultimate solution due to concentration gradient along the catalyst layer.This will “underestimate” the activity of high surface electrocatalyst and the degree of underestimation will depend on the thickness, porosity and morphology of the catalyst layer. </p> <p> </p>

scholarly journals Rugae-like FeP nanocrystal assembly on a carbon cloth: an exceptionally efficient and stable cathode for hydrogen evolution

Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 10974-10981 ◽  
Author(s):  
Xiulin Yang ◽  
Ang-Yu Lu ◽  
Yihan Zhu ◽  
Shixiong Min ◽  
Mohamed Nejib Hedhili ◽  
...  
Keyword(s):  
Gas Phase ◽  
Surface Area ◽  
Hydrogen Evolution ◽  
Hydrogen Generation ◽  
High Surface ◽  
High Surface Area ◽  
Catalytic Efficiency ◽  
Carbon Cloth ◽  
Nanocrystal Assembly

High surface area FeP nanosheets on a carbon cloth were prepared by gas phase phosphidation of electroplated FeOOH, which exhibit exceptionally high catalytic efficiency and stability for hydrogen generation.

High Surface Area NiCoP Nanostructure as Efficient Water Splitting Electrocatalyst for the Oxygen Evolution Reaction

2021 ◽  
pp. 111312
Author(s):  
Sisir Maity ◽  
Dheeraj Kumar Singh ◽  
Divya Bhutani ◽  
Suchitra Prasad ◽  
Umesh V. Waghmare ◽  
...  
Keyword(s):  
Surface Area ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Surface ◽  
High Surface Area

scholarly journals Fast synthesis of high surface area bio-based porous carbons for p-nitrophenol removal

MethodsX ◽  
2021 ◽  
pp. 101464
Author(s):  
Yichen Wu ◽  
Nan Zhang ◽  
Charles-François de Lannoy
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Porous Carbons ◽  
Fast Synthesis

Synthesis of high surface area and functionalized nanoporous biocarbons and their efficiency for CO2 capture and supercapacitors

2021 ◽  
Author(s):  
Gurwinder Singh ◽  
Rohan Bahadur ◽  
Ajanya Maria Ruban ◽  
Jefrin Marykala Davidraj ◽  
Dawei Su ◽  
...  
Keyword(s):  
Energy Storage ◽  
Surface Area ◽  
Co2 Capture ◽  
Water Purification ◽  
High Surface ◽  
High Surface Area ◽  
Energy Storage And Conversion ◽  
Waste Biomass ◽  
Fabrication Technology ◽  
Significant Attention

Nanoporous biocarbons derived from waste biomass have created significant attention owing to their great potential for energy storage and conversion and water purification. However, the fabrication technology for these materials...

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