Mechanically Robust Atomic Oxygen-Resistant Coatings Capable of Autonomously Healing Damage in Low Earth Orbit Space Environment

2018 ◽  
Vol 30 (36) ◽  
pp. 1803854 ◽  
Author(s):  
Xiaohan Wang ◽  
Yixuan Li ◽  
Yuhai Qian ◽  
Hong Qi ◽  
Jian Li ◽  
...  
2011 ◽  
Vol 239-242 ◽  
pp. 1368-1371 ◽  
Author(s):  
Mi Mi Song ◽  
Shu Wang Duo ◽  
Ting Zhi Liu

In order to improve the atomic oxygen (AO) erosion resistance of polyimide films in low earth orbit space environment, a type PDMS/POSS hybrid coating on polyimide substrate was prepared based on a silanol terminated polydimethylsiloxane (PDMS-OH) and Octakis(trimethylsiloxy)octaprismosilsesquioxane (Q8[Si(CH3)3]8) by copolymerizing process in DMAc solution. The atomic oxygen exposure tests were carried out using a ground-based atomic oxygen simulation facility. The mass loss, surface morphology and surface chemical compositions of PDMS/POSS hybrid films before and after exposure to incremental AO flux were investigated by using microbalance and field emission scanning electron microscopy (FE-SEM) and X-ray photoelectron spectroscopy (XPS), respectively. The data indicated that a silica-rich layer was formed on the surface of the hybrid coating when the coating is exposed to AO flux, which could provide a protective barrier on the surface preventing further degradation of the polymer during extended exposure to AO and obviously improved the AO resistance of polyimide films.


Polymer ◽  
2020 ◽  
Vol 191 ◽  
pp. 122270 ◽  
Author(s):  
Ranjana Shivakumar ◽  
Asaf Bolker ◽  
Siu Hon Tsang ◽  
Nurit Atar ◽  
Ronen Verker ◽  
...  

2000 ◽  
Vol 12 (1) ◽  
pp. 43-52 ◽  
Author(s):  
John W Connell

Thin films of phenylphosphine oxide-containing polymers were exposed to low Earth orbit aboard a space shuttle flight (STS-85) as part of flight experiment designated Evaluation of Space Environment and Effects on Materials (ESEM). This flight experiment was a cooperative effort between the NASA Langley Research Center (LaRC) and the National Space Development Agency of Japan (NASDA). The thin-film samples described herein were part of an atomic oxygen exposure (AOE) experiment and were exposed to primarily atomic oxygen (∼1×1019 atoms cm−2). The thin-film samples consisted of three phosphine oxide-containing polymers (arylene ether, benzimidazole and imide). Based on post-flight analyses using atomic force microscopy, x-ray photo-electron spectroscopy and weight loss data, it was found that the exposure of these materials to atomic oxygen (AO) produces a phosphorus oxide layer on the surface of the samples. Earlier work has shown that this layer provides a barrier towards further attack by AO. Consequently, these materials do not exhibit linear erosion rates which is in contrast with most organic polymers. Qualitatively, the results obtained from these analyses compare favourably with those obtained from samples exposed to AO and/or an oxygen plasma in ground-based exposure experiments. The results of the low Earth orbit AO exposure on these materials will be compared with those of ground-based exposure to AO.


1995 ◽  
Vol 30 (2) ◽  
pp. 308-320 ◽  
Author(s):  
S. Packirisamy ◽  
D. Schwam ◽  
M. H. Litt

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