Chiral Octahydro‐Binaphthol Compound‐Based Thermally Activated Delayed Fluorescence Materials for Circularly Polarized Electroluminescence with Superior EQE of 32.6% and Extremely Low Efficiency Roll‐Off

2019 ◽  
Vol 31 (28) ◽  
pp. 1900524 ◽  
Author(s):  
Zheng‐Guang Wu ◽  
Hua‐Bo Han ◽  
Zhi‐Ping Yan ◽  
Xu‐Feng Luo ◽  
Yi Wang ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Circularly Polarized ◽  
Thermally Activated ◽  
Low Efficiency

Thermally activated delayed fluorescence with circularly polarized luminescence characteristics

2015 ◽  
Vol 51 (68) ◽  
pp. 13268-13271 ◽  
Author(s):  
Takuro Imagawa ◽  
Shuzo Hirata ◽  
Kenro Totani ◽  
Toshiyuki Watanabe ◽  
Martin Vacha
Keyword(s):  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Circularly Polarized ◽  
Metal Free ◽  
Thermally Activated ◽  
Sign Inversion ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence ◽  
Large Conformational Change ◽  
Luminescence Characteristics

A metal-free aromatic compound exhibiting thermally activated delayed fluorescence as well as circularly polarized luminescence (CPL) with dissymmetry factors of 10−3 is reported. This compound shows a sign inversion between its circular dichroism signal and CPL, which is caused by a large conformational change upon photoexcitation.

Controlling the exciton lifetime of blue thermally activated delayed fluorescence emitters using a heteroatom-containing pyridoindole donor moiety

2017 ◽  
Vol 4 (4) ◽  
pp. 619-624 ◽  
Author(s):  
Gyeong Heon Kim ◽  
Raju Lampande ◽  
Joon Beom Im ◽  
Jung Min Lee ◽  
Ju Young Lee ◽  
...  
Keyword(s):  
Molecular Design ◽  
Delayed Fluorescence ◽  
Energy Splitting ◽  
Triplet Energy ◽  
High Quantum Efficiency ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Exciton Lifetime ◽  
Low Efficiency ◽  
Donor Moiety

We demonstrate a promising molecular design approach to achieve short exciton lifetime, small singlet and triplet energy splitting and high photoluminescence quantum yield in thermally activated delayed fluorescence emitters for high quantum efficiency and low efficiency roll-off characteristics in OLEDs.

Solution-processable orange-red thermally activated delayed fluorescence emitters with 3,6-disubstituted carbazole for highly efficient OLEDs with low efficiency roll-off

2022 ◽  
Author(s):  
Yaxing Zhang ◽  
Yuanyuan Zheng ◽  
Changsheng Shi ◽  
Jinyan Zhang ◽  
Tao Wang ◽  
...  
Keyword(s):  
Light Emitting Diodes ◽  
Delayed Fluorescence ◽  
Organic Light Emitting Diodes ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Organic Light ◽  
Green Materials ◽  
Device Efficiency ◽  
Low Efficiency

The progress of orange-red thermally activated delayed fluorescence (TADF) emitters for solution-processed organic light-emitting diodes (OLEDs) is still lagged behind blue and green materials in terms of device efficiency. In...

Theoretical study on the light-emitting mechanism of circularly polarized luminescence molecules with both thermally activated delayed fluorescence and aggregation-induced emission

2019 ◽  
Vol 21 (14) ◽  
pp. 7288-7297 ◽  
Author(s):  
Xiu Yin ◽  
Jian-Zhong Fan ◽  
Jie Liu ◽  
Lei Cai ◽  
Hao Sun ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Circularly Polarized ◽  
Aggregation Induced Emission ◽  
Thermally Activated ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence

The light-emitting mechanism of circularly polarized luminescence molecules with both TADF and AIE.

Triazatruxene-based small molecules with thermally activated delayed fluorescence, aggregation-induced emission and mechanochromic luminescence properties for solution-processable nondoped OLEDs

2018 ◽  
Vol 6 (46) ◽  
pp. 12503-12508 ◽  
Author(s):  
Yonghong Chen ◽  
Shumeng Wang ◽  
Xiaofu Wu ◽  
Yuxiang Xu ◽  
Hua Li ◽  
...  
Keyword(s):  
Small Molecules ◽  
Delayed Fluorescence ◽  
Luminescence Properties ◽  
Thermally Activated Delayed Fluorescence ◽  
Aggregation Induced Emission ◽  
Thermally Activated ◽  
Solution Processable ◽  
Low Efficiency ◽  
Mechanochromic Luminescence

Thermally activated delayed fluorescence, aggregation-induced emission and mechanochromic luminescence properties are combined in triazatruxene-based small molecules, which exhibit low efficiency roll-off in OLED devices.

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