All‐Solid‐State Batteries with a Limited Lithium Metal Anode at Room Temperature using a Garnet‐Based Electrolyte

2020 ◽  
Vol 33 (1) ◽  
pp. 2002325
Author(s):  
Shaojie Chen ◽  
Jingxuan Zhang ◽  
Lu Nie ◽  
Xiangchen Hu ◽  
Yuanqi Huang ◽  
...  
Keyword(s):  
Solid State ◽  
Room Temperature ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Solid State Batteries ◽  
All Solid State Batteries

Protecting lithium metal anode in all-solid-state batteries with a composite electrolyte

Rare Metals ◽  
2020 ◽  
Author(s):  
Wen-Qing Wei ◽  
Bing-Qiang Liu ◽  
Yi-Qiang Gan ◽  
Hai-Jian Ma ◽  
Da-Wei Cui
Keyword(s):  
Solid State ◽  
Lithium Metal ◽  
Composite Electrolyte ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Solid State Batteries ◽  
All Solid State Batteries

Creep and Anisotropy of Free-Standing Lithium Metal Foils in an Industrial Dry Room

2021 ◽  
pp. 1-32
Author(s):  
Lara Dienemann ◽  
Anil Saigal ◽  
Michael A Zimmerman
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
High Volume ◽  
Dominant Mode ◽  
Lithium Metal ◽  
Free Standing ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
Lithium Metal Anode ◽  
Solid State Batteries

Abstract Commercialization of energy-dense lithium metal batteries relies on stable and uniform plating and stripping on the lithium metal anode. In electrochemical-mechanical modeling of solid-state batteries, there is a lack of consideration of specific mechanical properties of battery-grade lithium metal. Defining these characteristics is crucial for understanding how lithium ions plate on the lithium metal anode, how plating and stripping affect deformation of the anode and its interfacing material, and whether dendrites are suppressed. Recent experiments show that the dominant mode of deformation of lithium metal is creep. This study measures the time and temperature dependent mechanics of two thicknesses of commercial lithium anodes inside an industrial dry room, where battery cells are manufactured at high volume. Furthermore, a directional study examines the anisotropic microstructure of 100 µm thick lithium anodes and its effect on bulk creep mechanics. It is shown that these lithium anodes undergo plastic creep as soon as a coin cell is manufactured at a pressure of 0.30 MPa, and achieving thinner lithium foils, a critical goal for solid-state lithium batteries, is correlated to anisotropy in both lithium's microstructure and mechanical properties.

Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries

2020 ◽  
Vol 120 (15) ◽  
pp. 7745-7794 ◽  
Author(s):  
Thorben Krauskopf ◽  
Felix H. Richter ◽  
Wolfgang G. Zeier ◽  
Jürgen Janek
Keyword(s):  
Solid State ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Solid State Batteries

Conformation of lithium-aluminium alloy interphase-layer on lithium metal anode used for solid state batteries

2018 ◽  
Vol 277 ◽  
pp. 268-275 ◽  
Author(s):  
Hai Zhong ◽  
Lin Sang ◽  
Fei Ding ◽  
Jiangxuan Song ◽  
Yaohua Mai
Keyword(s):  
Solid State ◽  
Aluminium Alloy ◽  
Interphase Layer ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Aluminium ◽  
Lithium Metal Anode ◽  
Solid State Batteries

scholarly journals Suppressing Void Formation in All-Solid-State Batteries: The Role of Interfacial Adhesion on Alkali Metal Vacancy Transport

2021 ◽  
Author(s):  
Ieuan Seymour ◽  
Ainara Aguadero
Keyword(s):  
Solid State ◽  
Interfacial Adhesion ◽  
Void Formation ◽  
Rechargeable Batteries ◽  
Metal Anode ◽  
Solid State Batteries ◽  
Promising Solution ◽  
Metal Vacancy ◽  
All Solid State Batteries

All-solid-state batteries containing a solid electrolyte and a lithium (Li) or sodium (Na) metal anode are a promising solution to simultaneously increase the energy density and safety of rechargeable batteries....

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