Ultrathin Modified Silica “Skin” for the Transfer Hydrogenation Catalyst: Improving Selectivity by Adjusting Surface Wettability

2021 ◽  
pp. 2100013
Author(s):  
Rongxiu Guo ◽  
Guangqi He ◽  
Xinyu Chen ◽  
Xinyue Zhang ◽  
Ze‐nan Hu ◽  
...  
2013 ◽  
Vol 52 (18) ◽  
pp. 10601-10609 ◽  
Author(s):  
Süleyman Gülcemal ◽  
Aytaç Gürhan Gökçe ◽  
Bekir Çetinkaya

2019 ◽  
Vol 48 (31) ◽  
pp. 11838-11847 ◽  
Author(s):  
Joseph P. Byrne ◽  
Pauline Musembi ◽  
Martin Albrecht

Triazolylidene NHCs decorated with a carbohydrate wingtip group were complexed to a ruthenium(ii) center. Deprotection of the carbohydrate in the metal complex affords a carbohydrate–NHC hybrid system for use as a transfer hydrogenation catalyst.


2019 ◽  
Vol 491 ◽  
pp. 544-552 ◽  
Author(s):  
Longkang Zhang ◽  
Junmin Wang ◽  
Ningzhao Shang ◽  
Shutao Gao ◽  
Yongjun Gao ◽  
...  

Inorganics ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 114 ◽  
Author(s):  
Yuta Nishina

Biomass has gained great attention as an alternative to fuel-derived chemicals. This report concerns new catalytic systems consisting of [IrCp*Cl2]2 (Cp*: Pentamethylcyclopentadienyl) for the reduction of aldehyde and biogenetic alcohols as hydrogen sources. [IrCp*Cl2]2 has been used as a transfer hydrogenation catalyst using fossil fuel-derived alcohols as hydrogen sources in the presence of a base. In contrast, our system does not require any base, and the reaction can proceed in water. Various types of biogenetic alcohols can be used as hydrogen sources, such as monosaccharides, oligosaccharides, and glycerol. Aromatic and aliphatic aldehydes, as well as ketones, were successfully reduced to the corresponding alcohols in the present system.


ChemInform ◽  
2010 ◽  
Vol 29 (45) ◽  
pp. no-no
Author(s):  
D. J. BAYSTON ◽  
C. B. TRAVERS ◽  
M. E. C. POLYWKA

2012 ◽  
Vol 354 (16) ◽  
pp. 3036-3044 ◽  
Author(s):  
Simone Manzini ◽  
César A. Urbina Blanco ◽  
Steven P. Nolan

1998 ◽  
Vol 9 (12) ◽  
pp. 2015-2018 ◽  
Author(s):  
Daniel J Bayston ◽  
Catherine B Travers ◽  
Mario E.C Polywka

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