The question of the dependence of the specific heat of carbon dioxide upon its density having been investigated, so far as is described in Part II., the further question remained over as to whether the specific heat of a gas is dependent upons range of temperature over which the gas is heated. The question was evidently within the power of the steam calorimeter to answer, provided arrangements were ride for varying the lower limit of temperature—the initial temperature. To vary upper limit by resorting to vapours other than steam would, on the large scale on which operations were being conducted, have been costly and troublesome, though not attended with any inaccuracy, as the experiments of Wirtz on the Heats of several vapours, determined by the method of condensation, appear show. It is to be observed, indeed, that the use of vapours other than water would .ow of operations being conducted upon smaller quantities of the gas, as it would be sy to find liquids whose vapours possessed a latent heat one-half or one-fourth as eat as that of water; and a construction necessitating but little loss of vapour at experiment could be easily contrived. In this case, also, it would be necessary provide a means of varying the initial temperature. Chiefly on the grounds of supense I decided upon the use of steam in conjunction with a means of altering the initial temperature. It appeared probable, too, that the alteration of the initial temperature between 10° and 100° would disclose the chief points of interest in these of the gas under consideration, the critical temperature lying within this range.
Large‐Scale Sub‐1‐nm Random Gaps Approaching the Quantum Upper Limit for Quantitative Chemical Sensing
