Multicomponent vapor-liquid equilibria at high pressures: Part I. Experimental study of the nitrogen—oxygen—carbon dioxide system at 0°C

AIChE Journal ◽  
1965 ◽  
Vol 11 (6) ◽  
pp. 1092-1096 ◽  
Author(s):  
N. K. Muirbrook ◽  
J. M. Prausnitz
2014 ◽  
Vol 12 (9) ◽  
pp. 953-961 ◽  
Author(s):  
Sergiu Sima ◽  
Catinca Secuianu ◽  
Viorel Feroiu ◽  
Dan Geană

AbstractNew vapor-liquid equilibria (VLE) data at 333.15, 343.15, and 353.15 K and pressures up to 130.0 bar are reported for the carbon dioxide + 2-methyl-1-propanol (isobutanol) system. The experimental method used in this work was a static analytical method with liquid and vapor phases sampling using a rapid online sampler injector (ROLSITM) coupled to a gas chromatograph (GC) for analysis. Measured VLE data and literature data for carbon dioxide + 2-methyl-1-propanol system were modeled with the Soave-Redlich-Kwong (SRK) cubic equation of state with classical van der Waals (two-parameter conventional mixing rule, 2PCMR) mixing rules. A single set of interaction parameters that lead to a correct phase behavior was used in this work to model the new VLE data and critical points of the mixtures in a wide range of temperature and pressure. The SRK prediction results were compared to the new data measured in this study and to available literature data.


1975 ◽  
Vol 8 (2) ◽  
pp. 89-92 ◽  
Author(s):  
TAKASHI KATAYAMA ◽  
KAZUNARI OHGAKI ◽  
GORO MAEKAWA ◽  
MOTOJIRO GOTO ◽  
TAMON NAGANO

2014 ◽  
Vol 12 (9) ◽  
pp. 893-900 ◽  
Author(s):  
Sergiu Sima ◽  
Catinca Secuianu ◽  
Viorel Feroiu ◽  
Dan Geană

AbstractNew vapor-liquid equilibria (VLE) data at 323.15, 333.15, 343.15, and 353.15 K and pressures up to 112.9 bar are reported for the carbon dioxide + 2-methyl-2-propanol system. The experimental method used in this work was a static analytical method with liquid and vapor phases sampling using a rapid online sampler injector (ROLSI™) coupled to a gas chromatograph (GC) for analysis. Measured VLE data and literature data for carbon dioxide + 2-methyl-2-propanol system were modeled with the Soave-Redlich-Kwong (SRK) cubic equation of state with classical van der Waals (two-parameter conventional mixing rule, 2PCMR) mixing rules. A single set of interaction parameters that lead to a correct phase behavior was used in this work to model the new VLE data and critical points of the mixtures in a wide range of temperature and pressure. The SRK prediction results were compared to the new data measured in this study and to available literature data.


1998 ◽  
Vol 43 (6) ◽  
pp. 954-956 ◽  
Author(s):  
Katsumi Tochigi ◽  
Kunihisa Hasegawa ◽  
Norihiro Asano ◽  
Kazuo Kojima

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