scholarly journals Highly Conductive Anion-Exchange Membranes from Microporous Tröger's Base Polymers

2016 ◽  
Vol 128 (38) ◽  
pp. 11671-11674 ◽  
Author(s):  
Zhengjin Yang ◽  
Rui Guo ◽  
Richard Malpass-Evans ◽  
Mariolino Carta ◽  
Neil B. McKeown ◽  
...  
Keyword(s):  
Anion Exchange ◽  
Anion Exchange Membranes ◽  
Troger's Base

Multi-cation crosslinked anion exchange membranes from microporous Tröger's base copolymers

2018 ◽  
Vol 6 (27) ◽  
pp. 13302-13311 ◽  
Author(s):  
Chuan Hu ◽  
Qiugen Zhang ◽  
Chenxiao Lin ◽  
Zhen Lin ◽  
Ling Li ◽  
...  
Keyword(s):  
Ion Channels ◽  
Anion Exchange ◽  
Dimensional Stability ◽  
Alkali Resistance ◽  
Anion Exchange Membranes ◽  
Ion Diffusion ◽  
Troger's Base

The multi-cation cross-linked AEMs based on Tröger's base promote the formation of continuous ion diffusion channels. The prepared AEMs, with the size of ion channels in the range of 15–26 nm, have good dimensional stability and excellent alkali resistance while exhibiting a high hydroxide conductivity of 103.9 mS cm−1 (80 °C) at a low IEC of 1.67 meq g−1.

Multiple Enhancement Effects of Crown Ether in Tröger’s Base Polymers on the Performance of Anion Exchange Membranes

2020 ◽  
Vol 12 (22) ◽  
pp. 24806-24816
Author(s):  
Qian Yang ◽  
Yuan Yuan Cai ◽  
Zhao Yu Zhu ◽  
Li Xuan Sun ◽  
Yvonne Shuen Lann Choo ◽  
...  
Keyword(s):  
Crown Ether ◽  
Anion Exchange ◽  
Anion Exchange Membranes ◽  
Troger's Base

scholarly journals Highly Conductive Anion-Exchange Membranes from Microporous Tröger's Base Polymers

2016 ◽  
Vol 55 (38) ◽  
pp. 11499-11502 ◽  
Author(s):  
Zhengjin Yang ◽  
Rui Guo ◽  
Richard Malpass-Evans ◽  
Mariolino Carta ◽  
Neil B. McKeown ◽  
...  
Keyword(s):  
Anion Exchange ◽  
Anion Exchange Membranes ◽  
Troger's Base

scholarly journals Quaternized Tröger’s base polymer with crown ether unit for alkaline stable anion exchange membranes

2020 ◽  
Vol 354 ◽  
pp. 136693 ◽  
Author(s):  
Chenxiao Lin ◽  
Yang Gao ◽  
Na Li ◽  
Min Zhang ◽  
Junming Luo ◽  
...  
Keyword(s):  
Crown Ether ◽  
Anion Exchange ◽  
Anion Exchange Membranes ◽  
Troger's Base ◽  
Base Polymer ◽  
Stable Anion

Polymeric materials as anion-exchange membranes for alkaline fuel cells

2011 ◽  
Vol 36 (11) ◽  
pp. 1521-1557 ◽  
Author(s):  
Guillaume Couture ◽  
Ali Alaaeddine ◽  
Frédéric Boschet ◽  
Bruno Ameduri
Keyword(s):  
Fuel Cells ◽  
Anion Exchange ◽  
Polymeric Materials ◽  
Anion Exchange Membranes ◽  
Alkaline Fuel Cells

High‐capacity multimodal anion‐exchange membranes for polishing of therapeutic proteins

2021 ◽  
Author(s):  
Joshua Osuofa ◽  
Daniel Henn ◽  
Jinxiang Zhou ◽  
Anna Forsyth ◽  
Scott M. Husson
Keyword(s):  
Anion Exchange ◽  
Therapeutic Proteins ◽  
High Capacity ◽  
Anion Exchange Membranes

scholarly journals Innovative BPPO Anion Exchange Membranes Formulation Using Diffusion Dialysis-Enhanced Acid Regeneration System

Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 311
Author(s):  
Muhammad Imran Khan ◽  
Majeda Khraisheh ◽  
Fares AlMomani
Keyword(s):  
Anion Exchange ◽  
Room Temperature ◽  
Feed Solution ◽  
Exchange Capacity ◽  
Anion Exchange Membranes ◽  
Regeneration System ◽  
Waste Streams ◽  
Acid Recovery ◽  
Aqueous Waste ◽  
Diffusion Dialysis

Recycling of acid from aqueous waste streams is crucial not only from the environmental point of view but also for maturing the feasible method (diffusion dialysis). Anion exchange membrane (AEM)–based diffusion dialysis process is one of the beneficial ways to recover acid from aqueous waste streams. In this article, the synthesis of a series of brominated poly (2, 6–dimethyl-1, 4–phenylene oxide) (BPPO)-based anion exchange membranes (AEMs) through quaternization with triphenylphosphine (TPP) were reported for acid recovery via diffusion dialysis process. The successful synthesis of the prepared membranes was confirmed by Fourier transform infrared (FTIR) spectroscopy. The as-synthesized anion exchange membranes represented water uptake (WR) of 44 to 66%, ion exchange capacity of (IEC) of 1.22 to 1.86 mmol/g, and linear swelling ratio (LSR) of 8 to 20%. They exhibited excellent thermal, mechanical, and acid stability. They showed homogeneous morphology. The acid recovery performance of the synthesized AEMs was investigated in a two compartment stack using simulated mixture of HCl and FeCl2 as feed solution at room temperature. For the synthesized anion exchange membranes TPP–43 to TPP–100, the diffusion dialysis coefficient of acid (UH+) was in the range of 6.7 to 26.3 (10−3 m/h) whereas separation factor (S) was in the range of 27 to 49 at 25 °C. Obtained results revealed that diffusion dialysis performance of the synthesized AEMs was higher than the commercial membrane DF–120B (UH+ = 0.004 m/h, S = 24.3) at room temperature. It showed that the prepared AEMs here could be excellent candidates for the diffusion dialysis process.

scholarly journals Transport Characteristics of CJMAED™ Homogeneous Anion Exchange Membranes in Sodium Chloride and Sodium Sulfate Solutions

2021 ◽  
Vol 22 (3) ◽  
pp. 1415
Author(s):  
Veronika Sarapulova ◽  
Natalia Pismenskaya ◽  
Valentina Titorova ◽  
Mikhail Sharafan ◽  
Yaoming Wang ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Anion Exchange ◽  
Volume Fraction ◽  
Exchange Capacity ◽  
Polymer Materials ◽  
Transport Numbers ◽  
Anion Exchange Membranes ◽  
Microheterogeneous Model ◽  
Pass Through ◽  
Pes Membrane

The interplay between the ion exchange capacity, water content and concentration dependences of conductivity, diffusion permeability, and counterion transport numbers (counterion permselectivity) of CJMA-3, CJMA-6 and CJMA-7 (Hefei Chemjoy Polymer Materials Co. Ltd., China) anion-exchange membranes (AEMs) is analyzed using the application of the microheterogeneous model to experimental data. The structure–properties relationship for these membranes is examined when they are bathed by NaCl and Na2SO4 solutions. These results are compared with the characteristics of the well-studied homogenous Neosepta AMX (ASTOM Corporation, Japan) and heterogeneous AMH-PES (Mega a.s., Czech Republic) anion-exchange membranes. It is found that the CJMA-6 membrane has the highest counterion permselectivity (chlorides, sulfates) among the CJMAED series membranes, very close to that of the AMX membrane. The CJMA-3 membrane has the transport characteristics close to the AMH-PES membrane. The CJMA-7 membrane has the lowest exchange capacity and the highest volume fraction of the intergel spaces filled with an equilibrium electroneutral solution. These properties predetermine the lowest counterion transport number in CJMA-7 among other investigated AEMs, which nevertheless does not fall below 0.87 even in 1.0 eq L−1 solutions of NaCl or Na2SO4. One of the reasons for the decrease in the permselectivity of CJMAED membranes is the extended macropores, which are localized at the ion-exchange material/reinforcing cloth boundaries. In relatively concentrated solutions, the electric current prefers to pass through these well-conductive but nonselective macropores rather than the highly selective but low-conductive elements of the gel phase. It is shown that the counterion permselectivity of the CJMA-7 membrane can be significantly improved by coating its surface with a dense homogeneous ion-exchange film.

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