Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese

2018 ◽  
Vol 57 (41) ◽  
pp. 13444-13448 ◽  
Author(s):  
Uttam Kumar Das ◽  
Subrata Chakraborty ◽  
Yael Diskin-Posner ◽  
David Milstein
2018 ◽  
Vol 130 (41) ◽  
pp. 13632-13636 ◽  
Author(s):  
Uttam Kumar Das ◽  
Subrata Chakraborty ◽  
Yael Diskin-Posner ◽  
David Milstein

ChemInform ◽  
2007 ◽  
Vol 38 (52) ◽  
Author(s):  
Mohammad Navid Soltani Rad ◽  
Ali Khalafi-Nezhad ◽  
Somayeh Behrouz ◽  
Mohammad Ali Faghihi

2021 ◽  
Author(s):  
Diana Ainembabazi ◽  
Jonathan Horlyck ◽  
Darren Dolan ◽  
Adam Lee ◽  
Karen Wilson ◽  
...  

<p>Design of active and selective supported catalysts is critical for developing new tandem processes for upgrading biomass-derived alcohols. Hydrogen-free upgrading alcohols to liquid hydrocarbons is desirable for producing drop-in fuel substitutes, but direct and atom-economical processes are yet to be reported. Here we report a novel alcohol upgrading and<b> </b>deoxygenation cascade that meets these criteria. This hydrogen-free cascade is catalyzed by multifunctional Pd catalysts, whose supports feature a range of acid-base properties: primarily basic MgO, acidic Al<sub>2</sub>O<sub>3</sub> and Mg-Al hydrotalcite (HT) with a combination of Lewis acidic and basic sites. The impact of support selection on selectivity offers insights into the design principles for next-generation catalysts for this process and related transformations.</p>


2007 ◽  
Vol 48 (38) ◽  
pp. 6779-6784 ◽  
Author(s):  
Mohammad Navid Soltani Rad ◽  
Ali Khalafi-Nezhad ◽  
Somayeh Behrouz ◽  
Mohammad Ali Faghihi

2014 ◽  
Vol 43 (46) ◽  
pp. 17248-17254 ◽  
Author(s):  
Jong-Hoo Choi ◽  
Leo E. Heim ◽  
Mike Ahrens ◽  
Martin H. G. Prechtl

In this work, we present a mild method for direct conversion of primary alcohols into carboxylic acids with the use of water as an oxygen source.


1995 ◽  
Vol 36 (4) ◽  
pp. 609-612 ◽  
Author(s):  
Reni Joseph ◽  
Pradeep S. Pallan ◽  
A. Sudalai ◽  
T. Ravindranathan

2000 ◽  
Vol 2 (13) ◽  
pp. 1959-1961 ◽  
Author(s):  
Chengzhi Yu ◽  
Bin Liu ◽  
Longqin Hu

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