Coherent Vibration and Femtosecond Dynamics of the Platinum Complex Oligomers upon Intermolecular Bond Formation in the Excited State

A systematic survey of the Cambridge Structural Database (CSD) has identified all intramolecular hydrogen-bonded ring motifs comprising less than 20 atoms with N and O donors and acceptors. The probabilities of formation Pm of the 50 most common motifs, which chiefly comprise five- and six-membered rings, have been derived by considering the number of intramolecular motifs which could possibly form. The most probable motifs (Pm > 85%) are planar conjugated six-membered rings with a propensity for resonance-assisted hydrogen bonding and these form the shortest contacts, whilst saturated six-membered rings typically have Pm < 10%. The influence of intramolecular-motif formation on intermolecular hydrogen-bond formation has been assessed for a planar conjugated model substructure, showing that a donor-H is considerably less likely to form an intermolecular bond if it forms an intramolecular one. On the other hand, the involvement of a carbonyl acceptor in an intramolecular bond does not significantly affect its ability to act as an intermolecular acceptor and thus carbonyl acceptors display a substantially higher inclination for bifurcation if one hydrogen bond is intramolecular.

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Femtosecond Dynamics on 2-(2′-Hydroxy-4′-diethylaminophenyl)benzothiazole: Solvent Polarity in the Excited-State Proton Transfer

ChemPhysChem ◽

10.1002/cphc.200600017 ◽

2006 ◽

Vol 7 (6) ◽

pp. 1372-1381 ◽

Cited By ~ 47

Author(s):

Yi-Ming Cheng ◽

Shih-Chieh Pu ◽

Chia-Jung Hsu ◽

Chin-Hung Lai ◽

Pi-Tai Chou

Keyword(s):

Excited State ◽

Proton Transfer ◽

Solvent Polarity ◽

Femtosecond Dynamics ◽

Excited State Proton Transfer

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NMR and kinetic studies on phosphine-induced coupling of (.eta.3-methallyl)(acetylacetonato)palladium and -platinum: uniquely facile carbon-carbon bond formation with (.eta.3-allyl)platinum complex

Organometallics ◽

10.1021/om00109a029 ◽

1989 ◽

Vol 8 (7) ◽

pp. 1756-1760 ◽

Cited By ~ 9

Author(s):

Hideo. Kurosawa ◽

Koichiro. Ishii ◽

Yoshikane. Kawasaki ◽

Shinji. Murai

Keyword(s):

Bond Formation ◽

Platinum Complex ◽

Kinetic Studies ◽

Carbon Bond ◽

Carbon Carbon Bond

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Behavior of intermolecular bond formation in the late stage of heat-induced gelation of glycinin

Journal of Agricultural and Food Chemistry ◽

10.1021/jf00067a008 ◽

1986 ◽

Vol 34 (1) ◽

pp. 33-36 ◽

Cited By ~ 48

Author(s):

Tomohiko Mori ◽

Takashi Nakamura ◽

Shigeru Utsumi

Keyword(s):

Late Stage ◽

Bond Formation ◽

Intermolecular Bond

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New Insight into the Origin of the Red/Near-Infrared Intense Fluorescence of a Crystalline 2-Hydroxychalcone Derivative: A Comprehensive Picture from the Excited-State Femtosecond Dynamics

The Journal of Physical Chemistry Letters ◽

10.1021/acs.jpclett.7b02601 ◽

2017 ◽

Vol 8 (22) ◽

pp. 5603-5608 ◽

Cited By ~ 15

Author(s):

N. Idayu Zahid ◽

Mohamad Syafie Mahmood ◽

Balamurugan Subramanian ◽

Suhana Mohd Said ◽

Osama K. Abou-Zied

Keyword(s):

Excited State ◽

Near Infrared ◽

Femtosecond Dynamics ◽

Intense Fluorescence ◽

Comprehensive Picture ◽

Insight Into

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Interactions of nitric oxide and organic nitroso compounds with metalloporphyrins and heme

Journal of Porphyrins and Phthalocyanines ◽

10.1002/(sici)1099-1409(200006/07)4:4<354::aid-jpp240>3.0.co;2-v ◽

2000 ◽

Vol 04 (04) ◽

pp. 354-357 ◽

Cited By ~ 7

Author(s):

GEORGE B. RICHTER-ADDO

Keyword(s):

Nitric Oxide ◽

Excited State ◽

Electronic Properties ◽

Ground State ◽

Bond Formation ◽

Metal Center ◽

Nitroso Compounds ◽

Model Compounds ◽

Axial Ligands ◽

Metal Nitrosyls

The chemistry of nitric oxide (NO) has taken on new dimensions since the discovery, about a decade ago, of a myriad of biological events that NO participates in. Many of the foundations of metal-NO chemistry were laid out earlier by inorganic chemists and biochemists investigating the structures and electronic properties of the heme-NO moiety or its model compounds. Certainly, the persistent work over the last three decades by chemists working with metal nitrosyls has paid off. Current areas of research in heme-NO chemistry include (i) how the NO group approaches and binds to the metal center (or how it dissociates from the metal center); (ii) the ground state and excited state geometries of the metal-NOfragment; (iii) effects of the trans axial ligands on NO orientation and/or dissociation; and (iv) N-N bond formation from NO molecules catalyzed by heme groups.

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