Isothermal crystallization of copolyamides. I. Kinetics of crystallization of nylon 6–piperazine adipate and nylon 6–piperazine terephthalate random copolyamides

1972 ◽  
Vol 16 (8) ◽  
pp. 1959-1965 ◽  
Author(s):  
S. Gogolewski ◽  
E. Turska
2015 ◽  
Vol 23 (8) ◽  
pp. 1403-1407 ◽  
Author(s):  
Min He ◽  
Siqi Zong ◽  
Yahuan Zhou ◽  
Huaibing Guo ◽  
Qingchun Fan

2019 ◽  
Vol 54 (11) ◽  
pp. 1467-1481
Author(s):  
Azzedine Makhlouf ◽  
Abdelheq Layachi ◽  
Imane Kouadri ◽  
Ahmed Belaadi ◽  
Hamid Satha

The present research aims at studying the kinetics of non-isothermal crystallization of the polyamide 66 matrix and its composites with the presence of a glass fiber load. To achieve that goal, the non-isothermal crystallization of polyamide 66 has been studied by means of DSC. The ratio of tested reinforcement varies from 7% to 50% of glass fiber in mass. The modeling, by the theories of Jeziorny and those of Mo, has allowed us to study the influence of adding this reinforcement, as well as the variation of the rate of cooling, on the kinetics of crystallization of the composites in question, which has been manifested by a remarkable change in the nucleation mechanism of the polyamide 66 matrix. Regarding the reinforcement effect, the incorporation of the glass fibers load into the polyamide 66 matrix has caused the appearance of exothermic peaks in a higher temperature range and that for all the working materials. Finally, the results showed that the Mo model is the most suitable for the study of polyamide 66/glass fiber crystallization kinetics.


2000 ◽  
Vol 650 ◽  
Author(s):  
Lance L. Snead ◽  
Martin Balden

ABSTRACTDensification and crystallization kinetics of bulk SiC amorphized by neutron irradiation is studied. The temperature of crystallization onset of this highly pure, fully amorphous bulk SiC was found to be between 875-885°C and crystallization is nearly complete by 950°C. In-situ TEM imaging confirms the onset of crystallization, though thin-film effects apparently alter the kinetics of crystallization above this temperature. It requires >1125°C for complete crystallization of the TEM foil. Annealing at temperatures between the irradiation and crystallization onset temperature is seen to cause significant densification attributed to a relaxation, or reordering, of the as-amorphized structure.


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