Effects of Clay in Nylon Fibe

Since the introduction of nylon 6:6, and nylon 6, the nylon fiber was in significant demand in home textile and technical textile articles. Its uses in hosiery, sail cloth, parachute, blouses, gowns and veils, swim suit, parachute, and lingerie etc. Improving the performance of any nylon matrix with the loading of clay content, for the desired effects, can be an important subject to expand the utilization of nylon in automotive, technical textiles etc. This review study is to find out how clay may contribute in the performance of nylon fiber, and what research directions are appealing in achieving the desired effects in nylon fibers. The known effects on orientation and crystal structure of any nylon polymer; and how the advantageous effects in the utilization of nylon are achievable through the incorporation of clay mineral particularly in composite fiber. Strength, fatigue and thermal stability are some improved effects possible. Heat resistance and flame retardancy are particularly discussed. The aim of this review study is to realize how the nylon fiber was modified using the montmorillonite clay; and to explore what are the possible effects, and improvement achieved.

Fast and Clean Synthesis of Nylon-6/Synthetic Saponite Nanocomposites

Nylon/saponite nanocomposites were synthesized and characterized. The nanocomposites were prepared by means of a fast, efficient, low cost, and environmentally friendly method. All of the tested preparations resulted in the pre-designed nanocomposites. To this end, delaminated saponites were directly synthesized to be used as a filler in a polymer matrix formed by nylon-6 by the in situ intercalation polymerisation of an ε-caprolactam monomer without the use of surfactants or other organic reagents to organophilise the clay, thus avoiding the drawbacks of contamination. The efficiency of the preparation method increased, and significant savings were achieved in terms of both energy reaction time, savings of 60% and 70%, respectively, by using microwave radiation as an energy source during the synthesis of the nanocomposites. In addition, given that the method that was followed avoids the use of contaminating organophilic agents, it is important to highlight the savings in reagents and the fact that there was zero environmental contamination.

Effect of nylon fabric reinforcement on the mechanical performance of adhesive joints made between glass and GFRP

The use of reinforcements in adhesive joints makes the stress distribution more uniform, improving their mechanical performance and adhesion. The present paper aims to verify the effectiveness and efficiency of the insertion of nylon 6 fabric in the adhesive layer, to study their applicability and functionality in building components. The increase in stiffness achieved by applying nylon 6 fabric in the adhesive layer between glass and GFRP pultruded profiles and steel laminates applied to GFRP beams is investigated. Three different epoxy adhesives and one epoxy resin are used and compared. Three different types of tests are carried out in order to study the different properties of the reinforcement system: tensile tests on GFRP/GFRP single-lap adhesive joints, with and without nylon fabric reinforcement; tensile tests on double-lap adhesive joints between float glass and pultruded GFRP profiles reinforced with nylon fabric according to four configurations (in the middle plane of the adhesive layer, on the glass surfaces, on the GFRP surfaces, on both GFRP and glass configurations) to verify the influence of its position; three-point bending tests on long GFRP tubular profiles reinforced with steel plates and nylon fabric in different configurations, to study resistance to bending loads. The results from the experimental campaign show the effectiveness of the reinforcement system using nylon fabric 6. In general, both a reduction in ultimate strength and an increase in joint stiffness compared to unreinforced configurations are observed.

Kinetic Analysis of Pyrolysis and Thermo-Oxidative Decomposition of Tennis String Nylon Wastes

Thermal degradation of nylon-6 tennis string nylon wastes in inert nitrogen and air atmospheres was investigated by means of multiple heating-rate thermogravimetric analyses. The results obtained under the heating rates of 5–20 K/min are compared in terms of degradation feature and specific temperature for two atmospheres. Using nonisothermal data, kinetic analysis was thoroughly conducted using various isoconversional model-free methods, including Starink, Madhusudanan–Krishnan–Ninan, Tang, Coats–Redfern, and Flynn–Wall–Ozawa methods. With these kinetic analysis methods, the activation energy over the entire degradation process was successfully calculated. By means of the model-fitting master-plots method, the first-order chemical reaction model was determined to be the most appropriate mechanism function for describing pyrolysis and oxidative thermal degradation of nylon-6 waste. Using kinetic parameters, satisfactory matching against experimental data resulted using the Coats–Redfern method for both cases. Furthermore, thermodynamic parameters such as changes in entropy, enthalpy, and Gibbs free energy during thermal degradation processes were evaluated.

Aluminum metal composites primed by fused deposition modeling-assisted investment casting: Hardness, surface, wear, and dimensional properties

Fused deposition modeling -based three-dimensional printing techniques, when merged with the investment casting process, is one of the most innovative techniques for developing functionally graded metal–matrix composites in high-performance industrial applications. In this study, Al–Al2O3 matrix composites have been prepared by the combined route of fused deposition modeling and modified investment casting processes. In the first step, the Al–Al2O3 particles have been reinforced into nylon 6 thermoplastics for the preparation of fused deposition modeling-based feedstock filaments (in two configurations: C1 (60% nylon 6–30% Al–10% Al2O3) and C2 (60% nylon 6–28% Al–12% Al2O3). In the next step, the investment casting patterns of the fused deposition modeling process of nylon 6–Al–Al2O3 composites were prepared. Furthermore, the investment casting has been performed by controlling the proportion of nylon 6–Al–Al2O3, the volume of pattern, the density of pattern, barrel finishing media weight, barrel fining time, and number of mold wall layers considering Taguchi L18-based experimental design. Finally, the functional aluminum matrix composites were subjected to testing to investigate average surface roughness ( Ra), deviation inside the cube, average wear, and average hardness. The study results have suggested that maintaining a higher proportion of Al2O3 in three-dimensional printed parts leads to higher Ra, higher dimensional deviation, and higher hardness of investment cast parts. On the contrary, solid patterns have provided low wear rates and low-density patterns resulting in increased wear rates in final investment casted products. Furthermore, the responses are optimized concurrently with the “technique for order of preference by similarity to ideal solution–Taguchi” technique while considering the analytical hierarchical process and entropy weights of significance.

Optimization of Nylon 6 electrospun nanofiber diameter in needle-less wire electrode using central composite design and response surface methodology

In this study, Nylon 6 nanofiber were prepared by needle-less wire electrospinning technique. Since, the fiber diameter determines the porosity, filtration efficiency, and mechanical properties of electrospun nanofiber mat, Central Composite Design (CCD) and Response Surface Methodology have been employed to design the experiments and evaluate the interactive effects of the operating variables such as concentration of the polymeric solution, the distance between two electrodes, applied voltage, and relative humidity (RH%) on the diameter of the Nylon 6 nanofiber. With this connection, an objective of this study was to find out the most influential variables for the finest nanofiber diameter during the spinning with wire type electrode to make the highest possible effective face mask without the addition of any functional additives in it. The overall results show that the combined effect of 12% polymer concentration, 65% RH, 155 mm distance between two electrodes, and 40 kV applied positive voltage have the strongest surface response and are the most significant than the other interactive effects. The Pareto chart illustrates the order of significance affecting the Nylon 6 nanofiber diameter in the order of concentration of the polymeric solution, RH%, the distance between electrodes, and applied positive voltage. Further, bacterial filtration efficiency% of the control sample and five-layer facemask incorporated with optimized nanofiber membrane was found to be 87.4% and 97.5%, respectively, against Staphylococcus Aureus ATCC 6538 bacteria.

SLIDING FRICTION WEAR BEHAVIOUR OF SEASHELL PARTICULATE REINFORCED POLYMER MATRIX COMPOSITE – MODELING AND OPTIMIZATION THROUGH RSM AND GREY WOLF OPTIMIZER

In this work, the friction wear behaviour of seashell particles reinforced in thermoplastic polymer Nylon-6 is investigated.. Seashells were collected from the seashores, uniform size 75 µm is obtained using mechanical ball milling and vibrating sieve. Various proportions of seashells such as 12, 15 and 18% by weight are added to nylon-6 and the polymer composites wear performance in dry sliding is studied as per ASTM G99 standard, loss of material in wear, friction coefficient and interface temperature are optimized. For experiment design Response surface methodology (RSM) based Box-Behnken method (BBD) is adopted and multi-objective analysis is performed using desirability analysis. Observation shows that interface temperature is highly influenced by rotational speed (41.61%), % reinforcement of seashells influences the wear loss significantly (35.71%) and coefficient of friction is influenced greatly by rotational speed (41.48%)and % reinforcement of seashells (18.18%). A novel metaheuristic algorithm Grey wolf optimizer is used for constrained optimization, which shows that for 0.3 CoF and 25°C interface temperature as constraint wear loss is 35.77 microns for % reinforcement of seashell as 3.59, whereas for 0.3 CoF and 30°C interface temperature wear loss is 28.99 microns for a seashell reinforcement of 18%.