Fabrication of carbon fibers from the cupric ion impregnated and thermally stabilized poly(hexamethylene adipamide) precursor

The conversion of poly (hexamethylene adipamide) or polyamide 66 precursor fiber to carbon fibers was accomplished through thermal stabilization and carbonization processes. Thermal stabilization was conducted of cupric chloride (CuCl2)–ethanol-impregnated polyamide 66 (PA66) fibers in the air. To determine the influence of heating rate on the fiber structure and properties of the resultant carbon fibers, carbonization experiments were performed at selected temperatures of 500, 700, 900, and 1100°C using 2.5 and 5 °C/min heating rates with no dwelling. The results conclusively revealed that the volume density and tensile properties of the PA66 fiber were higher at 2.5 °C/min heating rate. After fixing the heating rate as 2.5°C/min, further carbonization experiments were conducted at temperatures from 500 to 1100°C, using increments of 100°C with no dwelling time. Linear density, volume density, fiber diameter, carbon yield, elemental composition, tensile, and electrical properties exhibited a strong dependence on the carbonization temperature. After taking into account the effects of structural defects (i.e., microvoids), tensile strength, and tensile modulus of the carbon fibers increased to 794 MPa and 92.4 GPa, respectively, when carbonized at 1100°C. X-ray diffraction analysis of the carbon fibers further revealed the existence of a greatly disordered (i.e., amorphous) structure, which developed during the carbonization process. FT-IR analysis confirmed the formation of highly aromatic carbon clusters at temperatures of 500°C and higher. The outcomes of electrical conductivity in this study confirm that the PA66 precursor was converted into a semi-conducting state once it was carbonized.

Effect of Vulcanization Process Parameters on the Tensile Strength of Carcass of Textile-Rubber Reinforced Conveyor Belts

Textile-reinforced conveyor belts are most widely used in various industries, including in the mining, construction, and manufacturing industries, to transport materials from one place to another. The conveyor belt’s tensile strength, which primarily relies on the property of the carcass, determines the area of application of the belt. The main aim of the current work was to investigate the influence of vulcanization temperature and duration of the vulcanization process on the tensile properties of the carcass part of the conveyor belt. An extensive experiment was carried out on the tensile properties of woven fabrics that were intended to reinforce conveyor belts by aging the fabrics at the temperature of 140 °C, 160 °C, and 220 °C for six and thirty-five minutes of aging durations. Afterward, the textile-reinforced conveyor belts were produced at vulcanization temperatures of 140 °C, 160 °C, and 220 °C for six and thirty-five minutes of vulcanizing durations. The influence of the vulcanization process parameters on the tensile property of fabrics utilized for the reinforcement of the conveyor belt was analyzed. In addition, the effect of the dipping process of woven fabric in resorcinol–formaldehyde–latex on the tensile property of polyester/polyamide 66 woven fabric (EP fabric) was investigated. The investigation results revealed that the tensile strength of the carcass of the conveyor belt was significantly affected by vulcanization temperature. The conveyor belt vulcanized at 160 °C for 35 min has shown the optimum tensile strength, which is 2.22% and 89.06% higher than the samples vulcanized at 140 °C and 220 °C for 35 min, respectively. Furthermore, the tensile strength and percentage elongation at break of conveyor belts vulcanized at 220 °C were almost destroyed regardless of the vulcanization duration.

The study of a consistent pattern of heat and mass transfer at drying fiber-forming polymers

In this article, the consistent pattern of mass transfer in the process of drying granular polyethylene terephthalate (PET), polycaproamide (PCA), and polyamide 66 (PA 66) were studied. A modified quasi-stationary method was used to analyze the data. The characteristic time and the hydrodynamic intensity index were obtained based on experimental data. Some features of water sorption and desorption by fiber-forming polymers were studied.

A Modular U-Net for Automated Segmentation of X-Ray Tomography Images in Composite Materials

X-Ray Computed Tomography (XCT) techniques have evolved to a point that high-resolution data can be acquired so fast that classic segmentation methods are prohibitively cumbersome, demanding automated data pipelines capable of dealing with non-trivial 3D images. Meanwhile, deep learning has demonstrated success in many image processing tasks, including materials science applications, showing a promising alternative for a human-free segmentation pipeline. However, the rapidly increasing number of available architectures can be a serious drag to the wide adoption of this type of models by the end user. In this paper a modular interpretation of U-Net (Modular U-Net) is proposed with a parametrized architecture that can be easily tuned to optimize it. As an example, the model is trained to segment 3D tomography images of a three-phased glass fiber-reinforced Polyamide 66. We compare 2D and 3D versions of our model, finding that the former is slightly better than the latter. We observe that human-comparable results can be achievied even with only 13 annotated slices and using a shallow U-Net yields better results than a deeper one. As a consequence, neural networks show indeed a promising venue to automate XCT data processing pipelines needing no human, adhoc intervention.

Thermal, Morphological, Electrical Properties and Touch-Sensor Application of Conductive Carbon Black-Filled Polyamide Composites

Polyamide 66 (PA66) is a well-known engineering thermoplastic polymer, primarily employed in polymer composites with fillers and additives of different nature and dimensionality (1D, 2D and 3D) used as alternatives to metals in various technological applications. In this work, carbon black (CB), a conductive nanofiller, was used to reinforce the PA66 polymer in the 9–27 wt. % CB loading range. The reason for choosing CB was intrinsically associated with its nature: a nanostructured carbon filler, whose agglomeration characteristics affect the electrical properties of the polymer composites. Crystallinity, phase composition, thermal behaviour, morphology, microstructure, and electrical conductivity, which are all properties engendered by nanofiller dispersion in the polymer, were investigated using thermal analyses (thermogravimetry and differential scanning calorimetry), microscopies (scanning electron and atomic force microscopies), and electrical conductivity measurements. Interestingly, direct current (DC) electrical measurements and conductive-AFM mapping through the samples enable visualization of the percolation paths and the ability of CB nanoparticles to form aggregates that work as conductive electrical pathways beyond the electrical percolation threshold. This finding provides the opportunities to investigate the degree of filler dispersion occurring during the transformation processes, while the results of the electrical properties also contribute to enabling the use of such conductive composites in sensor and device applications. In this regard, the results presented in this paper provide evidence that conductive carbon-filled polymer composites can work as touch sensors when they are connected with conventional low-power electronics and controlled by inexpensive and commercially available microcontrollers.

The Effect of a Hollow Fixture on Energy Dissipation of Ultrasonic Welded Carbon Fiber/Polyamide 66 Composite

In this study, the effect of the fixture configuration on ultrasonic welding of 4-mm-thick carbon-fiber-reinforced polyamide 66 (CF/PA66) composite with 30% mass fiber was evaluated. An analytical model to estimate the energy dissipation in the welding zone of lapped CF/PA66 samples was derived. Calculation analyses showed the energy dissipation at the faying interface of joints made from hollow-fixture ultrasonic welding (HFUSW) was about 25% higher than those made from conventional ultrasonic welding (CUSW) under the given process variables. This was primarily attributed to the almost total reflection at the workpiece-to-fixture interface in HFUSW. Experimental results indicated that the HFUSW joints exhibited a greater peak load and weld area than CUSW joints when the weld time was less than 2.1 s. The optimal weld time for CUSW and HFUSW processes were 2.1 and 1.7 s. When the weld time exceeded the optimal time, the joints occurred with a porous region, which was caused by thermal decomposition of the material, resulting in the decrease in peak load. Experimental and simulation results demonstrated the HFUSW process changed the propagation behavior of the ultrasonic wave and enhanced the energy dissipation at the faying interface. This study enriched the understanding of energy dissipation during ultrasonic welding of polymers.