Quantitative measurement of physisorbed silane on a silica particle surface treated with silane coupling agents by thermogravimetric analysis

Composites with nano-SiO2 particles and high density polyethylene (HDPE) matrix were produced by hot pressing with various particle contents and particle surface treatment using commercially available silane coupling agents: γ-methacryloxypropyltrimethoxy silane and γ- glycidyloxypropyltrimethoxysilane. The influence of the particle treatment on the mechanical properties of composites was determined by compression and indentation tests. Additionally, numerical analysis was performed in order to calculate Young’s modulus and stress concentrations for various particle contents in order to provide reference data by simulating micro- and macro particle composites with perfect bonding to the matrix.

Download Full-text

Structure of silane layer formed on silica particle surfaces by treatment with silane coupling agents having various functional groups

Journal of Adhesion Science and Technology ◽

10.1080/01694243.2014.926576 ◽

2014 ◽

Vol 28 (19) ◽

pp. 1895-1906 ◽

Cited By ~ 8

Author(s):

Yoshinobu Nakamura ◽

Ryota Yamazaki ◽

Tomoyoshi Fukuda ◽

Kohei Shitajima ◽

Syuji Fujii ◽

...

Keyword(s):

Functional Groups ◽

Silica Particle ◽

Coupling Agents ◽

Silane Coupling Agents ◽

Silane Coupling ◽

Silane Layer

Download Full-text

Mechanical properties of silica particle-filled styrene-butadiene rubber composites containing polysulfide-type silane coupling agents: Influence of loading method of silane

Journal of Applied Polymer Science ◽

10.1002/app.39175 ◽

2013 ◽

Vol 130 (1) ◽

pp. 322-329 ◽

Cited By ~ 18

Author(s):

Tomoyoshi Fukuda ◽

Syuji Fujii ◽

Yoshinobu Nakamura ◽

Mariko Sasaki

Keyword(s):

Mechanical Properties ◽

Silica Particle ◽

Styrene Butadiene Rubber ◽

Coupling Agents ◽

Butadiene Rubber ◽

Silane Coupling Agents ◽

Rubber Composites ◽

Loading Method ◽

Silane Coupling ◽

Styrene Butadiene

Download Full-text

Rheo-optical Behaviors and Stability of a Silica Particle Suspension Coated with Silane Coupling Agents

Journal of Colloid and Interface Science ◽

10.1006/jcis.1998.5651 ◽

1998 ◽

Vol 205 (2) ◽

pp. 397-409 ◽

Cited By ~ 16

Author(s):

Jae-Dong Lee ◽

Seung-Man Yang

Keyword(s):

Silica Particle ◽

Coupling Agents ◽

Particle Suspension ◽

Silane Coupling Agents ◽

Silane Coupling

Download Full-text

Functionalization of Porous Clay Heterostructures with Silane Coupling Agents

Materiale Plastice ◽

10.37358/mp.17.2.4847 ◽

2017 ◽

Vol 54 (2) ◽

pp. 341-344

Author(s):

Anda Ionelia Mihai (Voicu) ◽

Sorina Alexandra Garea ◽

Eugeniu Vasile ◽

Cristina Lavinia Nistor ◽

Horia Iovu

Keyword(s):

Pore Volume ◽

Total Pore Volume ◽

Coupling Agents ◽

Silane Coupling Agents ◽

Porous Clay Heterostructures ◽

Bet Analysis ◽

Silane Coupling ◽

Ftir Spectrometry ◽

Textural Parameters ◽

Epoxy Groups

The goal of this paper was to study the modification of porous clay heterostructures (PCHs) with various silane coupling agents. Two commercial coupling agents (3-aminopropyl-triethoxysilane (APTES) and 3-glycidoxypropyl-trimethoxysilane (GPTMS)) with different functional groups (amine and epoxy groups) were used as modifying agents for the PCHs functionalization. The functionalization of PCH with APTES and GPTMS was evaluated by Fourier transform infrared (FTIR) spectrometry, thermogravimetric analysis (TGA), X-Ray Diffractions (XRD) and BET Analysis. FTIR spectra of modified PCHs confirmed the presence of characteristic peaks of silane coupling agents. TGA results highlighted an increase of weight loss for the modified PCHs that was assigned to the degradation of silane coupling agents (APTES and GPTMS) attached to the PCHs. The XRD results showed that the structure of modified PCHs was influenced by the type of the silane coupling agent. The functionalization of PCHs with silane coupling agents was also confirmed by BET analysis. Textural parameters (specific surface area (SBET), total pore volume (Vt )) suggested that the modified PCHs exhibit lower values of SBET and a significant decrease of total pore volume than unmodified PCHs.

Download Full-text