Mechanistic Insight into the CO2Capture by Amidophosphoranes: Interplay of the Ring Strain and thetransInfluence Determines the Reactivity of the Frustrated Lewis Pairs
Bis(perchlorocatecholato)silane and bidentate N,N- or N,P-heteroleptic donors form hexacoordinated complexes. Depending on the ring strain and hemilability in the adducts, Frustrated Lewis pair reactivity with aldehydes and catalytic ammonia borane...