Mechanistic Insight into the CO2Capture by Amidophosphoranes: Interplay of the Ring Strain and thetransInfluence Determines the Reactivity of the Frustrated Lewis Pairs

2013 ◽  
Vol 8 (12) ◽  
pp. 3147-3151 ◽  
Author(s):  
Jun Zhu ◽  
Ke An
2021 ◽  
Author(s):  
Deborah Hartmann ◽  
Sven Braner ◽  
Lutz Greb

Bis(perchlorocatecholato)silane and bidentate N,N- or N,P-heteroleptic donors form hexacoordinated complexes. Depending on the ring strain and hemilability in the adducts, Frustrated Lewis pair reactivity with aldehydes and catalytic ammonia borane...


RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 20961-20969
Author(s):  
Yunqing He ◽  
Wanli Nie ◽  
Ying Xue ◽  
Qishan Hu

Hydrosilylation or amination products? It depends on water amount and nucleophiles like excess water or produced/added amines.


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