The Heck Reaction of Allylic Alcohols Catalyzed by Palladium Nanoparticles in Water: Chemoenzymatic Synthesis of (R)-(−)-Rhododendrol

ChemCatChem ◽  
2010 ◽  
Vol 3 (2) ◽  
pp. 347-353 ◽  
Author(s):  
Alberto Boffi ◽  
Sandro Cacchi ◽  
Pierpaolo Ceci ◽  
Roberto Cirilli ◽  
Giancarlo Fabrizi ◽  
...  
Keyword(s):  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Chemoenzymatic Synthesis ◽  
Allylic Alcohols

ChemInform Abstract: The Heck Reaction of Allylic Alcohols Catalyzed by Palladium Nanoparticles in Water: Chemoenzymatic Synthesis of (R)-(-)-Rhododendrol.

ChemInform ◽  
2011 ◽  
Vol 42 (22) ◽  
pp. no-no
Author(s):  
Alberto Boffi ◽  
Sandro Cacchi ◽  
Pierpaolo Ceci ◽  
Roberto Cirilli ◽  
Giancarlo Fabrizi ◽  
...  
Keyword(s):  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Chemoenzymatic Synthesis ◽  
Allylic Alcohols

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

Microwave-Based Heck Reaction with Palladium Nanoparticles

Synfacts ◽  
2008 ◽  
Vol 2008 (11) ◽  
pp. 1228-1228
Author(s):  
A. Vallribera ◽  
S. Niembro ◽  
A. Shafir ◽  
R. Alibes
Keyword(s):  
Heck Reaction ◽  
Palladium Nanoparticles

Chiral (R)- and (S)-allylic alcohols via a one-pot chemoenzymatic synthesis

2007 ◽  
Vol 18 (23) ◽  
pp. 2791-2796 ◽  
Author(s):  
Simona Sgalla ◽  
Giancarlo Fabrizi ◽  
Roberto Cirilli ◽  
Alberto Macone ◽  
Alessandra Bonamore ◽  
...  
Keyword(s):  
Chemoenzymatic Synthesis ◽  
Allylic Alcohols ◽  
One Pot

ChemInform Abstract: Fabrication of Palladium Nanoparticles-loaded Carbon Nanofibers Catalyst for the Heck Reaction.

ChemInform ◽  
2014 ◽  
Vol 45 (22) ◽  
pp. no-no
Author(s):  
Liping Guo ◽  
Jie Bai ◽  
Chunping Li ◽  
Haiou Liang ◽  
Weiyan Sun ◽  
...  
Keyword(s):  
Carbon Nanofibers ◽  
Heck Reaction ◽  
Palladium Nanoparticles

Immobilized palladium nanoparticles on potassium zirconium phosphate as an efficient recoverable heterogeneous catalyst for a clean Heck reaction in flow

2015 ◽  
Vol 401 ◽  
pp. 27-34 ◽  
Author(s):  
Chiara Petrucci ◽  
Matteo Cappelletti ◽  
Oriana Piermatti ◽  
Morena Nocchetti ◽  
Monica Pica ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Zirconium Phosphate

Palladium Nanoparticles Supported on an Organic−Inorganic Fluorinated Hybrid Material. Application to Microwave-Based Heck Reaction

2008 ◽  
Vol 10 (15) ◽  
pp. 3215-3218 ◽  
Author(s):  
Sandra Niembro ◽  
Alexandr Shafir ◽  
Adelina Vallribera ◽  
Ramon Alibés
Keyword(s):  
Hybrid Material ◽  
Heck Reaction ◽  
Palladium Nanoparticles

The use of palladium nanoparticles supported with MCM-41 and basic (Al)MCM-41 mesoporous sieves in microwave-assisted Heck reaction

2008 ◽  
Vol 132 (1-4) ◽  
pp. 63-67 ◽  
Author(s):  
Jan Demel ◽  
Sang-Eon Park ◽  
Jiří Čejka ◽  
Petr Štěpnička
Keyword(s):  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Microwave Assisted ◽  
Mesoporous Sieves ◽  
Mcm 41

Palladium Nanoparticles Anchored on Magnesium Organosilicate: An Effective and Selective Catalyst for the Heck Reaction

Synthesis ◽  
2020 ◽  
Author(s):  
Nelson Luís C. Domingues ◽  
Beatriz F. dos Santos ◽  
Beatriz A. L. da Silva ◽  
Aline R. de Oliveira ◽  
Maria H. Sarragiotto ◽  
...  
Keyword(s):  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Amorphous Solid ◽  
Selective Catalyst ◽  
Cross Coupling Reaction ◽  
Efficient Route ◽  
High Yields ◽  
Short Time

AbstractA new and effective palladium catalyst supported on a magnesium organosilicate for application in the Heck reaction is presented. A group of compounds comprising 22 examples were synthesized in moderate to high yields (up to 99%) within a short time. The palladium supported on magnesium organosilicate catalyst was characterized as an amorphous solid by SEM, containing around 33% of palladium inside the solid, and even with this low quantity of palladium, the catalyst was very efficient in the Heck reaction. Besides, based on the Scherrer equation, the crystallite size of the synthesized palladium nanoparticles was ultrasmall (around 1.3 nm). This strategy is a simple and efficient route for the formation of C–C bonds via the Heck cross-coupling reaction.

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