Dual Site Lewis-Acid Metal-Organic Framework Catalysts for CO2 Fixation: Counteracting Effects of Node Connectivity, Defects and Linker Metalation

ChemCatChem ◽  
2018 ◽  
Vol 10 (16) ◽  
pp. 3506-3512 ◽  
Author(s):  
Konstantin Epp ◽  
A. Lisa Semrau ◽  
Mirza Cokoja ◽  
Roland A. Fischer
Keyword(s):  
Lewis Acid ◽  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Node Connectivity ◽  
Metal Organic ◽  
Dual Site ◽  
Organic Framework

Design and synthesis of a new magnetic metal organic framework as a versatile platform for immobilization of acidic catalysts and CO2 fixation reaction

2021 ◽  
Author(s):  
Faezeh Taghavi ◽  
Amir Khojastehnezhad ◽  
Reza Khalifeh ◽  
Maryam Rajabzadeh ◽  
Fahimeh Rezaei ◽  
...  
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
Chemical Fixation ◽  
Design And Synthesis ◽  
Acidic Catalysts ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Fixation Reaction ◽  
Organic Framework

The first report of the use of an acidic magnetic metal organic framework for the chemical fixation of CO2 as an environmentally friendly reaction.

Highly effective Brønsted base/lewis acid cooperative catalysis: a new Cd metal–organic framework for the synthesis of Hantzsch 1,4-DHPs at ambient temperature

2017 ◽  
Vol 41 (24) ◽  
pp. 15475-15484 ◽  
Author(s):  
Farzaneh Rouhani ◽  
Ali Morsali
Keyword(s):  
Ambient Temperature ◽  
Lewis Acid ◽  
Functional Group ◽  
Metal Organic Framework ◽  
Cooperative Catalysis ◽  
Highly Effective ◽  
Metal Organic ◽  
Brønsted Base ◽  
Organic Framework

A new 3D metal–organic framework {[Cd3(BDC)3(OPP)(DMF)2]·2DMA}n (TMU-33) has been synthesized. The performance of the imine functional group of the OPP ligand as a Brønsted base and open Cd site as a Lewis acid in this framework was investigated as cooperative catalyst.

Catalytic CO2 Fixation over a Robust Lactam-Functionalized Cu(II) Metal Organic Framework

2019 ◽  
Vol 58 (15) ◽  
pp. 9723-9732 ◽  
Author(s):  
Shagufi Naz Ansari ◽  
Pawan Kumar ◽  
Anoop K. Gupta ◽  
Pradeep Mathur ◽  
Shaikh M. Mobin
Keyword(s):  
Co2 Fixation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Tandem catalysis with a bifunctional site-isolated Lewis acid–Brønsted base metal–organic framework, NH2-MIL-101(Al)

2012 ◽  
Vol 48 (95) ◽  
pp. 11650 ◽  
Author(s):  
Renganathan Srirambalaji ◽  
Soonsang Hong ◽  
Ramalingam Natarajan ◽  
Minyoung Yoon ◽  
Raghunandan Hota ◽  
...  
Keyword(s):  
Base Metal ◽  
Lewis Acid ◽  
Metal Organic Framework ◽  
Tandem Catalysis ◽  
Metal Organic ◽  
Brønsted Base ◽  
Organic Framework
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