Packed-Bed Microreactor for Continuous-Flow Adipic Acid Synthesis from Cyclohexene and Hydrogen Peroxide

2013 ◽  
Vol 36 (6) ◽  
pp. 1001-1009 ◽  
Author(s):  
M. Shang ◽  
T. Noël ◽  
Q. Wang ◽  
V. Hessel
Keyword(s):  
Hydrogen Peroxide ◽  
Adipic Acid ◽  
Continuous Flow ◽  
Packed Bed ◽  
Acid Synthesis

Clean Adipic Acid Synthesis from Liquid-Phase Oxidation of Cyclohexanone and Cyclohexanol Using (NH4)xAyPMo12O40 (A: Sb, Sn, Bi) Mixed Heteropolysalts and Hydrogen Peroxide in Free Solvent

2017 ◽  
Vol 148 (2) ◽  
pp. 612-620 ◽  
Author(s):  
Lynda Mouheb ◽  
Leila Dermeche ◽  
Tassadit Mazari ◽  
Siham Benadji ◽  
Nadine Essayem ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Adipic Acid ◽  
Acid Synthesis ◽  
Liquid Phase Oxidation ◽  
Phase Oxidation

scholarly journals Green Process for Adipic Acid Synthesis: Oxidation by Hydrogen Peroxide in Water Micromelusions using Benzalkonium Chloride C12-14 Surfactant

2012 ◽  
Vol 10 (1) ◽  
Author(s):  
Geoffroy Lesage ◽  
Isariebel Quesada Peñate ◽  
Patrick Cognet ◽  
Martine Poux
Keyword(s):  
Hydrogen Peroxide ◽  
Adipic Acid ◽  
Phase Transfer ◽  
Industrial Process ◽  
Acid Synthesis ◽  
Operating Conditions ◽  
High Yield ◽  
Green Process ◽  
Phase Transfer Catalysts ◽  
Reaction Media

Abstract Adipic acid was synthesized by the oxidation of cyclohexene using 30% hydrogen peroxide in a microemulsion in the presence of sodium tungstate as catalyst. The proposed green process is environmentally friendly since catalyst and surfactant are recycled and pure adipic acid is produced in high yield (70% to 79%). Microemulsions are used as a “green solvent” and give a better contact between the phases. Alkyldimethylbenzylammonium chloride (C12-C14) was used as a surfactant for the generation of the microemulsion since it enables the use of harmful organic solvents and phase-transfer catalysts to be avoided. Optimised operating conditions (temperature, reaction time, separation process) have been defined and applied to evaluate the industrial practicability. The main interest of the present work is the easy recovery of pure adipic acid and the reuse of the reaction media (surfactant and catalyst). This shows promise for developing a future green industrial process that will enable greenhouse gas emissions (N2O), among others, to be reduced.

Continuous-Flow Synthesis of Adipic Acid from Cyclohexene Using Hydrogen Peroxide in High-Temperature Explosive Regimes

ChemSusChem ◽  
2013 ◽  
Vol 6 (6) ◽  
pp. 978-982 ◽  
Author(s):  
Markus Damm ◽  
Bernhard Gutmann ◽  
C. Oliver Kappe
Keyword(s):  
Hydrogen Peroxide ◽  
High Temperature ◽  
Adipic Acid ◽  
Continuous Flow ◽  
Flow Synthesis

Design of a continuous flow immobilized-cell reactor for biosynthetical production of L-aspartic acid

1985 ◽  
Vol 50 (10) ◽  
pp. 2122-2133 ◽  
Author(s):  
Jindřich Zahradník ◽  
Marie Fialová ◽  
Jan Škoda ◽  
Helena Škodová
Keyword(s):  
Aspartic Acid ◽  
Continuous Flow ◽  
Immobilized Cells ◽  
Scale Up ◽  
Fixed Bed ◽  
Packed Bed ◽  
Fixed Bed Reactor ◽  
Experimental Program ◽  
Design Parameters ◽  
Immobilized Cell

An experimental study was carried out aimed at establishing a data base for an optimum design of a continuous flow fixed-bed reactor for biotransformation of ammonium fumarate to L-aspartic acid catalyzed by immobilized cells of the strain Escherichia alcalescens dispar group. The experimental program included studies of the effect of reactor geometry, catalytic particle size, and packed bed arrangement on reactor hydrodynamics and on the rate of substrate conversion. An expression for the effective reaction rate was derived including the effect of mass transfer and conditions of the safe conversion-data scale-up were defined. Suggestions for the design of a pilot plant reactor (100 t/year) were formulated and decisive design parameters of such reactor were estimated for several variants of problem formulation.

Anderson-type polyoxometalate as excellent catalyst for green synthesis of adipic acid with hydrogen peroxide

2021 ◽  
Vol 510 ◽  
pp. 111705
Author(s):  
Peng Jin ◽  
Huijuan Wei ◽  
Limin Zhou ◽  
Donghui Wei ◽  
Yiqiang Wen ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Green Synthesis ◽  
Adipic Acid

Influence of reactional parameters in the adipic acid synthesis from cyclohexene using heterogeneous polyoxometalates

2020 ◽  
Author(s):  
João Carlos S. Soares ◽  
Arthur Henrique A. Gonçalves ◽  
Fátima M.Z. Zotin ◽  
Lucia R. Raddi de Araújo ◽  
Alexandre B. Gaspar
Keyword(s):  
Adipic Acid ◽  
Acid Synthesis
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