Structural Insight into Binary Protein Metal–Organic Frameworks with Ferritin Nanocages as Linkers and Nickel Clusters as Nodes

2020 ◽  
Vol 26 (14) ◽  
pp. 3016-3021 ◽  
Author(s):  
Chunkai Gu ◽  
Hai Chen ◽  
Yingjie Wang ◽  
Tuo Zhang ◽  
Hongfei Wang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nickel Clusters ◽  
Metal Organic ◽  
Structural Insight ◽  
Insight Into

Quantum Mechanical Interpretation of the Ultra-Low Energy Methyl-Rotation Dynamics in Porous Metal-Organic Frameworks Probed by Low-Frequency Vibrational Spectroscopy and ab initio Simulations

2018 ◽  
Author(s):  
Qi Li ◽  
Adam J. Zaczek ◽  
Timothy M. Korter ◽  
J. Axel Zeitler ◽  
Michael T. Ruggiero
Keyword(s):  
Ab Initio ◽  
Metal Organic Frameworks ◽  
Low Frequency ◽  
Rotor Dynamics ◽  
Quantum Mechanical ◽  
Valuable Insight ◽  
Void Space ◽  
Ab Initio Simulations ◽  
Metal Organic ◽  
Insight Into

<div>Understanding the nature of the interatomic interactions present within the pores of metal-organic frameworks</div><div>is critical in order to design and utilize advanced materials</div><div>with desirable applications. In ZIF-8 and its cobalt analogue</div><div>ZIF-67, the imidazolate methyl-groups, which point directly</div><div>into the void space, have been shown to freely rotate - even</div><div>down to cryogenic temperatures. Using a combination of ex-</div><div>perimental terahertz time-domain spectroscopy, low-frequency</div><div>Raman spectroscopy, and state-of-the-art ab initio simulations,</div><div>the methyl-rotor dynamics in ZIF-8 and ZIF-67 are fully charac-</div><div>terized within the context of a quantum-mechanical hindered-</div><div>rotor model. The results lend insight into the fundamental</div><div>origins of the experimentally observed methyl-rotor dynamics,</div><div>and provide valuable insight into the nature of the weak inter-</div><div>actions present within this important class of materials.</div>

Insight into the Unique Fluorescence Quenching Property of Metal-Organic Frameworks upon DNA Binding

2017 ◽  
Vol 89 (21) ◽  
pp. 11366-11371 ◽  
Author(s):  
Huai-Song Wang ◽  
Hai-Ling Liu ◽  
Kang Wang ◽  
Ya Ding ◽  
Jing-Juan Xu ◽  
...  
Keyword(s):  
Dna Binding ◽  
Fluorescence Quenching ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Insight Into

scholarly journals Synthetic investigation of competing magnetic interactions in 2D metal–chloranilate radical frameworks

2020 ◽  
Vol 11 (23) ◽  
pp. 5922-5928 ◽  
Author(s):  
Kelsey A. Collins ◽  
Richard J. Saballos ◽  
Majed S. Fataftah ◽  
Danilo Puggioni ◽  
James M. Rondinelli ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Magnetic Interactions ◽  
Spin Physics ◽  
Metal Organic ◽  
Synthetic Investigation ◽  
Insight Into

2D metal–organic frameworks provide insight into kagomé spin physics.

Insight into the catalytic properties and applications of metal–organic frameworks in the cyanosilylation of aldehydes

RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79355-79360 ◽  
Author(s):  
Zhiguo Zhang ◽  
Jingwen Chen ◽  
Zongbi Bao ◽  
Ganggang Chang ◽  
Huabin Xing ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Systematic Investigation ◽  
Metal Organic ◽  
Insight Into

This paper presents a systematic investigation of the cyanosilylation of aldehydes with TMSCN by using several MOFs as catalysts.

Atomistic Insight into Adsorption, Mobility, and Vibration of Water in Ion-Exchanged Zeolite-like Metal−Organic Frameworks

ACS Nano ◽  
2009 ◽  
Vol 3 (9) ◽  
pp. 2563-2572 ◽  
Author(s):  
A. Nalaparaju ◽  
R. Babarao ◽  
X. S. Zhao ◽  
J. W. Jiang
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Insight Into

Insight into luminescence enhancement of coordinated water-containing lanthanide metal–organic frameworks by guest molecules

2015 ◽  
Vol 44 (5) ◽  
pp. 2217-2222 ◽  
Author(s):  
Yanlong Wang ◽  
Zhenzhen Xue ◽  
Zhihao Sun ◽  
Chunhong Tan ◽  
Yuehong Wen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Guest Molecules ◽  
Luminescence Enhancement ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Coordinated Water ◽  
Insight Into

The luminescence of novel metal–organic frameworks can be enhanced and reversibly modified by different guest molecules.

Water interactions in metal organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 247-260 ◽  
Author(s):  
Kui Tan ◽  
Nour Nijem ◽  
Yuzhi Gao ◽  
Sebastian Zuluaga ◽  
Jing Li ◽  
...  
Keyword(s):  
Structural Variation ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Insight into the structural variation of metal organic framework materials upon hydration.

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