scholarly journals Synthetic investigation of competing magnetic interactions in 2D metal–chloranilate radical frameworks

2020 ◽  
Vol 11 (23) ◽  
pp. 5922-5928 ◽  
Author(s):  
Kelsey A. Collins ◽  
Richard J. Saballos ◽  
Majed S. Fataftah ◽  
Danilo Puggioni ◽  
James M. Rondinelli ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Magnetic Interactions ◽  
Spin Physics ◽  
Metal Organic ◽  
Synthetic Investigation ◽  
Insight Into

2D metal–organic frameworks provide insight into kagomé spin physics.

Quantum Mechanical Interpretation of the Ultra-Low Energy Methyl-Rotation Dynamics in Porous Metal-Organic Frameworks Probed by Low-Frequency Vibrational Spectroscopy and ab initio Simulations

2018 ◽  
Author(s):  
Qi Li ◽  
Adam J. Zaczek ◽  
Timothy M. Korter ◽  
J. Axel Zeitler ◽  
Michael T. Ruggiero
Keyword(s):  
Ab Initio ◽  
Metal Organic Frameworks ◽  
Low Frequency ◽  
Rotor Dynamics ◽  
Quantum Mechanical ◽  
Valuable Insight ◽  
Void Space ◽  
Ab Initio Simulations ◽  
Metal Organic ◽  
Insight Into

<div>Understanding the nature of the interatomic interactions present within the pores of metal-organic frameworks</div><div>is critical in order to design and utilize advanced materials</div><div>with desirable applications. In ZIF-8 and its cobalt analogue</div><div>ZIF-67, the imidazolate methyl-groups, which point directly</div><div>into the void space, have been shown to freely rotate - even</div><div>down to cryogenic temperatures. Using a combination of ex-</div><div>perimental terahertz time-domain spectroscopy, low-frequency</div><div>Raman spectroscopy, and state-of-the-art ab initio simulations,</div><div>the methyl-rotor dynamics in ZIF-8 and ZIF-67 are fully charac-</div><div>terized within the context of a quantum-mechanical hindered-</div><div>rotor model. The results lend insight into the fundamental</div><div>origins of the experimentally observed methyl-rotor dynamics,</div><div>and provide valuable insight into the nature of the weak inter-</div><div>actions present within this important class of materials.</div>

Insight into the Unique Fluorescence Quenching Property of Metal-Organic Frameworks upon DNA Binding

2017 ◽  
Vol 89 (21) ◽  
pp. 11366-11371 ◽  
Author(s):  
Huai-Song Wang ◽  
Hai-Ling Liu ◽  
Kang Wang ◽  
Ya Ding ◽  
Jing-Juan Xu ◽  
...  
Keyword(s):  
Dna Binding ◽  
Fluorescence Quenching ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Insight Into

scholarly journals Probing magnetic interactions in metal–organic frameworks and coordination polymers microscopically

2018 ◽  
Vol 47 (38) ◽  
pp. 13257-13280 ◽  
Author(s):  
Paul J. Saines ◽  
Nicholas C. Bristowe
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Atomic Scale ◽  
Magnetic Interactions ◽  
Magnetic Metal ◽  
Metal Organic

This perspective paper highlights the insights obtained through experimental and computational probes of magnetic metal–organic frameworks at the atomic scale.

Insight into the catalytic properties and applications of metal–organic frameworks in the cyanosilylation of aldehydes

RSC Advances ◽  
2015 ◽  
Vol 5 (97) ◽  
pp. 79355-79360 ◽  
Author(s):  
Zhiguo Zhang ◽  
Jingwen Chen ◽  
Zongbi Bao ◽  
Ganggang Chang ◽  
Huabin Xing ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Systematic Investigation ◽  
Metal Organic ◽  
Insight Into

This paper presents a systematic investigation of the cyanosilylation of aldehydes with TMSCN by using several MOFs as catalysts.

Structural Insight into Binary Protein Metal–Organic Frameworks with Ferritin Nanocages as Linkers and Nickel Clusters as Nodes

2020 ◽  
Vol 26 (14) ◽  
pp. 3016-3021 ◽  
Author(s):  
Chunkai Gu ◽  
Hai Chen ◽  
Yingjie Wang ◽  
Tuo Zhang ◽  
Hongfei Wang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nickel Clusters ◽  
Metal Organic ◽  
Structural Insight ◽  
Insight Into

Atomistic Insight into Adsorption, Mobility, and Vibration of Water in Ion-Exchanged Zeolite-like Metal−Organic Frameworks

ACS Nano ◽  
2009 ◽  
Vol 3 (9) ◽  
pp. 2563-2572 ◽  
Author(s):  
A. Nalaparaju ◽  
R. Babarao ◽  
X. S. Zhao ◽  
J. W. Jiang
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Insight Into

Insight into luminescence enhancement of coordinated water-containing lanthanide metal–organic frameworks by guest molecules

2015 ◽  
Vol 44 (5) ◽  
pp. 2217-2222 ◽  
Author(s):  
Yanlong Wang ◽  
Zhenzhen Xue ◽  
Zhihao Sun ◽  
Chunhong Tan ◽  
Yuehong Wen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Guest Molecules ◽  
Luminescence Enhancement ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Coordinated Water ◽  
Insight Into

The luminescence of novel metal–organic frameworks can be enhanced and reversibly modified by different guest molecules.

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